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2.9-In retrosynthetic fashion, dissect the following molecule into two compounds, one of which is the indicated...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H.O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H2O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated...
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [8 points] NH ONH2 Make starting with
1) What is the correct assignment of assignment of the functional groups in the following compounds?...
1) What is the correct assignment of assignment of the functional groups in the following compounds? a. 1 = amide; 2 = ester; 3 = nitrile b. 1 = nitrile; 2 = ester; 3 = imide c. 1 = nitrile; 2 = ester; 3 = amide d. 1 = amide; 2 = carboxylic acid; 3 = imide 2) What is the IUPAC name of the following compound? a. butyl isopropanoate b. isopropyl pentanoate c. pentanoyl isopropane d. isopropyloxybutanal 3) What...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, eg. 1) LAH 2) H.O should be considered as one step Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
identify which compound is more acidic and explain your choice. or each of the following compounds,...
identify which compound is more acidic and explain your choice. or each of the following compounds, Make sure you include structures of these which compounds in your answers ounds, 1. F (e) 24-Dimethy-3,5-hepanedione or 4, 4-Dimethy)-3,5-heptanedione (b) 1.2-Cyclopentanedione or 1,3-cyclopentanedione 2. When 2-hepten-4-one is treated with LDA, a proton is removed from one of the gamma (z) positions. identily which gamma position is deprotonated, and explain why the y proton is the most acidie proton in the compound. 3. Rank...
Which of the following compounds are potentia acetic ester synthesis? ne rollowing compounds are "potential' targets...
Which of the following compounds are potentia acetic ester synthesis? ne rollowing compounds are "potential' targets for either the malonic ester or the aceto hem. For each of these, draw the structurels) of the alkylating agents and indicate if the compound could be made efficiently by this method. Select the best reagent system to prepare each of the following. Use a given method only once LO 00+ АО Hydrolysis of a nitrile made from a five-carbon alcohol Oxidative cleavage of...
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving tw...
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
Complete questions 10-27 PART II: REACTIONS: Here is another different" question. Pretend you have been asked...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
**(left structure)****(right structure)** The two structures for the assignment are above and the task is: 1....
**(left structure)****(right
structure)**
The two structures for the assignment are above and
the task is:
1. Perform a retrosynthetic analysis on the two target
molecules assigned to you. In each case the organic
starting material (what you have to work backwards toward) depends
upon the target. For the structure given above (structure on left),
the starting material is either malonic ester or acetoacetic ester
and any halide. For the structure given above (structure on right),
the starting material is any...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H.O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H2O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [8 points] NH ONH2 Make starting with
1) What is the correct assignment of assignment of the functional groups in the following compounds? a. 1 = amide; 2 = ester; 3 = nitrile b. 1 = nitrile; 2 = ester; 3 = imide c. 1 = nitrile; 2 = ester; 3 = amide d. 1 = amide; 2 = carboxylic acid; 3 = imide 2) What is the IUPAC name of the following compound? a. butyl isopropanoate b. isopropyl pentanoate c. pentanoyl isopropane d. isopropyloxybutanal 3) What...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, eg. 1) LAH 2) H.O should be considered as one step Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
identify which compound is more acidic and explain your choice. or each of the following compounds, Make sure you include structures of these which compounds in your answers ounds, 1. F (e) 24-Dimethy-3,5-hepanedione or 4, 4-Dimethy)-3,5-heptanedione (b) 1.2-Cyclopentanedione or 1,3-cyclopentanedione 2. When 2-hepten-4-one is treated with LDA, a proton is removed from one of the gamma (z) positions. identily which gamma position is deprotonated, and explain why the y proton is the most acidie proton in the compound. 3. Rank...
Which of the following compounds are potentia acetic ester synthesis? ne rollowing compounds are "potential' targets for either the malonic ester or the aceto hem. For each of these, draw the structurels) of the alkylating agents and indicate if the compound could be made efficiently by this method. Select the best reagent system to prepare each of the following. Use a given method only once LO 00+ АО Hydrolysis of a nitrile made from a five-carbon alcohol Oxidative cleavage of...
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
**(left structure)****(right
structure)**
The two structures for the assignment are above and
the task is:
1. Perform a retrosynthetic analysis on the two target
molecules assigned to you. In each case the organic
starting material (what you have to work backwards toward) depends
upon the target. For the structure given above (structure on left),
the starting material is either malonic ester or acetoacetic ester
and any halide. For the structure given above (structure on right),
the starting material is any...
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