1. Predict the products of the following reactions. (2.5) OH Sock int H2O U CH, 1....
Predict the products of the following reactions. a. b. c. (1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
2. Predict the products of the following Grignard reactions. 1. excess EtMgBr 2. H2O Och3 B. o 1. excess CH3MgCI 2. H30*
Predict the products of the following reactions. a. b. c. (1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Predict the products, if any, of the following reactions. COOH (1) LiAlH (2) H2O* (b) CH B (1) NaCN (2) 40*, heat (1) SOCI2 (a) oct-4-ino KMnO4 H20 (warm , conc.) (2) AICI COOH Ph 10 O Na,Cr,O, H,SO4 BH CH,OHN_C6:0, 14,50. CHCH.–CH-COOH BH, CH,OH (1) CH,CH, -CH-COOH CH,OH KMnO4, H2O (warm, conc.) KMnO,H,O (hot , conc.)
Predict the products of the following reactions. H2O + H2O- OH + H2O R, & H2O - - R-NOL + H2O. hook + H2O - kort H2o
Question 1 (4 Points) What are the products of the following reactions? + CH CH,OH HCI, excess a. CH3CH H trace acid + CH3NH2 1 CHACH O 1. NaBH4 2. H30+ c. CH CH CH; HCI d. CH3CH CH-CH + NaC=N- excess
1) (5 points each) Give the products of the following reactions: Br2, H30+,H,O OH, H2O 1) OH, H20 i 10.40 2) H20 H30+
:) Predict the necessary set of reagents/products for the reactions to react with 2-methylpropanal. HOCH,CH,OH Na,Cr,0, H2SO4, H2O 1) CH CH.Li 2) H20 1) NaCN 2) HCI HO NaBH4 CH3CH2OH NH,OH 13
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
Predict the products of the following reactions. 1. BH3 2. H2O2, OH CHCl3, KOH I-C1 (show the dipole in 1-C1, which is more electronegative?) 1. Hg(OAC)2, H2O 2. NaBHA 1. Hg(OAC)2, EtOH (not water) 2. NaBH4 m-CPBA H30+ 1. Os04 2. NaHSO3, H20