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Spectroscopy 1. How to identify the presence of chlorine, bromine, sulfur and nitrogen in an organic...

Spectroscopy

1. How to identify the presence of chlorine, bromine, sulfur and nitrogen in an organic compound from its mass spectrum?

2. How are the electronic absorptions carried out according to their different types of transition?

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Answer #1

we can identify chlorine and bromine based on their isotopes since abundance of 37Cl and 35Cl is 1:3

and about 81 Br and 79 Br is 1:1 so we will be having different intensities for the corresponding peaks

and about N

ions having even no. of nitrogen refres to odd electron ions with even mass number or even electron ions with odd mass number

ions with odd no. of nitrogen refers to odd electron ions with odd mass number or even electron ions with even mass number

answer 2.

types of transition

  • Transitions involving p, s, and n electrons.
  • Transitionsinvolving charge-transfer electrons.
  • Transitions involving d and f electrons
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