Question

1. What is the major product for the following reaction?What is the major product for the following reaction? Nal acetone (solvent) 110 I I ID IV III and IV III O land II II

2. What is the major product for the following reaction?What is the major product for the following reaction? 3 Cl2, H20 OH CI CI -OH None of these choices. OH + enantiomer CI Схон

3. What is the major product for the following reaction? a. O3, CH2Cl2, -78°C b. Mezs in OH + enantiomer OH *** OH HO iy I

4. Which reagent or test could be used to distinguish between 3-methyl-2-octene and 3-methyloctane?

Ethanol

Br2/CCl4

Sodium hydroxide aqueous solution

Two of these choices.

All of these choices.

5. Which of the following reagents give the highest yield for conversion of 2-bromopentane to 1-pentene?

KOH/H2O

KOH/CH3OH

(CH3)3COK/(CH3)3COH

CH3ONa/CH3OH

CH3CH2ONa/CH3CH2OH

6. What is the major product of the following reaction sequence? -Br 1. EtON, EtOH, heat 2a. Hg(OAC)2, H20 26. NaBH4, OH An equa

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Answer #1

For Question 1 Answer is D (II ) , it is an example of SN2 reaction, so inversion in configuration will take place.

For Question 2 Answer is C (None of choices) because in this reaction OH and CH2Cl will attch on same carbon of cyclopentane.

For Question 3 Answer is A , it is an example of Ozonolysis reaction , double bond will be cleaved and 1,6 dicarbonyl will be formed.

For Question 4 Answer is B (Br2/CCl4) alkene will react with bromine but and will decolourise it, but will not decolorise with alkane.

For Question 5 Answer is C ( (CH3)3COK/(CH3)3COH ), it is a bulky base and will form terminal alkene.

For Question 6 Answer is BBr Etona Etoh Higfone), H2O Naghy OH

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