give the product(s) for each of the reactions and choose any two that draw/write the mechanism...
The following questions describe a few samples. Give the produ (2 points each). Also, choose (15 points) olve sequences of aldol, Claisen, Michael, and Mannich reactions. ct(s) for each of the following reactions any two to write/draw mechanisms for the transformation (3 points/each) C2HsO2C 1) NaOC2H5 2) H30+ & heat1911803 C6Hs C2HsO2C C2Hs02C 2 1) NaOC2Hs& heat C7H1003 C2HsO20 2人、.co2C2H5 1) NaoCzHs & heat 2) H30*, 0 oc +CH2-0 C13H18Og +2 CO2C2Hs 1) Na0C2Hs 8 heat 4 C7H406 CO2C2Hs 2)...
Many useful synthetic produces involve sequences of aldol, Claisen, Michael, and Mannich reactions. The following questions describe a few samples. Give the product(s) for each of the following reactions. Also, choose any two to write/draw mechanisms for the transformations. 1) Na。CzHs & heat 2) H30+, 0 °C C13H1805 2 co2C2Hs 2) N3OCzHs & heat cyH406 C가406 人+ 4 CO2C2Hs 2) H30 1) Na。CzHs & heat 2) H30+, 0 °C C13H1805 2 co2C2Hs 2) N3OCzHs & heat cyH406 C가406 人+ 4...
Predict the structure of the products of the following reactions C2H9O2C CH2 1) NaOC2Hs C19H18O3 1 CaHs CHs 2) H30 & heat C2HtsO2c C2H502C. 1) NaOC2Hs & heat CH2 2 co2CaHs 2) H30 & heat C7H1003 2 C2H502C 1) NaOC2Hs & heat C13H1805 .CO2C2Hs 2 +CH2-O 3 2) H30, 0 °C 1) NaOC2Hs & heat CO2C2H5 2 C7H4O6 4 2) H30 CO2C2HS C19H21NO +2 CEH5CHONH4OAC C2Hg02C 1) aq. NaHCO3 2) Ha0 & heat c o CaHgO2C- C12H1602 +2 Predict the...
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a heat H1003 2 0 Co2C2Hs CH2-O 3 2 2 Co:CHs1) NaoCHts & heat +2 2) H3O & heat Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a...
1. Give a detailed mechanism for each of the following reactions. 2. Classify each of the following reactions as an Aldo condensation, a Claisen condensation, Dieckmann condensation, or Michael reaction 1. Give a detailed mechanism for each of the following reactions. 2. Classify each of the following reactions as an Aldo condensation, a Claisen condensation, Dieckmann condensation, or Michael reaction. & then H30+ hale ch CHO CHO 1. ETON, ETOH 2. H307 Room temperature OH CO2Et CO2Et 1. Catalytic NaOEt...
Give the organic products of each of the following reactions and indicate the major product where appropriate. Give the organic products of each of the following reactions and indicate tne major product where appropriate. Write your answers on these sheets. NO2 Ö T ise Hotels omosha BF3/HF C(CH3)3 + (CH3)2C=CH2 - 1) AICI: 2) HCl(aq), Zn(Hg) ON + OH- 1) NaHCO3 2) H30+
4. Give the major organic product(s) for each of the following reactions or sequences of reactions. H Br 1. N.CN 2. NaOH,H,O, heat 3.H30 Ind o do CH,COOH 1. LiAlH, THF, heat 2.H,0 HO CH Br 1. NaCN, acetone 2.H30, heat h ome couco C:03, H30* он
1. Give a detailed mechanism for each of the following reactions, 2. Classify each of the following reactions as an Aldo condensation, a Claisen condensation, Dieckmann condensation, or Michael reaction. CO2Et CO,Et 1. Catalytic NaOet 2. Hz0* COEt
Select two reactions and give the major product and suggest a plausable mechanism VI. SELECT TWO REACTIONS: Give the major product and suggest a plausible mechanism. (Show your work on the next two pages). (20 pts) 10: 1. CH3Li 2. H30* Brz THF NH3 HCI H-C=C-CH2-CH3 H30Ⓡ
Part I – Reactions Draw the expected major product(s) or required reagent(s) for each of the following reactions. Part 1 - Reactions (20 marks) Draw the expected major product(s) or required reagent(s) for each of the following reactions. Question Answer 1. MgBr 1. CH3CN 2. H30* 2. OH HT ОН 3. Br PPh3 1. BULI 2. CH20 CI (1 mole) ОН 5. 1. LDA ? (directed aldol condensation) 2. CH3CHO 6. HO H (cat) OH ? (cyclic anhydride) . (-H20)...