Homework Answers
Solution:
Correct option A) the ddx orbital is 0.4 delta above the berycentre.
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In a tetrahedral complex, (A) the dxy orbital is 0.4 delta above the barycentre (B) the...
2 A molecular orbital diagram for a tetrahedral transition metal complex is shown below. Show how...
2 A molecular orbital diagram for a tetrahedral transition metal complex is shown below. Show how the electrons occupy the molecular orbitals in the diagram for each complex (a)-(g). Why are low-spin, tetrahedral transition metal complexes rare? (a) [MnBra (d) [CuCl (b) [CrC (e) [NICI (c) IMnO (OsO (g) MoF ΔΤ e+t a+t 4L a (b) Identify the bonding, anti-bonding, and non-bonding orbitals in this diagram. M
The complex ion [VBr4l has a tetrahedral structure. How many d electrons are on the V?...
The complex ion [VBr4l has a tetrahedral structure. How many d electrons are on the V? 2 dxy dyz dxz A: How many electrons total are in the set of e orbitals? How many electrons total are in the set of t2 orbitals?
If the delta of a European call option is 0.4, calculate the delta of an equivalent...
If the delta of a European call option is 0.4, calculate the delta of an equivalent European put option 0.6 0.4 -0.4 -0.6
10. Tetrahedral complexes of Co2+ are quite common. Use a d-orbital splitting diagram to rationalize the...
10. Tetrahedral complexes of Co2+ are quite common. Use a d-orbital splitting diagram to rationalize the stability of Co+ tetrahedral complex ions. 11. [Ni(H2O)6JC12 is green whereas Ni(NH3%)Cb is purple. Explain this difference in color? What would you expect the magnetic properties of each complex to be? Explain briefly
i) Consider the crystal field diagram for a tetrahedral complex and the relative d orbital configuration....
i) Consider the crystal field diagram for a tetrahedral complex and the relative d orbital configuration. Show the purple colour of MnO4 - cannot be from d-d transitions and briefly explain your answer. ii) Draw a simplified molecular orbital diagram (i.e. like those used for ligand field theory in lectures) to show the possible origin of the transition responsible for the purple colour of an aqueous KMnO4 solution. iii) MnO4 - ions actually have two intense transitions, one at 541...
The complex ion Fe(NH3)42- is paramagnetic. The shape of this complex is a) octahedral b) tetrahedral...
The complex ion Fe(NH3)42- is paramagnetic. The shape of this complex is a) octahedral b) tetrahedral c) Square planar
Which orbital diagram represents the electron configuration of high-spin octahedral complex [Cr(NH3)6]2+? Select the cor...
Which orbital diagram represents the electron configuration of
high-spin octahedral complex [Cr(NH3)6]2+?
Select the correct
answer below:
d₂2 dx?_v2 sp p гр d₂2 dx² - y2 ep "p 2ър прес d₂2 dx² - y2 ep "p 2ър də də - у dxy dyz dyz
PLEASE ANSWER ALL QUESTIONS THANK YOU 17. Identify the orbital. A) pz orbital B) dxy orbital...
PLEASE ANSWER ALL QUESTIONS
THANK YOU
17. Identify the orbital. A) pz orbital B) dxy orbital C) px orbital D) dyz orbital E) py orbital 18.) Identify the orbital. .y A) d orbital B) dry orbital C) px orbital D) forbital E) py orbital 19.) Identify the orbital. A) d orbital B) dxy orbital C) px orbital D) forbital E) /y orbital 20. Which of the following transitions (in a hydrogen atom) represent emission of the longest wavelength photon? C)...
1. Consider the following 4-coordinate complexes. For each of these: a. Do you expect the complex...
1. Consider the following 4-coordinate complexes. For each of these: a. Do you expect the complex to be tetrahedral or square planar? Why? b. Draw an electron-orbital occupancy diagram for the d orbitals. c. If the complex is tetrahedral, calculate an LFSE in units of 4. Note that, for tetrahedral complexes, e orbitals are -3/54 relative to the average d-orbital energy, and t, orbitals are +2/54 relative to the average d-orbital energy. Ni(CO). [Rh(PPh.) (CO), [Rec] [PdCl.Bry] 2. Which of...
3.) Consider the arrangement of ligand in a tetrahedral metal complex (MLA), and the resulting crystal...
3.) Consider the arrangement of ligand in a tetrahedral metal complex (MLA), and the resulting crystal field splitting that was discussed in class. What would you expect the crystal field splitting pattern to look like for a cubic complex ML8, which has 8 ligands at the corners of a cube? Draw the orbital splitting diagram with all orbitals labelled. Give your rationale for the pattern. How would you expect the size of the splitting to compare to that for ML4....
2 A molecular orbital diagram for a tetrahedral transition metal complex is shown below. Show how the electrons occupy the molecular orbitals in the diagram for each complex (a)-(g). Why are low-spin, tetrahedral transition metal complexes rare? (a) [MnBra (d) [CuCl (b) [CrC (e) [NICI (c) IMnO (OsO (g) MoF ΔΤ e+t a+t 4L a (b) Identify the bonding, anti-bonding, and non-bonding orbitals in this diagram. M
The complex ion [VBr4l has a tetrahedral structure. How many d electrons are on the V? 2 dxy dyz dxz A: How many electrons total are in the set of e orbitals? How many electrons total are in the set of t2 orbitals?
If the delta of a European call option is 0.4, calculate the delta of an equivalent European put option 0.6 0.4 -0.4 -0.6
10. Tetrahedral complexes of Co2+ are quite common. Use a d-orbital splitting diagram to rationalize the stability of Co+ tetrahedral complex ions. 11. [Ni(H2O)6JC12 is green whereas Ni(NH3%)Cb is purple. Explain this difference in color? What would you expect the magnetic properties of each complex to be? Explain briefly
i) Consider the crystal field diagram for a tetrahedral complex and the relative d orbital configuration. Show the purple colour of MnO4 - cannot be from d-d transitions and briefly explain your answer. ii) Draw a simplified molecular orbital diagram (i.e. like those used for ligand field theory in lectures) to show the possible origin of the transition responsible for the purple colour of an aqueous KMnO4 solution. iii) MnO4 - ions actually have two intense transitions, one at 541...
Which orbital diagram represents the electron configuration of
high-spin octahedral complex [Cr(NH3)6]2+?
Select the correct
answer below:
d₂2 dx?_v2 sp p гр d₂2 dx² - y2 ep "p 2ър прес d₂2 dx² - y2 ep "p 2ър də də - у dxy dyz dyz
PLEASE ANSWER ALL QUESTIONS
THANK YOU
17. Identify the orbital. A) pz orbital B) dxy orbital C) px orbital D) dyz orbital E) py orbital 18.) Identify the orbital. .y A) d orbital B) dry orbital C) px orbital D) forbital E) py orbital 19.) Identify the orbital. A) d orbital B) dxy orbital C) px orbital D) forbital E) /y orbital 20. Which of the following transitions (in a hydrogen atom) represent emission of the longest wavelength photon? C)...
1. Consider the following 4-coordinate complexes. For each of these: a. Do you expect the complex to be tetrahedral or square planar? Why? b. Draw an electron-orbital occupancy diagram for the d orbitals. c. If the complex is tetrahedral, calculate an LFSE in units of 4. Note that, for tetrahedral complexes, e orbitals are -3/54 relative to the average d-orbital energy, and t, orbitals are +2/54 relative to the average d-orbital energy. Ni(CO). [Rh(PPh.) (CO), [Rec] [PdCl.Bry] 2. Which of...
3.) Consider the arrangement of ligand in a tetrahedral metal complex (MLA), and the resulting crystal field splitting that was discussed in class. What would you expect the crystal field splitting pattern to look like for a cubic complex ML8, which has 8 ligands at the corners of a cube? Draw the orbital splitting diagram with all orbitals labelled. Give your rationale for the pattern. How would you expect the size of the splitting to compare to that for ML4....
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