Given cyclohexane in a chair conformation, substitute two of the H labels with Br to construct...
Given cyclohexane in a chair conformation, substitute two of the H labels with bromine and chlorine to construct the more stable conformation of cis-1-bromo-3-chlorocyclohexane. Use the numbering provided on the ring.
Given cyclohexane in a chair conformation, substitute two of the H labels with methyl and propyl to construct the more stable conformation of cis-1-methyl-2-propylcyclohexane. Use the numbering provided on the ring.
Cyclohexane: 1.Make a boat conformation. 2.Then a chair conformation In which case are the C-H bonds on neighboring carbons eclipsing the most? 3. In which case do the H atoms on C1 and C4 approach each other most closely? 4. Based on what you saw above, which will be the most stable conformation of cyclohexane? Draw both conformations
1. Now construct cis-1,2-dimethylcyclohexane in the chair conformation and draw it. Perform the ring flip and draw that conformation. Which of the two conformations is preferred? This compound is meso, find the conformation that accounts for this? 2. Construct and draw trans-1-ethyl-2-methylcyclohexane in the chair conformation. Perform the ring flip and draw that conformation. Which conformation is preferred/most stable? Why? Construct and draw the cis isomer in the most stable chair conformation. Perform the ring flip and draw that conformation....
38. Provide the correct hexagonal conformation or Ring-flipped chair conformations for the following cyclohexane (as parent chain) compounds. Then circle the more stable chair conformation. Flat Hexagon structure Chair conformation A Chair conformation B OH "CH₃ Br CH₃
38. Provide the correct hexagonal conformation or Ring-flipped chair conformations for the following cyclohexane (as parent chain) compounds. Then circle the more stable chair conformation. Flat Hexagon structure Chair conformation A Chair conformation B CH₃ Br I CH₃ oh
with explanation
1) Draw a chair conformation of cyclohexane. Then, draw and level properly all axial and equatorial positions on chair form of cyclohexane. 2) Draw chair, half-chair and boat conformations of ethyl cyclohexane and draw an energy diagram to explain their relative stability: 3) Draw two possible chair conformations for each of the mono-substituted cyclohexanes and determine their relative stability with proper explanation. OH 4) Draw two possible chair conformations for each of the di-substituted cyclohexanes and determine their...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
Given the planar trisubstituted cyclohexane below, fill in all boxes (with H, Cl or Br) to complete the two possible cyclohexane chair conformations. Which is the more stable conformer?
3. (10 pts) For each cyclohexane, draw both chair conformations and circle the conformation that is more stable (use the relative size of each substituent to determine which has more 1,3-diaxial strain) S-Bu NH2 t-Bu /25 pts