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1. Provide a neatly drawn detailed...
10. Provide a detailed mechanism for the following transformation. Be sure to use curved arrows, correct...
10. Provide a detailed mechanism for the following transformation. Be sure to use curved arrows, correct reaction arrows, Show all relevant lone pairs and bonds, formal charges and all intermediates. Think about what your components are and what would happen first. (5 points) HBr Me on me mé Br + Ho Me
7. Provide a detailed me rovide a detailed mechanism for the following transformation. Be sure to...
7. Provide a detailed me rovide a detailed mechanism for the following transformation. Be sure to use curved arrows, Show all relevant lone pairs and bonds, formal charges and all intermediates. Be sure to account for the appropriate stereochemistry. (5 points) NaH (1 equiv), THF Me Me
Draw a detailed, stepwise mechanism to show how the products of this Sy1 reaction form. Clearly draw the structures of...
Draw a detailed, stepwise mechanism to show how the products of this Sy1 reaction form. Clearly draw the structures of all reactive intermediates. Use curved arrows and include all formal charges. (0.7 pts)
Predict the product of the following reaction and draw a detailed step-wise mechanism for the transformation....
Predict the product of the following reaction and draw a
detailed step-wise mechanism for the transformation. Be sure to
show to all intermediates, formal charges, and show the movement of
electrons with curved arrows.
HA (pH 4-5)
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows...
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows to show the movement of electrons. (Hint: Begin by drawing the resonance structure for the reagent over the arrow) from med arrows total) Mecha H2C=N=N O-H OCH3 NEN (gas) 7. (18 points total) Mechanism: Provide a detailed, stepwise mechanism for the following reaction. Use curved arrows to show the movement of electrons. O Me Me
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be...
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be sure to show all steps, intermediates, formal charges, and show the movement of electrons with curved arrows. You do not need to draw transition states. H2SO4 H20 ?? The hydration of alkynes can also occur under aqueous acidic conditions however, instead of forming the alcohol, a ketone is formed. Draw the detailed stepwise mechanism for the conversion of the alkyne to the ketone (one...
2. Draw a detailed, stepwise mechanism to show how the products of this reaction form. Clearly...
2. Draw a detailed, stepwise mechanism to show how the products of this reaction form. Clearly draw the structures of all reactive intermediates. Use curved arrows and include all formal charges. Hint: both Sy1 and SN2 chemistry is required. (2 pts) Oor 21Oo..mo
3. Provide the missing reagents for each transformation below. + +4-3 4. Provide a detailed mechanism...
3. Provide the missing reagents for each transformation below. + +4-3 4. Provide a detailed mechanism for each part of the Hell-Volhard-Zelinsky Reaction below. Note that this reaction is covered in our textbook (among many sections) and that the reaction conditions are modified slightly. Be sure to account for this and be as detailed in every step as possible. Do not create reagents that are not made logically in the pathway (no HBr essentially so it's a "neutral" pathway). Include...
5. [5 pts] Use curved-arrow notation to write out a detailed, step-wise mechanism for the reaction...
5. [5 pts] Use curved-arrow notation to write out a detailed, step-wise mechanism for the reaction listed below. Be sure to (a) include all of your lone pairs, (b) include all formal charges, (c) draw your arrows neatly and precisely, and (d) enclose intermediates within square brackets. If you get stuck, number the atoms of your reactant and the corresponding atoms in your product to help recognize what bonds are made and broken! HBr r Mechanism: +4 +
Provide the product of this reaction and draw a detailed step-by-step mechanism. Make sure to use...
Provide the product of this reaction and draw a detailed
step-by-step mechanism. Make sure to use the curved arrows
correctly and indicate all relevant unshared electron pairs and all
formal charges.
Thank you!
o cat. H20+ НО, MgSO4 anhydrous OH
10. Provide a detailed mechanism for the following transformation. Be sure to use curved arrows, correct reaction arrows, Show all relevant lone pairs and bonds, formal charges and all intermediates. Think about what your components are and what would happen first. (5 points) HBr Me on me mé Br + Ho Me
7. Provide a detailed me rovide a detailed mechanism for the following transformation. Be sure to use curved arrows, Show all relevant lone pairs and bonds, formal charges and all intermediates. Be sure to account for the appropriate stereochemistry. (5 points) NaH (1 equiv), THF Me Me
Draw a detailed, stepwise mechanism to show how the products of this Sy1 reaction form. Clearly draw the structures of all reactive intermediates. Use curved arrows and include all formal charges. (0.7 pts)
Predict the product of the following reaction and draw a
detailed step-wise mechanism for the transformation. Be sure to
show to all intermediates, formal charges, and show the movement of
electrons with curved arrows.
HA (pH 4-5)
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows to show the movement of electrons. (Hint: Begin by drawing the resonance structure for the reagent over the arrow) from med arrows total) Mecha H2C=N=N O-H OCH3 NEN (gas) 7. (18 points total) Mechanism: Provide a detailed, stepwise mechanism for the following reaction. Use curved arrows to show the movement of electrons. O Me Me
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be sure to show all steps, intermediates, formal charges, and show the movement of electrons with curved arrows. You do not need to draw transition states. H2SO4 H20 ?? The hydration of alkynes can also occur under aqueous acidic conditions however, instead of forming the alcohol, a ketone is formed. Draw the detailed stepwise mechanism for the conversion of the alkyne to the ketone (one...
2. Draw a detailed, stepwise mechanism to show how the products of this reaction form. Clearly draw the structures of all reactive intermediates. Use curved arrows and include all formal charges. Hint: both Sy1 and SN2 chemistry is required. (2 pts) Oor 21Oo..mo
3. Provide the missing reagents for each transformation below. + +4-3 4. Provide a detailed mechanism for each part of the Hell-Volhard-Zelinsky Reaction below. Note that this reaction is covered in our textbook (among many sections) and that the reaction conditions are modified slightly. Be sure to account for this and be as detailed in every step as possible. Do not create reagents that are not made logically in the pathway (no HBr essentially so it's a "neutral" pathway). Include...
5. [5 pts] Use curved-arrow notation to write out a detailed, step-wise mechanism for the reaction listed below. Be sure to (a) include all of your lone pairs, (b) include all formal charges, (c) draw your arrows neatly and precisely, and (d) enclose intermediates within square brackets. If you get stuck, number the atoms of your reactant and the corresponding atoms in your product to help recognize what bonds are made and broken! HBr r Mechanism: +4 +
Provide the product of this reaction and draw a detailed
step-by-step mechanism. Make sure to use the curved arrows
correctly and indicate all relevant unshared electron pairs and all
formal charges.
Thank you!
o cat. H20+ НО, MgSO4 anhydrous OH
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