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calculate the delta h,delta s and delta s universe for this
reaction. determine the spontaneity of...
2. Lastly, use the table of thermodynamic functions to compute the AHo and ASo for the...
2. Lastly, use the table of thermodynamic functions to compute the AHo and ASo for the reactions in #1. Then using AH° and AS° and your knowledge of the second law, compute which reactions are spontaneous under standard conditions. You must show all your calcualtions. (7pts) Spontaneous ASo ASuniv ΔΗ Reaction 2H2(g) + 02(g) 2H20() CO2(s)-CO2(g) K (aq)+ Cl (aq)- KCI(s) Thermodynamic Properties at 298 K AH AG Substance kJ/mol kJ/mol 3/(mol-K) Ag(s) Ag (aq) AgBr(s) AgCls) Agl(s) Cl:(g) CI(8)...
2Cl(g) = Cl2(g) Calculate the AH, AS and AS universe for this reaction. Determine the spontaneity...
2Cl(g) = Cl2(g) Calculate the AH, AS and AS universe for this reaction. Determine the spontaneity of the reaction.
Question 5 The spontaneity of a reaction depends both on the enthalpy change, Delta H, and...
Question 5 The spontaneity of a reaction depends both on the enthalpy change, Delta H, and entropy change, Delta S. Reactions that release energy produce more stable products, and the universe tends toward disorder. Thus, an exothermic reaction with a positive entropy change will always be spontaneous. Mathematically, this relationship can be represented as where Delta G is the change in Gibbs free energy and T is the Kelvin temperature. If Delta G is negative, then the reaction is spontaneous....
CHANGES IN ENTROPY OF UNIVERSE VS SYSTEM. Evaluating Spontaneity Considering both Entropy and Enthalpy 7. In...
CHANGES IN ENTROPY OF UNIVERSE VS SYSTEM. Evaluating Spontaneity Considering both Entropy and Enthalpy 7. In a spontaneous process, which of the following always increases? a. the entropy of the system b. the entropy of the surroundings c. the entropy of the universe d. the entropy of the system and the universe c. the entropy of the system, surroundings and the universe (Hand S refer to the system), a. AH>0 8. Processes are always spontaneous, regardless of temperature, when and...
8.) From the values of delta H and delta S, calculate delta G then predict whether...
8.) From the values of delta H and delta S, calculate delta G then predict whether the following reactions would be spontaneous or not at 25 C. a) Reaction A: delta H= 10.5 kJ/mol, and delta S = 30 J/K mol b) Reaction B: delta H=1.8 kJ/mol, and delta S = -113 J/K mol 9.) Calculate the delta G and K, for the following equilibrium reaction at 25 C: 2H2O(Ⓡ) <-> 2H2(g) + O2(8) delta Gran H2O(x) = -228.6 kJ/mol
To decide whether AgCl should dissolve in water ( spontaneous reaction ) at 25 degrees celcius, the delta H and T delta...
To decide whether AgCl should dissolve in water ( spontaneous reaction ) at 25 degrees celcius, the delta H and T delta S must be used in the Gibbs Free Energy equation to calculate delta G AgCl (s) + H2O (I) -> Ag+ + Cl- + H2O Standard Enthalpies of formation and standard entropies of common compounds substance state AgCl s -127010 96.20 Cl- aq -167080. 56.50 Ag+ aq. 105790. 72.70
Determine the standard entropy change of the universe at 25°C for the reaction NHİ (aq) +...
Determine the standard entropy change of the universe at 25°C for the reaction NHİ (aq) + Cl-(aq) NH, Cl (s) given the following information. Is the reaction spontaneous under standard conditions? Substance Δ AHP(kJ/mol) S° (J/mol K) NH,Cl(s) NH (aq) Cl (aq) -314.4 -132.5 -167.2 94.6 113.4 56.5 +124.6 J/K, yes +26.0 J/K, yes d. a. -26.0 J/K, no b. +49.3 J/K, yes c. -75.3 J/K, no e.
For a given reaction, Delta H = -19.9 kJ/mol and Delta S = -55.5 J/K-mol. Calculate...
For a given reaction, Delta H = -19.9 kJ/mol and Delta S = -55.5 J/K-mol. Calculate the temperature in K where Delta G = 0. Assume that Delta H and Delta S do not vary with temperature. Also, what is the equilibrium constant at that temperature?
DeltaH degree is +23 kJ mol^-1 of phosphine (PH_3) for the reaction Calculate Delta S degree...
DeltaH degree is +23 kJ mol^-1 of phosphine (PH_3) for the reaction Calculate Delta S degree for this reaction. Explain how this information allows you to determine the spontaneity or non-spontaneity of this reaction at any temperature. (S degree for PH_3 is 210 J K^-1 mol^-1.) Do these results indicate anything about the possibility of the existence of phosphine? Explain your answer.
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow...
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow 2 AlCl_3(s) given: 2 Al(s) + 6 HCl(aq) rightarrow 2 AlCl_3(aq) + 3 H_2(g) Delta H = -1049 kJ HCl(g) rightarrow HCl(aq) Delta H = -74.8 kJ H_2(g) + Cl_2(g) rightarrow 2 HCl(g) Delta H = -185 kJ AlCl_3(s) rightarrow AlCl_3(aq) Delta H = -323 kJ
2. Lastly, use the table of thermodynamic functions to compute the AHo and ASo for the reactions in #1. Then using AH° and AS° and your knowledge of the second law, compute which reactions are spontaneous under standard conditions. You must show all your calcualtions. (7pts) Spontaneous ASo ASuniv ΔΗ Reaction 2H2(g) + 02(g) 2H20() CO2(s)-CO2(g) K (aq)+ Cl (aq)- KCI(s) Thermodynamic Properties at 298 K AH AG Substance kJ/mol kJ/mol 3/(mol-K) Ag(s) Ag (aq) AgBr(s) AgCls) Agl(s) Cl:(g) CI(8)...
2Cl(g) = Cl2(g) Calculate the AH, AS and AS universe for this reaction. Determine the spontaneity of the reaction.
Question 5 The spontaneity of a reaction depends both on the enthalpy change, Delta H, and entropy change, Delta S. Reactions that release energy produce more stable products, and the universe tends toward disorder. Thus, an exothermic reaction with a positive entropy change will always be spontaneous. Mathematically, this relationship can be represented as where Delta G is the change in Gibbs free energy and T is the Kelvin temperature. If Delta G is negative, then the reaction is spontaneous....
CHANGES IN ENTROPY OF UNIVERSE VS SYSTEM. Evaluating Spontaneity Considering both Entropy and Enthalpy 7. In a spontaneous process, which of the following always increases? a. the entropy of the system b. the entropy of the surroundings c. the entropy of the universe d. the entropy of the system and the universe c. the entropy of the system, surroundings and the universe (Hand S refer to the system), a. AH>0 8. Processes are always spontaneous, regardless of temperature, when and...
8.) From the values of delta H and delta S, calculate delta G then predict whether the following reactions would be spontaneous or not at 25 C. a) Reaction A: delta H= 10.5 kJ/mol, and delta S = 30 J/K mol b) Reaction B: delta H=1.8 kJ/mol, and delta S = -113 J/K mol 9.) Calculate the delta G and K, for the following equilibrium reaction at 25 C: 2H2O(Ⓡ) <-> 2H2(g) + O2(8) delta Gran H2O(x) = -228.6 kJ/mol
Determine the standard entropy change of the universe at 25°C for the reaction NHİ (aq) + Cl-(aq) NH, Cl (s) given the following information. Is the reaction spontaneous under standard conditions? Substance Δ AHP(kJ/mol) S° (J/mol K) NH,Cl(s) NH (aq) Cl (aq) -314.4 -132.5 -167.2 94.6 113.4 56.5 +124.6 J/K, yes +26.0 J/K, yes d. a. -26.0 J/K, no b. +49.3 J/K, yes c. -75.3 J/K, no e.
For a given reaction, Delta H = -19.9 kJ/mol and Delta S = -55.5 J/K-mol. Calculate the temperature in K where Delta G = 0. Assume that Delta H and Delta S do not vary with temperature. Also, what is the equilibrium constant at that temperature?
DeltaH degree is +23 kJ mol^-1 of phosphine (PH_3) for the reaction Calculate Delta S degree for this reaction. Explain how this information allows you to determine the spontaneity or non-spontaneity of this reaction at any temperature. (S degree for PH_3 is 210 J K^-1 mol^-1.) Do these results indicate anything about the possibility of the existence of phosphine? Explain your answer.
Use Hess's Law to determine Delta H for the reaction 2 Al(s) + 3 Cl_2(g) rightarrow 2 AlCl_3(s) given: 2 Al(s) + 6 HCl(aq) rightarrow 2 AlCl_3(aq) + 3 H_2(g) Delta H = -1049 kJ HCl(g) rightarrow HCl(aq) Delta H = -74.8 kJ H_2(g) + Cl_2(g) rightarrow 2 HCl(g) Delta H = -185 kJ AlCl_3(s) rightarrow AlCl_3(aq) Delta H = -323 kJ
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