1. The following is a proposed mechanism for the gas phase decomposition of nitryl chloride: 2...
The following is a proposed mechanism for the gas phase decomposition of nitryl chloride. step 1 fast: NO2CNO2+CI step 2 slow: NO2CI+CI NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete...
33 5 points The thermal decomposition of nitryl chloride (NO2Cl) as shown below, 2NO+2NO2 + Cl2 is thought to occur as follows: NO2Cl + NO2 + CI (slow step) NO2CI+ CI+NO2 + Cl2 (fast step) The rate law derived from the above mechanism would be: O rate = k[NO2Cl] O rate = k[NO2Cl][CI] O rate = k[NO2][Cl] o rate = k[NO2Ci] O rate = k[NO21[Cl2] Previous
6. The decomposition of gaseous nitryl chloride, NO2Cl, on heating is thought to occur by the following mechanism: step (1): . Mogl ? NO2 + Cl step (2): CI + O-Cl ? NO2 + Cl2 a. What is the overall reaction? (2 marks) b. Identify any reaction intermediates. (1 mark) c. What is the molecularity of each step? (2 marks) d. Assuming this mechanism is correct, which is the rate-determining step if the experimental rate law is first order in...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Answer Choices: Rate =...
Please show your work. Thanks! B) The following mechanism has been suggested for the overall reaction NO2CI -NO2+2C12. k1 Mechanism: 1) NO2CI - NO2 + CI k2 NO2 +Cl2 2) NO2CI+ CI Derive the rate law expression for the production of Cl2 by two methods. a) Derive the rate law assuming step 1 is the rate limiting step. b) Derive the rate law assuming step 2 is the rate limiting step
A proposed mechanism for the gas phase reaction between nitrogen monoxide and oxygen is as follows: ..... step 1 ..... fast: ...... NO + O2NO3 ..... step 2 ..... slow: .... NO3 + NO 2 NO2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species...
13.6 #3 The following mechanism for the gas phase decomposition of oxygen difluoride is consistent with the observed rate law. .....step 1.....fast:......2 OF2 <-----> O2F4 .....step 2.....slow:....O2F4 -----> O2 + 2 F2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. _____+_____----->_____+_____ (2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank: ________ (3) Complete the rate...
please i need help with all these questions.. thanks so much Use the References to access important values if needed for this question. The activation energy for the gas phase isomerization of cis cyanostyrene is 193 kJ. cis-CH CH CHCN-trans-C H CH CHCN The rate constant at 670 K is 3.54x10-4 /s. The rate constant will be 4.67x10 3 /s at Submit Answer Retry Entire Group 3 more group attempts remaining (References] Use the References to access important values if...
A mechanism for the gas phase reaction of fluorine with chlorine dioxide that is consistent with the observed rate law is: step slow: F2+CIO, FCIO, + F step 2 fast: F+CIO, FCIO, (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank (3) Which species acts as a reaction intermediate? Enter formula....
- The mechanism for the decomposition of NO2Cl is the following: NO CI+NO+C1 NO_C1+C1_">NO, +C1 a. Write the overall reaction. b. Assuming the second step in the mechanism is the rate determining step, write a rate law expression for the appearance of Cl2.