Homework Answers
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c)...
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c) ОН ОН (d) Br ОН ОН NH2 2) Draw the condensed and line structures for the following compounds (a) 3,4-dimethylhexanoic acid (b) Phenylacetic acid (c) 3,4-dinitrobenzoic acid (d) 2,2,3-triflurobutanoic acid (e) 3-hydroxybutanoic acid (1) o-hydroxybenzoic acid (g) a-aminopropionic acid 3) Name the following dicarboxylic acids (use both IUPAC and common names) Он (а) НО ОН НО. (b) он ОН ОН (d) ОН он ОН...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1....
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
Circle the one correct answer for our pluvieill. (100) A. The reaction of an alkene with...
Circle the one correct answer for our pluvieill. (100) A. The reaction of an alkene with chloroform (CHCl3) in the presence of a strong base, such as potassium tert-butoxide (KOC(CH3)3) gives a: a) epoxide b) aldehyde c) alcohold) cycloalkanee ) ketone B. Which of the following would give formaldehyde (H2C=0) upon treatment with aqueous periodic acid (HIO)? a) а) CH2OH b) d) н -он HO-LH CH OH CH OH Но HOH CH OH CH OCH3 Ε0 OH CH OH FO...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc C...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc CHOICH CH 10 | | CH-CH HỒ CH-CH CH-CH CH-CH CH-CH но он но HO он но OH OH HO A B C D Do not e How many carbons does each of the above sugars contain? Name to E n ipo Which sugars are aldoses and which are ketoses? Identify each sugar. Name the linkage for each...
List in Order (a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O...
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
What is the major Organic product of the following reaction? o CH N OH O NH...
What is the major Organic product of the following reaction? o CH N OH O NH CH; woon OCH; (a) (b) (c) N NH, CH; (d) ce Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о H,C, 1) -MgCI 2) Н,0* ОН ОН нс ОН не КА HC ІН (b) (c) CH ОН H О Н HC H нс, What is the major Organic product of the following sequence of reactions? 1) NaH,...
10. Which of the following roduct, if any, is not a heterocyclic amine? CHE HCNN Ho all of them are heterocy...
10. Which of the following roduct, if any, is not a heterocyclic amine? CHE HCNN Ho all of them are heterocyclic amines i Cho OH HOH OH LCH, HOW N & CH₂ IN-CH HO (e) (b) 11. What is the IUPAC har is the IUPAC name of the following compound pound? OOH 9 TOH OH 9 hydroxy-1.4-dimethyl-5-oxohexanoic acid hydroxy-2-methyl-5-oxohexanoic acid (d) 2-hydro ydroxy-2,5-dimethyl-6-oxoheptanoic acid 2-hydroxy-1-methyl-4-oxopentanoic acid (e) 3-hydrox 3-hydroxy-2,5-dimethyl-5-oxohexanoic acid O 3-hydroxy-2,5-dimethy 12. Predict the product/s, the product/s, if any,...
оо 15. HỌN _C02 1) (CH3)3COCOCOC(CH3)3 Ph 2) -N: C: NH- CHO HO+H PhNHNH | 16....
оо 15. HỌN _C02 1) (CH3)3COCOCOC(CH3)3 Ph 2) -N: C: NH- CHO HO+H PhNHNH | 16. H+OH (3 equiv.) н+он HOHH CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) Br ÇO2Et ON starting material product
Select the molecules that contains sphingosine. CH2 CH2 CH2 CH2 CH2 CH2 CH3 HO-CH-CH=CH2 CH2 CH2...
Select the molecules that contains sphingosine. CH2 CH2 CH2 CH2 CH2 CH2 CH3 HO-CH-CH=CH2 CH2 CH2 CHỊ CH2 CH2 CH2 — OCH CHO CH NH C H 2 CH2 CH2 CH2 CH, CH2 CH, Molecule B Moleculec sphingomyelins phosphatidylcholine Molecule A CH NH C CH CH, CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH CH2-O-P-O-CH2-CH2-NCH CH3 Molecule A CH(CH2)4-C-0-CH CH(CH) --0-CH NH CHE-O-P-O-CH2-HC COO Molecule B O CH2-0-HC CH(CH2)---NH-CH Сн-он CH(CH3)2 -CH=CH Molecule C 0-0-1 0-0-1
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c) ОН ОН (d) Br ОН ОН NH2 2) Draw the condensed and line structures for the following compounds (a) 3,4-dimethylhexanoic acid (b) Phenylacetic acid (c) 3,4-dinitrobenzoic acid (d) 2,2,3-triflurobutanoic acid (e) 3-hydroxybutanoic acid (1) o-hydroxybenzoic acid (g) a-aminopropionic acid 3) Name the following dicarboxylic acids (use both IUPAC and common names) Он (а) НО ОН НО. (b) он ОН ОН (d) ОН он ОН...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
Circle the one correct answer for our pluvieill. (100) A. The reaction of an alkene with chloroform (CHCl3) in the presence of a strong base, such as potassium tert-butoxide (KOC(CH3)3) gives a: a) epoxide b) aldehyde c) alcohold) cycloalkanee ) ketone B. Which of the following would give formaldehyde (H2C=0) upon treatment with aqueous periodic acid (HIO)? a) а) CH2OH b) d) н -он HO-LH CH OH CH OH Но HOH CH OH CH OCH3 Ε0 OH CH OH FO...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc CHOICH CH 10 | | CH-CH HỒ CH-CH CH-CH CH-CH CH-CH но он но HO он но OH OH HO A B C D Do not e How many carbons does each of the above sugars contain? Name to E n ipo Which sugars are aldoses and which are ketoses? Identify each sugar. Name the linkage for each...
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
What is the major Organic product of the following reaction? o CH N OH O NH CH; woon OCH; (a) (b) (c) N NH, CH; (d) ce Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о H,C, 1) -MgCI 2) Н,0* ОН ОН нс ОН не КА HC ІН (b) (c) CH ОН H О Н HC H нс, What is the major Organic product of the following sequence of reactions? 1) NaH,...
10. Which of the following roduct, if any, is not a heterocyclic amine? CHE HCNN Ho all of them are heterocyclic amines i Cho OH HOH OH LCH, HOW N & CH₂ IN-CH HO (e) (b) 11. What is the IUPAC har is the IUPAC name of the following compound pound? OOH 9 TOH OH 9 hydroxy-1.4-dimethyl-5-oxohexanoic acid hydroxy-2-methyl-5-oxohexanoic acid (d) 2-hydro ydroxy-2,5-dimethyl-6-oxoheptanoic acid 2-hydroxy-1-methyl-4-oxopentanoic acid (e) 3-hydrox 3-hydroxy-2,5-dimethyl-5-oxohexanoic acid O 3-hydroxy-2,5-dimethy 12. Predict the product/s, the product/s, if any,...
оо 15. HỌN _C02 1) (CH3)3COCOCOC(CH3)3 Ph 2) -N: C: NH- CHO HO+H PhNHNH | 16. H+OH (3 equiv.) н+он HOHH CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) Br ÇO2Et ON starting material product
Select the molecules that contains sphingosine. CH2 CH2 CH2 CH2 CH2 CH2 CH3 HO-CH-CH=CH2 CH2 CH2 CHỊ CH2 CH2 CH2 — OCH CHO CH NH C H 2 CH2 CH2 CH2 CH, CH2 CH, Molecule B Moleculec sphingomyelins phosphatidylcholine Molecule A CH NH C CH CH, CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH CH2-O-P-O-CH2-CH2-NCH CH3 Molecule A CH(CH2)4-C-0-CH CH(CH) --0-CH NH CHE-O-P-O-CH2-HC COO Molecule B O CH2-0-HC CH(CH2)---NH-CH Сн-он CH(CH3)2 -CH=CH Molecule C 0-0-1 0-0-1
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
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