Answer:-
1):-
(CrO3/H2SO4 , H2O) is called Jones reagent. It oxidizes the -CHO group (aldehydic group) to carboxylic group (-COOH) and secondary alcohol group to ketone .
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2):-
LAH (lithium aluminium hydride) is a strong reducing agent. It reduces ketone to a secondary alcohol.
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3):-
This reaction is called hydroboration- oxidation reaction . The reaction involves indirect addition of water molecule across the double bond according to anti-Markovnikov's rule.
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4):-
This reaction is the nucleophilic addition of propylmagnesium bromide (grignard reagent) on ketone.
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Ег МСРВА H2SO4 но Brz CH.Cl2 BH, THF Сн,он 1) 9 вBN 2) но, но", но
1. BH 'THE 2. Но,, NaOH ОН .0 сте ,оғ. с з ( ) or 3 or 3 он ОН 1-methyl-1-cyclohexene What product would you expect if the starting material was: a. Styrene, b. a-methylstyrene c. B-methylstyrene d. norbornene
1. BH 'THE 2. Но,, NaOH ОН .0 сте ,оғ. с з ( ) or 3 or 3 он ОН 1-methyl-1-cyclohexene What product would you expect if the starting material was: a. Styrene, b. a-methylstyrene c. B-methylstyrene d. norbornene
RM-Q5 Predict the major organic product of the given reaction. ОН CrO3 ? НО ОН ОН a) b) C) d) Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a а) b b) с с) d d)
3. Provide a full arrow-pushing mechanism for each of the following reactions. Но, он НО Но он і - H- 0ң но он Насо, осна Нt H2O 4. A researcher wants to run the following sequence of reactions. However, they know starting Grignard reagent cannot exist due to the presence of its reactive carbonyl group. MgBr H.H cannot exist! An acetal group can be used to protect" a carbonyl from attack, allowing it to survive otherwise incompatible reaction conditions. Provide...
Question 35 (4 points) What product is expected from the following reaction? но 1. LAH, ether 2 но H ОН Оно OH но ОН ОН
н'-н,о) HS Raney Ni HS H'-но) + Н Но CH2OH NH2 CI 1) LAH ОН 2) H,О ZI Question 1 (6 points). Provide IUPAC names for the following structures. Question 2 (14 points). Convert the following IUPAC names into structures. 2,4-dimethylcyclopent-2-enone 5-hydroxy-2-phenyl-3-hexanone (S)-2-bromo-2-methylcyclobutanone 3-methyl-5-(4-chlorophenyl) hexanal 3-isobutylbenzoic acid Acetic butanoic anhydride N-phenyl-N-propyl-2,3-dimethylbutanamide Page 2 o
draw the organic products of these reactions.
он CrO3. H2504(aq) CH3 CH NaBH4 он он РСС KMnO4(aq), H3O KMnO4(aq), H3O* NH3 H2(g), Ni(s) NH2 NaBH4 1.NH4CI, KCN 2. NaOH, heat CH3 CH3SH, NaOH KCN, HCN heat
4. Give the products of the following reactions. (20 points) но он, на 1. (сн.),cuu 2. Etон ОН ОН HCN Но, но
Predict the products of the following reactions
но он ,н. 1. NaBH, 2. Hot