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6. Benzimidazole is an important organic base that comprises an important portion of vitamin B12. Its...
For the portion of the procedure shown below, create a flow chart for the acid-base extraction...
For the portion of the procedure shown below, create a
flow chart for the acid-base extraction at the end of the Grignard
Reaction. Start your flow chart with the crude reaction (see below)
mixture before addition of HCl and continue it until the product is
recovered. Depict the desired organic product, in its correct form
at each step of the procedure.
Crude reaction mixture procedure for reference: To
the flask add Mg turnings (120 mg, 4.94 mmol) to the flask...
1. A hydrogen atom in the organic base pyridine, CsHsN, can be substituted by various atoms...
1. A hydrogen atom in the organic base pyridine, CsHsN, can be substituted by various atoms or groups to give XCsH4N, where X is an atom such as Cl or a group such as CH3. The following table gives K, values for the conjugate acids of a variety of substituted pyridines. Atom or Group X (aq) + HCl(aq) → (aq) + Cl-(aq) NO K, of Conjugate Acid 5.9 x 10-2 1.5 x 10-4 6.8 x 10-6 1.0 x 10-6 н....
Succinic acid is a weak organic acid with the structure shown below and pKg = 4.21...
Succinic acid is a weak organic acid with the structure shown below and pKg = 4.21 for the first proton to be removed. If you wanted to make a buffer at pH = 3.95 using 0.194 M succinic acid and its conjugate base, what concentration of monosodium succinate is required in the final solution? Succinic acid: HO. Answer:
1. Aniline is a weak organic base with the formula C6H5NH2. The anilinium ion has the...
1. Aniline is a weak organic base with the formula C6H5NH2. The anilinium ion has the formula C6H5NH3+ and its Ka = 2.3 x 10¯5. a) write the chemical reaction showing the hydrolysis of anilinium ion. b) calculate the pH of a 0.0400 M solution of anilinium ion. 2.The Ksp of Sn3(BO3)4 is 6.128 x 10¯12. Determine the molar solubility. 3. The Ksp for CuCrO4 is 3.6 x 10-6. What is the molarity of a saturated solution of CuCrO4? 4....
Critical Skills #9 (Acid-Base Equilibria) Due: 6 pm Monday March 30 upload to Gradescope Class time:...
Critical Skills #9 (Acid-Base Equilibria) Due: 6 pm Monday March 30 upload to Gradescope Class time: 9:30 pH = 11:00 (from back of page) 2:00 1. Consider the conjugate acid-base pair NH' and NH, a. Write the acid dissociation (lonization) reaction for NHA' in water. Hint: NHU (aq) + HOS Label each conjugate acid-base pair. ? 6. Write the expression for equilibrium constant for this reaction ( ?) c. Write the base dissociation (lonization) reaction for NH, in water. Hint:...
i want answer to all questions please Answer: 29) Consider the following generalized buffer solution equilibrium: When a small amount of a strong base such as sodium hydroxide is added to the so...
i want answer to all questions please
Answer: 29) Consider the following generalized buffer solution equilibrium: When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? A) BH B)H C) HO D)B E None of the species would increase in concentration. Answer: ( 30) What is true about a solution whose pH is less than 7 at 25°C? A) It has...
a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction?...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice...
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is...
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is to learn how to use a separatory funnel to extract a single component away from other compounds in solution. To do so, we will apply the principles of solubility and acid-base behavior you’re seeing in class. One of the compounds is neutral in the acid-base sense. It has no ability to either donate or accept a proton from an aqueous solution, and will remain...
Please help and show all work! 7. Ibuprofen is the active ingredient of the over-the-counter painkiller...
Please help and show all work!
7. Ibuprofen is the active ingredient of the over-the-counter painkiller Advil. Its structure is shown below. Like other non-steroidal anti-inflammatory drugs, it works by inhibiting the synthesis of prostaglandins involved in the inflammation, pain, and fever pathway of the body. What is the Ka of ibuprofen if a 0.55 M aqueous solution of ibuprofen has a pH of 2.58 at 25°C? OH A. 1.45 x 10-3 B. 1.26 x 10-5 C. 7.31 x 10-7...
a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction?...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
c) Why did we have to use hot ethanol for the
recrystallization?
d) Why did we have to cool the...
For the portion of the procedure shown below, create a
flow chart for the acid-base extraction at the end of the Grignard
Reaction. Start your flow chart with the crude reaction (see below)
mixture before addition of HCl and continue it until the product is
recovered. Depict the desired organic product, in its correct form
at each step of the procedure.
Crude reaction mixture procedure for reference: To
the flask add Mg turnings (120 mg, 4.94 mmol) to the flask...
1. A hydrogen atom in the organic base pyridine, CsHsN, can be substituted by various atoms or groups to give XCsH4N, where X is an atom such as Cl or a group such as CH3. The following table gives K, values for the conjugate acids of a variety of substituted pyridines. Atom or Group X (aq) + HCl(aq) → (aq) + Cl-(aq) NO K, of Conjugate Acid 5.9 x 10-2 1.5 x 10-4 6.8 x 10-6 1.0 x 10-6 н....
Succinic acid is a weak organic acid with the structure shown below and pKg = 4.21 for the first proton to be removed. If you wanted to make a buffer at pH = 3.95 using 0.194 M succinic acid and its conjugate base, what concentration of monosodium succinate is required in the final solution? Succinic acid: HO. Answer:
Critical Skills #9 (Acid-Base Equilibria) Due: 6 pm Monday March 30 upload to Gradescope Class time: 9:30 pH = 11:00 (from back of page) 2:00 1. Consider the conjugate acid-base pair NH' and NH, a. Write the acid dissociation (lonization) reaction for NHA' in water. Hint: NHU (aq) + HOS Label each conjugate acid-base pair. ? 6. Write the expression for equilibrium constant for this reaction ( ?) c. Write the base dissociation (lonization) reaction for NH, in water. Hint:...
i want answer to all questions please
Answer: 29) Consider the following generalized buffer solution equilibrium: When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? A) BH B)H C) HO D)B E None of the species would increase in concentration. Answer: ( 30) What is true about a solution whose pH is less than 7 at 25°C? A) It has...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice...
Please help and show all work!
7. Ibuprofen is the active ingredient of the over-the-counter painkiller Advil. Its structure is shown below. Like other non-steroidal anti-inflammatory drugs, it works by inhibiting the synthesis of prostaglandins involved in the inflammation, pain, and fever pathway of the body. What is the Ka of ibuprofen if a 0.55 M aqueous solution of ibuprofen has a pH of 2.58 at 25°C? OH A. 1.45 x 10-3 B. 1.26 x 10-5 C. 7.31 x 10-7...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
c) Why did we have to use hot ethanol for the
recrystallization?
d) Why did we have to cool the...
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