If the delta G' value for an isomerization reaction, A --> A' is 8.0 kJ/mole at 37 degrees C
1)
a)Given Data :
G = 8000 J/mol
R = 8.314 J/mol K
T = 37 C = 310 K
G = -RTlnK
lnK = - 8000/ 8.314 * 310 = -3.1039
K = 0.0448 = 0.045
K, equillibrium constant is nothing but ratio of concentration of products to concentration of reactants. So we have,
K = [A']/[A] = 0.045
b) [A'] becomes 1/50 times its value in the second case. K the becomes,
K = {[A']/50}/[A] = 0.045/50 = 0.0009
G = -RTlnK
= - 8.314 * 310 * ln(0.0009)
= 18075.18 J/mol = 18.075 KJ/mol
If the delta G' value for an isomerization reaction, A --> A' is 8.0 kJ/mole at...
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