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1. Give the products and draw the mechanism for the following: H20, H+ 2. Propose a...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20 Qestion 5 (6 points) Propose a synthesis for the target compound with given starting materials. You may use additional reagents you need. The proposed synthesis should be no more than S steps. Hint: Enolate Reaction, Decarboxylation Reaction. Target Compound Starting Materials
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20
Qestion...
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B...
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B and C. Note: each step consists of more than one transformation. Step 1 in slope fin Step 2 Hint: you can use Br 1. H', ethylene glycol, heat 2. NaOH/H, O, heat 3. H30* Product A Step 3 HCl dilute Product C Product B 1. PhMgBr, ether 2. H20 acetone Step 1: Step 2: Step 3: 3. Show the full mechanism of Step 3...
4. 1) LIAIH 2) H20 5. Propose an efficient synthesis for one of the following transformations....
4. 1) LIAIH 2) H20 5. Propose an efficient synthesis for one of the following transformations. Please circle the synthesis you are completing. More than one step will be required; be sure to number each step. It will be significantly easier to award partial credit if you show the intermediate product after each step. CN Br ОН OR OH + enantiomer
5. (a) Propose a mechanism for the reaction of 2-bromopyridine with sodium amide to give 2-...
5. (a) Propose a mechanism for the reaction of 2-bromopyridine with sodium amide to give 2- aminopyridine (b) When 3-bromopyridine is used in this reaction, stronger reaction conditions are required to give a mixture of 3-aminopyridine and 4-aminopyridine results. Propose a mechanism which explains this curious result 6. Show the formation of the following reduction products, if the reaction proceeds. If not, propose a different reagent to reduce the starting material! NaBH, (b) NaBH4 KOH OH 1.) LAIH 2.) H,00...
Propose an efficient synthesis for each of the following transformations: O OH. - H20 1) [H*),...
Propose an efficient synthesis for each of the following transformations: O OH. - H20 1) [H*), HO 2) NaNH2 3) Eti 1) [H"), HO 2) Eti O H. - H2O 4) H30* OH-H20 1) [H"). HO 2) NaNH2 3) Eti 4) H30 O H. - H20 1) [H*). HO 2) NaNH2 3) H30 ОН 1) [н']), но 2) LiAIH, он, - H,0 он, - H,0 1) [н'], но 2) Н, 3) НО* 1) [н'], но 2) H2 он, -но он,...
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO...
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO d. OH H2o 10. For the following reaction, H,so, H,O он a. Give the curved arrow mechanism for the reaction, showing formation of both products b. Identify the major product and explain why it is favored. c. Draw the energy diagram for the formation of the major product. 11. Give the major organic product for the following reactions. If a racemic mixture is expected,...
Pericyclic Reactions 1. Predict the products of the following reactions and propose a mechanism that explains...
Pericyclic Reactions 1. Predict the products of the following reactions and propose a mechanism that explains it Me a heat OMCN heat 9. Ome =-COME HOY Y hest MeOC 2. Propose a synthesis of the following molecules using acetaldehyde as your only starting material 3. Propose a mechanism for the following transformations Meo,
Propose a plausible mechanism for the following transformation. For the mechanism, draw the curved arrows as...
Propose a plausible mechanism for the following transformation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. 1) NaOH 2) H20+
Conceptual Checkpoint 20.18 Propose a mechanism for the following transformation. For the mechanism, draw the curved...
Conceptual Checkpoint 20.18 Propose a mechanism for the following transformation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. 1) xs Et MgBr 2) conc. H,SO, heat Step 1 Get help answering Molecular Drawing questions. Draw Step 1 of the mechanism. HC—CHE Edit LINK TO TEXT
Show the products for the following reactions. Propose starting materials that can form the follo...
Show the products for the following reactions. Propose starting
materials that can form the following product in one step.
NaOH, Br2 d. PCls. Br2 он e. 4. Propose starting materials that can form the following product in one step Compound Z Synthesize the starting materials you proposed above from Ethanal and ethyl acetate (do not use other carbonyl compounds). You can use ethanal and ethyl acetate as many times as you need to. Hint: you will use the 3 carbon-carbon...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20 Qestion 5 (6 points) Propose a synthesis for the target compound with given starting materials. You may use additional reagents you need. The proposed synthesis should be no more than S steps. Hint: Enolate Reaction, Decarboxylation Reaction. Target Compound Starting Materials
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20
Qestion...
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B and C. Note: each step consists of more than one transformation. Step 1 in slope fin Step 2 Hint: you can use Br 1. H', ethylene glycol, heat 2. NaOH/H, O, heat 3. H30* Product A Step 3 HCl dilute Product C Product B 1. PhMgBr, ether 2. H20 acetone Step 1: Step 2: Step 3: 3. Show the full mechanism of Step 3...
4. 1) LIAIH 2) H20 5. Propose an efficient synthesis for one of the following transformations. Please circle the synthesis you are completing. More than one step will be required; be sure to number each step. It will be significantly easier to award partial credit if you show the intermediate product after each step. CN Br ОН OR OH + enantiomer
5. (a) Propose a mechanism for the reaction of 2-bromopyridine with sodium amide to give 2- aminopyridine (b) When 3-bromopyridine is used in this reaction, stronger reaction conditions are required to give a mixture of 3-aminopyridine and 4-aminopyridine results. Propose a mechanism which explains this curious result 6. Show the formation of the following reduction products, if the reaction proceeds. If not, propose a different reagent to reduce the starting material! NaBH, (b) NaBH4 KOH OH 1.) LAIH 2.) H,00...
Propose an efficient synthesis for each of the following transformations: O OH. - H20 1) [H*), HO 2) NaNH2 3) Eti 1) [H"), HO 2) Eti O H. - H2O 4) H30* OH-H20 1) [H"). HO 2) NaNH2 3) Eti 4) H30 O H. - H20 1) [H*). HO 2) NaNH2 3) H30 ОН 1) [н']), но 2) LiAIH, он, - H,0 он, - H,0 1) [н'], но 2) Н, 3) НО* 1) [н'], но 2) H2 он, -но он,...
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO d. OH H2o 10. For the following reaction, H,so, H,O он a. Give the curved arrow mechanism for the reaction, showing formation of both products b. Identify the major product and explain why it is favored. c. Draw the energy diagram for the formation of the major product. 11. Give the major organic product for the following reactions. If a racemic mixture is expected,...
Pericyclic Reactions 1. Predict the products of the following reactions and propose a mechanism that explains it Me a heat OMCN heat 9. Ome =-COME HOY Y hest MeOC 2. Propose a synthesis of the following molecules using acetaldehyde as your only starting material 3. Propose a mechanism for the following transformations Meo,
Propose a plausible mechanism for the following transformation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. 1) NaOH 2) H20+
Conceptual Checkpoint 20.18 Propose a mechanism for the following transformation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. 1) xs Et MgBr 2) conc. H,SO, heat Step 1 Get help answering Molecular Drawing questions. Draw Step 1 of the mechanism. HC—CHE Edit LINK TO TEXT
Show the products for the following reactions. Propose starting
materials that can form the following product in one step.
NaOH, Br2 d. PCls. Br2 он e. 4. Propose starting materials that can form the following product in one step Compound Z Synthesize the starting materials you proposed above from Ethanal and ethyl acetate (do not use other carbonyl compounds). You can use ethanal and ethyl acetate as many times as you need to. Hint: you will use the 3 carbon-carbon...
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