For CO and XeF,
Order of MO is given below.
Electrons are filled from low energy to high energy.
For , CO,
There (6+8) = 14 electrons.
These will be filled as given electronic configuration:
XeF+ have shorter bond length.
6. This question concerns heteronuclear diatomic molecules (a) Give the ground state configurations for (i) CO...
Question 13 Molecular Orbitals for Heteronuclear Diatomic Molecules Using the above molecular orbital diagram for CO, determine the bond order and magnetic properties. Assuming that it has similar molecular orbital energies to those of carbon monoxide, deduce the bond order of the NO+ ion.
5. Some heteronuclear d energy levels like th heteronuclear diatomic molecules have energy levels like those in Figure 3, while others to ey levels like those in Figure 4 (e.g., CN, CN-, and CNT). Write the molecular orbital electron configurations for these three species. For example electron configuration for H, is (015) b. Arrange these species in increasing bond order, increasing bond length, and increasing bond energy
give the ground-state Russell-Saunders terms for the following electronic configurations (a) Give the ground-state Russell-Saunders terms for the following electronic configurations: i. (3d) ii. (41) (Hint: S, P, D, F, G, H, I... for L=0, 1, 2, 3, 4, 5, 6 ...) (4 marks each, total 8 marks) (b) Determine ALL the atomic term symbols for the electronic configuration p3. Calculate the number of microstates and deduce the ground state term using Hund's rule. (10 marks)
Give the ground-state electron configurations of (a) Li2, (b) CO, (c) NO, and (d) CN- .
1000 diatomic molecules with vibrational state described by N molecules in the ground vibrational state O molecules in the lowest potential Total Energy Potential Energy state M molecules in an excited vibrational states P molecules in an excited potential energy states Schematic of Energy Eigenfunctions and the 1. Consider a sample of 1000 identically prepared diatomic molecules, each of which can be Potential Energy function of the Harmonic Oscillator described by the ground state of the Harmonic oscillator: Ψ-ψ。. If...
(a) Use the noble-gas notation and write the ground-state electronic configurations of the following ions: (i) S2- (ii) Sn4+ (iii) Mn2+ (b) Write the equation representing the 2nd ionization energy for Co. (c) The electron affinity of Cs is 45 kJ/mol. Write the equation for which this is the energy change. (d) Each of the following oxides reacts with water to produce an acid or a base, depending on whether the oxide is an acidic or a basic oxide. Give...
6. (like Ex. E9D.1) Give the ground state electron configurations and draw the molecular orbital energy level diagrams (like Fig. 9D.3) of CO and NO. Use atomic ionization energies to judge which orbitals are higher or lower. (Some were provided in Note Sheet 15.)
1. MO theory for homonuclear diatomic molecules (a) Determine the ground state electron configuration of the C2 anion. (1 points) (b) Calculate the bond order of the C2 anion. Is its dissociation energy greater or smaller than that of C2? Is its bond length greater or smaller than that of C2-(3 points) (c) Use MO theory to explain why the dissociation energy of the N is less than that of N2, but the dissociation energy of O is greater than...
Consider a gas of diatomic molecules (moment of inertia I) at an absolute temperature T. If Eg is a ground-state energy and Eex is the energy of an excited state, then the Maxwell-Boltzmann distribution predicts that the ratio of the numbers of molecules in the two states is nexng=e−(Eex−Eg)/kT. The ratio of the number of molecules in the lth rotational energy level to the number of molecules in the ground-state (l=0) rotational level is nln0=(2l+1)e−l(l+1)ℏ2/2IkT. The moment of inertia of...
Rigid rotor question Hi, I understand how to do rigid rotor questions for diatomic molecules, but I was wondering what if the molecule is linear CO2? What is the rotational first excited state energy of linear molecule CO2? Not sure if I have to just solve the energy for C=O like as a diatomic molecule, and then multiply by two...