1. Draw the major product or give the reagents necessary to complete the fol points each):...
1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) Ph H2 Lindlar cat. hexanes Me 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) Br CH 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) OME B OMe Me Me NaOH H2O2 Me Me H
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1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) H 1.9-BBN-H THE Me Me 2. NaOH H202 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) H Me Me Br Br Me Br Br 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) Ph Li(0) Ph Ph Ph NH30)
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. ETOA earrangement Oceurs H,PO Reagement Our KOCH.CH HOCH-CH, Show Specific Stereochemistry CH,CHE + CH -CH NaOCH, HOCH OCH) Show Specific Stereochemistry KOCH.CH HOCH.CH KOB HO.Bu Provide a complete, stepwise mechanism to explain the following transformation. Be...
Reactions: Give the structure of the major product(s) or the reagents necessary to complete each of the following reactions. If necessary, indicate the product stereochemistry.
7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2 (a-b) excess 2. LIAIHA 3. H20 ia -NH ?? excess (c-d) HO NH2 triethylamine ? (e-f) CEN 1. CHẠMgBr 2. H20, H NH2 (g-h) H20, H* H2. Pd (1-1) CH3NH2 4 products (m) 1. LAIH 2. H2O, H & NH (n) 1. LiAIH4 2. H20, H+ 8. Predict the four possible Aldol condensation products and their dehydration products. KOH, H20.A + H 1. Predict...
2. Draw a detailed arrow pushing mechanism for the following transformation (3 points): i 1)^_MGBT OH H2) H20
20. Provide the reagents necessary to complete the following the following transformation. A. 1. BH3 THF2. H2O2. HO- B. H20, H2SO4 C. OsO4 H202 D. CH3CO3H E. 1. CH3CO3H 2. H, H20 21. Provide the major organic product of the reaction below. 10. 2. (CHS uraw the major organic product generated in the reaction below. Pay particular attention to and stereochemical detail. CH3 CH, KMnO4 (warm, conc.) CH, H 23. Give the structure of the alkene which would yield the...
1. predict the major products.
2. draw detailed arrow mechanism.
1. Predict the major product of the reaction. Clearly indicate stercochemistry, if necessary На Lindlarca Me hexanes 2. Provide reagents to achieve the shown multi-step transformations (6 pts)
1)Draw all alkene prodcuts that could form
2) Circle the major alkene product expected
3) Draw a complete arrow pushing mechanism how the major
product is formed. (Show all srrows, intermediate structures,
formal charges)
2. (19pts) The alcohol dehydration product below is of the El type elimination. (i) Draw all of the alkene products that could possibly form. (ii) Circle the major alkene product expected. (ii) Draw a complete curved arrow-pushing mechanism illustrating how the major product is formed. Be...
Write the product and a complete arrow-pushing mechanism and propose (the) major product(s) for the following transformation. After a Grignard reaction. .... Each of the Grignard reactions we have studied so far produces an alcohol as the major organic product. Alcohols can be used as starting materials for a number of organic reactions. Use this exercise to consider the range of reactions that can be performed after a Grignard reaction. For each reaction sequence below, suggest a Grignard reagent and...