Homework Answers
Add Answer to:
- The mechanism for the decomposition of NO2Cl is the following: NO CI+NO+C1 NO_C1+C1_">NO, +C1 a....
The mechanism for the decomposition of NO2Cl
The mechanism for the decomposition of NO2Cl is:k-1<---NO2Cl --->NO2 + Clk1k2NO2Cl + Cl ---> NO2 + Cl2By making a steady-state approximation for [Cl], express the rate of appearance of Cl2in terms of the concentrations of NO2Cl and NO2.
6. The decomposition of gaseous nitryl chloride, NO2Cl, on heating is thought to occur by the...
6. The decomposition of gaseous nitryl chloride, NO2Cl, on heating is thought to occur by the following mechanism: step (1): . Mogl ? NO2 + Cl step (2): CI + O-Cl ? NO2 + Cl2 a. What is the overall reaction? (2 marks) b. Identify any reaction intermediates. (1 mark) c. What is the molecularity of each step? (2 marks) d. Assuming this mechanism is correct, which is the rate-determining step if the experimental rate law is first order in...
33 5 points The thermal decomposition of nitryl chloride (NO2Cl) as shown below, 2NO+2NO2 + Cl2...
33 5 points The thermal decomposition of nitryl chloride (NO2Cl) as shown below, 2NO+2NO2 + Cl2 is thought to occur as follows: NO2Cl + NO2 + CI (slow step) NO2CI+ CI+NO2 + Cl2 (fast step) The rate law derived from the above mechanism would be: O rate = k[NO2Cl] O rate = k[NO2Cl][CI] O rate = k[NO2][Cl] o rate = k[NO2Ci] O rate = k[NO21[Cl2] Previous
1. The following is a proposed mechanism for the gas phase decomposition of nitryl chloride: 2...
1. The following is a proposed mechanism for the gas phase decomposition of nitryl chloride: 2 NO2Cl → 2 NO2 + Cl2. step 1: NO2Cl → NO2+CI step 2: NO2CI+ Cl → NO2 + Cl2 a. (1 pt) Is there an intermediate? If so, what is it? b. (1 pt) Is there a catalyst? If so, what is it? C. (1 pt) Determine the net reaction for the mechanism. d. (2 pt) Use the reaction coordinate diagram below to determine...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Answer Choices: Rate =...
The following is a proposed mechanism for the gas phase decomposition of nitryl chloride. step 1...
The following is a proposed mechanism for the gas phase decomposition of nitryl chloride. step 1 fast: NO2CNO2+CI step 2 slow: NO2CI+CI NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 ...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 + O2 slow; rate determining step Step 2 NO3 + NO2 --> N2O5 fast a. What is the overall reaction? b. Identify the intermediates in the mechanism. c. Write the rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates...
#13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Br2  
#13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Br2 2Br fast Step 2 Br + H2 H2Br fast Step 3 H2Br + Br 2HBr slow a. What is the overall equation? b. Identify the intermediate(s) if any. c. What is the molecularity and the rate law for each step including any reversible steps? d. What is the predicted rate law expression for this reaction. Be sure to only list reactants from the overall equation and...
Please show your work. Thanks! B) The following mechanism has been suggested for the overall reaction...
Please show your work. Thanks!
B) The following mechanism has been suggested for the overall reaction NO2CI -NO2+2C12. k1 Mechanism: 1) NO2CI - NO2 + CI k2 NO2 +Cl2 2) NO2CI+ CI Derive the rate law expression for the production of Cl2 by two methods. a) Derive the rate law assuming step 1 is the rate limiting step. b) Derive the rate law assuming step 2 is the rate limiting step
Suppose the synthesis of ethylene dichloride proceeds by the following mechanism: step rate constant elementary reaction...
Suppose the synthesis of ethylene dichloride proceeds by the following mechanism: step rate constant elementary reaction CH,CH, (g)+ci, (g) → CH,CH,ci* (g)+ciº (9) CH,CH,CI* (g)+C1 (g) → CH,CH,C1, (g) Suppose also kq «k2. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = % 0
6. The decomposition of gaseous nitryl chloride, NO2Cl, on heating is thought to occur by the following mechanism: step (1): . Mogl ? NO2 + Cl step (2): CI + O-Cl ? NO2 + Cl2 a. What is the overall reaction? (2 marks) b. Identify any reaction intermediates. (1 mark) c. What is the molecularity of each step? (2 marks) d. Assuming this mechanism is correct, which is the rate-determining step if the experimental rate law is first order in...
33 5 points The thermal decomposition of nitryl chloride (NO2Cl) as shown below, 2NO+2NO2 + Cl2 is thought to occur as follows: NO2Cl + NO2 + CI (slow step) NO2CI+ CI+NO2 + Cl2 (fast step) The rate law derived from the above mechanism would be: O rate = k[NO2Cl] O rate = k[NO2Cl][CI] O rate = k[NO2][Cl] o rate = k[NO2Ci] O rate = k[NO21[Cl2] Previous
1. The following is a proposed mechanism for the gas phase decomposition of nitryl chloride: 2 NO2Cl → 2 NO2 + Cl2. step 1: NO2Cl → NO2+CI step 2: NO2CI+ Cl → NO2 + Cl2 a. (1 pt) Is there an intermediate? If so, what is it? b. (1 pt) Is there a catalyst? If so, what is it? C. (1 pt) Determine the net reaction for the mechanism. d. (2 pt) Use the reaction coordinate diagram below to determine...
The following is a proposed mechanism for the gas phase decomposition of nitryl chloride. step 1 fast: NO2CNO2+CI step 2 slow: NO2CI+CI NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete...
Please show your work. Thanks!
B) The following mechanism has been suggested for the overall reaction NO2CI -NO2+2C12. k1 Mechanism: 1) NO2CI - NO2 + CI k2 NO2 +Cl2 2) NO2CI+ CI Derive the rate law expression for the production of Cl2 by two methods. a) Derive the rate law assuming step 1 is the rate limiting step. b) Derive the rate law assuming step 2 is the rate limiting step
Suppose the synthesis of ethylene dichloride proceeds by the following mechanism: step rate constant elementary reaction CH,CH, (g)+ci, (g) → CH,CH,ci* (g)+ciº (9) CH,CH,CI* (g)+C1 (g) → CH,CH,C1, (g) Suppose also kq «k2. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = % 0
Most questions answered within 3 hours.
-
4. Without doing any calculations, predict whether the observed
∆T would increase, decrease or remain the...
asked 8 minutes ago -
Based on the range, which of the following sets of scores has
the greatest variability? 3,...
asked 1 hour ago -
Ripples in a pond travel at a velocity of 3 m/s with one peak
passing a...
asked 1 hour ago -
A man stands on the roof of a building of height 13.0 mm and
throws a...
asked 1 hour ago -
The extent to which assets are financed by borrowed funds and
other liabilities is indicated by:...
asked 2 hours ago -
Explain in detail
Germany is the fifth largest economy
explain what goods and services Germany specializes...
asked 2 hours ago -
The density of platinum is 21.45 g/mL. If a cube of platinum
with a mass of...
asked 2 hours ago -
Accounts Receivable
Sales
A/R Posting
Extended Sales Invoice
Packing Slip
Compare invoice to packing slip 2...
asked 2 hours ago -
Michaella, age 23, is a full-time law student and is claimed by
her parents as a...
asked 2 hours ago -
Why are polymers not typically casted into products?
asked 2 hours ago -
When rolling a die 129 times, what is the probability of rolling
a 6 no more...
asked 3 hours ago -
4. A call option currently sells for $7.75. It has a strike
price of $85 and...
asked 2 hours ago