in a solution, molarity = (number of moles of solute present in the solution) / (total volume of solution in litre)
therefore,
number of moles of solute present in the solution = molarity x
total volume of solution in litre
=(molarity x total volume of solution in ml) / 1000
= (0.1685 x 24.77) / 1000
= 0.004174 moles
= (4.174 * 10^-3) moles
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