Rate laws are commonly determined using a table of various initial concentrations and initial rates. The experimental data measured for reaction A --> 2 B + C at 25 ◦C are listed in the following table.
[A]0, (M) r (M/s)
0.45, 6.165 × 10−3
0.9, 1.233 × 10−2
1.8, 2.466 × 10−2
3.6 ?
(a) Determine the order of the reaction. Explain why.
(b) Determine the rate constant (including the unit).
(c) Determine the missing rate in the table above. Show your work.
(d) Determine the half-life of this reaction and complete the following table. Show your work.
[A]0 (M) t1/2 (s)
0.45
0.9
1.8
3.6
Rate laws are commonly determined using a table of various initial concentrations and initial rates. The...
For the reaction A+B+C→D+EA+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trials [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.20 0.20 0.20 6.0x10-5 2 0.20 0.20 0.60 1.8×10−4 3 0.40 0.20 0.20 2.4×10−4 4 0.40 0.40 0.20 2.4×10−4 Given the data calculated in Parts A, B, C, and D, determine the initial rate for a reaction that starts with 0.45 M of reagent A and 0.90 M...
For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.30 0.30 0.30 9.0×10−5 2 0.30 0.30 0.90 2.7×10−4 3 0.60 0.30 0.30 3.6×10−4 4 0.60 0.60 0.30 3.6×10−4 What is the value of the rate constant k for this reaction?
For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. What is the reaction order with respect to B? Also, how do you find the value of the rate constant k for this reaction? Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.30 0.30 0.30 9.0×10−5 2 0.30 0.30 0.90 2.7×10−4 3 0.60 0.30 0.30 3.6×10−4 4 0.60 0.60 0.30 3.6×10−4
± Experimental Determination of a Rate Law Part B: Calculate the initial rate for the formation of C at 25 ∘C, if [A]=0.50M and [B]=0.075M. Express your answer to two significant figures and include the appropriate units. Consider the reaction A+2B⇌C whose rate at 25 ∘C was measured using three different sets of initial concentrations as listed in the following table: Trial [A] (M) [B] (M) Rate (M/s) 1 0.50 0.030 9.0×10−3 2 0.50 0.060 1.8×10−2 3 1.00 0.030 3.6×10−2
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For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.40 0.40 0.40 1.2×10−4 2 0.40 0.40 1.20 3.6×10−4 3 0.80 0.40 0.40 4.8×10−4 4 0.80 0.80 0.40 4.8×10−4 Rate law equation The rate of a chemical reaction depends on the concentrations of the reactants. For the general reaction between Aand B, aA+bB⇌cC+dD The dependence of the reaction...
For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.40 0.40 0.40 1.2×10−4 2 0.40 0.40 1.20 3.6×10−4 3 0.80 0.40 0.40 4.8×10−4 4 0.80 0.80 0.40 4.8×10−4 Rate law equation The rate of a chemical reaction depends on the concentrations of the reactants. For the general reaction between A and B, aA+bB⇌cC+dD The dependence of the...
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