Homework Answers
the reduction potential is related to gibbs free energy by the relation
G
= - nFE0
for the above reaction n = 2 [ H- transfer ]
so ,
G = - 2 * 96500 * (- 0.536 )
G
= 103448 joules
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1. (4 points) The reduction potential for conversion of glyceraldehyde-3-phosphate to 3- phosphoglycerate is -0.536 V....
The reaction glyceraldehyde-3-phosphate + NAD++Pi→ 1,3 diphosphoglycerate + NADH+H+ has ΔrG∘′=6.3kJmol−1. If the standard reduction potential...
The reaction glyceraldehyde-3-phosphate + NAD++Pi→ 1,3 diphosphoglycerate + NADH+H+ has ΔrG∘′=6.3kJmol−1. If the standard reduction potential ε∘′ of NAD+ is -0.324 V and the reaction 1,3 diphosphoglycerate + ADP→ 3-phosphoglycerate + ATP has ΔrG∘′=−18.8kJ/mol, calculate the standard reduction potential ε∘′ for the reaction 3-phosphoglycerate +2e−+3H+→ glyceraldehyde-3-phosphate +H2O.
In the conversion of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate, NADH is made and phosphate is added. What drives...
In the conversion of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate, NADH is made and phosphate is added. What drives this reaction? O The hydrolysis of ATP to phosphorylate carbon 1 of glyceraldehyde-3-phosphate. The reduction of glyceraldehyde-3-phosphate. The reduction of NAD+. O The oxidation of glyceraldehyde-3-phosphate.
1. 2. 3. 4. Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate...
1.
2.
3.
4.
Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate ~2-phosphoglycerate 1) fructose-6-phosphate→ fructose-1,6-bisphosphate . glucose glucose-6-phosphate Select all that apply. Alcohol fermentation: consumes ATP as it produces ethanol. O produces carbon dioxide begins as pyruvate is decarboxylated to acetaldehyde in a reaction catalyzed by alcohol dehydrogenase m regenerates NAD requires the enzyme alcohol dehydrogenase, In the figure below, what is the reaction occurring at the location...
(8 pts) During glycolysis (a biological pathway we will investigate later in the semester), glyceraldehyde- 3-phosphate...
(8 pts) During glycolysis (a biological pathway we will investigate later in the semester), glyceraldehyde- 3-phosphate is oxidized and phosphorylated to a carboxylic acid derivative (a phosphoanhydride). Using thermodynamic values for the catalyzed and uncatalyzed reactions below, determine equilibrium constant (K ) for the reaction. At STP, does the reaction equilibrium lie on the reactants or products side of the reaction? Glyceraldehyde- CH2OPO,2- 3-Phosphate CH,OPO, Dehydrogenase НО. HO OPO, Н NADH NAD -at STP (AG°° = 6.3 kJ/mol), calculate Key...
In one step of glycolysis, glyceraldehyde 3-phosphate is oxidized by NAD+ to yield 3-phosphoglycerate and NADH....
In one step of glycolysis, glyceraldehyde 3-phosphate is oxidized by NAD+ to yield 3-phosphoglycerate and NADH. 1) Consider that reaction, in the direction written. Which chemicals) is(are) losing electrons, and which chemical(s) is(are) gaining electrons? It's best to answer this in a clear complete sentence. 2 2 2 Table 10-2 Standard Reduction Potentials for Redox Pairs of Biological Relevance* Redox Pair Number of (oxidized form → reduced form) Electrons E.(V) acetate pyruvate 2 -0.70 succinate → a-ketoglutarate 2 -0.67 acetate...
The mechanism of glyceraldehyde 3 phosphate dehydrogenase. In step 1 (Top Left) the sulfur from the cysteine loses its...
The mechanism of glyceraldehyde 3 phosphate dehydrogenase. In
step 1 (Top Left) the sulfur from the cysteine loses its hydrogen
to the carbonyl carbon of the substrate. I think is wrong and the
hydrogen is stolen by the histidine (nitrogen) using a base
catalyst reaction.
lser Glyceraldehyde 3-phosphate NAD CONH2 H -N + HH Hemithioacetal Oxidation NAD NADH CONH CONH2 Но RN + H -N / H Η Η Hн s NADH NAD Thioester intermediate Thioester intermediate Phosphorylation CONH2 O...
1) Which of the following glycolysis intermediates can be generated from glycerol? dihydroxyacetone phosphate 1,3-bisphosphoglycerate glyceraldehyde-3-phosphate...
1) Which of the following glycolysis intermediates can be generated from glycerol? dihydroxyacetone phosphate 1,3-bisphosphoglycerate glyceraldehyde-3-phosphate 3-phosphoglycerate 2) Which of the following is the oxidizing agent in the reaction that converts succinate to fumarate? FAD, NADH, NAD+, succinate, Coenzyme A, or FADH2 3) Five NADH molecules in the mitochondria can be made into _____ number of ATP.
35) The overall reaction of glyceraldehyde 3-phosphate dehydrogenase (GAP glyceraldehyde 3-phosphate + NAD+ + P =...
35) The overall reaction of glyceraldehyde 3-phosphate dehydrogenase (GAP glyceraldehyde 3-phosphate + NAD+ + P = 1,3-bisphosphoglycerate + NADH GAPDH couples together two reactions with favorable (AG'°-50 kj/mol) and unfavorable (AG' +50 kJ/mol) Gibbs free energies, respectively. a) (6 pts) Write the balanced chemical equations for the two separate reactions. b) (6 pts) Draw the structure of the thiohemiacetal intermediate and show the mechanism for generating the acyl thioester intermediate. 36) (4 pts) Under anaerobic conditions, lactic acid fermentation regenerates...
For the reaction: A + Bred = Ared + Box AGⓇ' = -nFAE Given: Nernst Equation:...
For the reaction: A + Bred = Ared + Box AGⓇ' = -nFAE Given: Nernst Equation: AE = AE" - 37) The oxidation of glyceraldehyde 3-phosphate by GAPDH is governed by the following reduction potentials: 3-phosphoglycerate + 2e →glyceraldehyde 3-phosphate E' = -0.55 NAD+ + H+ + 2e → NADH E'' = -0.32 a) (3 pts) What is the standard reduction potentials, AE', for this reaction? b) (4 pts) Show how to calculate of the standard Gibbs free energy, AG"....
17. The reaction shown below describes the formation of 1,3-disphosphoglycerate from glyceraldehyde-3-phosphate. This reaction is coupled...
17. The reaction shown below describes the formation of 1,3-disphosphoglycerate from glyceraldehyde-3-phosphate. This reaction is coupled with the formation of NADH from NAD+ Which statement below is correct? CH,-0-P CHOH c=0 3CH2--0- CHOH 'c=0 он a. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is an oxidation b. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is a reduction c. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is a hydrolysis. d. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is an isomerization.
In the conversion of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate, NADH is made and phosphate is added. What drives this reaction? O The hydrolysis of ATP to phosphorylate carbon 1 of glyceraldehyde-3-phosphate. The reduction of glyceraldehyde-3-phosphate. The reduction of NAD+. O The oxidation of glyceraldehyde-3-phosphate.
1.
2.
3.
4.
Select all that apply. Identify the reaction(s) of glycolysis inhibited by ATP □ glyceraldehyde-3-phosphate → 1,3-bisphosphoglycerate phosphoenolpyruvate +pyruvate 3-phosphoglycerate ~2-phosphoglycerate 1) fructose-6-phosphate→ fructose-1,6-bisphosphate . glucose glucose-6-phosphate Select all that apply. Alcohol fermentation: consumes ATP as it produces ethanol. O produces carbon dioxide begins as pyruvate is decarboxylated to acetaldehyde in a reaction catalyzed by alcohol dehydrogenase m regenerates NAD requires the enzyme alcohol dehydrogenase, In the figure below, what is the reaction occurring at the location...
(8 pts) During glycolysis (a biological pathway we will investigate later in the semester), glyceraldehyde- 3-phosphate is oxidized and phosphorylated to a carboxylic acid derivative (a phosphoanhydride). Using thermodynamic values for the catalyzed and uncatalyzed reactions below, determine equilibrium constant (K ) for the reaction. At STP, does the reaction equilibrium lie on the reactants or products side of the reaction? Glyceraldehyde- CH2OPO,2- 3-Phosphate CH,OPO, Dehydrogenase НО. HO OPO, Н NADH NAD -at STP (AG°° = 6.3 kJ/mol), calculate Key...
In one step of glycolysis, glyceraldehyde 3-phosphate is oxidized by NAD+ to yield 3-phosphoglycerate and NADH. 1) Consider that reaction, in the direction written. Which chemicals) is(are) losing electrons, and which chemical(s) is(are) gaining electrons? It's best to answer this in a clear complete sentence. 2 2 2 Table 10-2 Standard Reduction Potentials for Redox Pairs of Biological Relevance* Redox Pair Number of (oxidized form → reduced form) Electrons E.(V) acetate pyruvate 2 -0.70 succinate → a-ketoglutarate 2 -0.67 acetate...
The mechanism of glyceraldehyde 3 phosphate dehydrogenase. In
step 1 (Top Left) the sulfur from the cysteine loses its hydrogen
to the carbonyl carbon of the substrate. I think is wrong and the
hydrogen is stolen by the histidine (nitrogen) using a base
catalyst reaction.
lser Glyceraldehyde 3-phosphate NAD CONH2 H -N + HH Hemithioacetal Oxidation NAD NADH CONH CONH2 Но RN + H -N / H Η Η Hн s NADH NAD Thioester intermediate Thioester intermediate Phosphorylation CONH2 O...
35) The overall reaction of glyceraldehyde 3-phosphate dehydrogenase (GAP glyceraldehyde 3-phosphate + NAD+ + P = 1,3-bisphosphoglycerate + NADH GAPDH couples together two reactions with favorable (AG'°-50 kj/mol) and unfavorable (AG' +50 kJ/mol) Gibbs free energies, respectively. a) (6 pts) Write the balanced chemical equations for the two separate reactions. b) (6 pts) Draw the structure of the thiohemiacetal intermediate and show the mechanism for generating the acyl thioester intermediate. 36) (4 pts) Under anaerobic conditions, lactic acid fermentation regenerates...
For the reaction: A + Bred = Ared + Box AGⓇ' = -nFAE Given: Nernst Equation: AE = AE" - 37) The oxidation of glyceraldehyde 3-phosphate by GAPDH is governed by the following reduction potentials: 3-phosphoglycerate + 2e →glyceraldehyde 3-phosphate E' = -0.55 NAD+ + H+ + 2e → NADH E'' = -0.32 a) (3 pts) What is the standard reduction potentials, AE', for this reaction? b) (4 pts) Show how to calculate of the standard Gibbs free energy, AG"....
17. The reaction shown below describes the formation of 1,3-disphosphoglycerate from glyceraldehyde-3-phosphate. This reaction is coupled with the formation of NADH from NAD+ Which statement below is correct? CH,-0-P CHOH c=0 3CH2--0- CHOH 'c=0 он a. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is an oxidation b. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is a reduction c. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is a hydrolysis. d. The reaction of glyceraldehyde-3-phosphate to form 1,3-disphosphoglycerate is an isomerization.
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