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Give a detailed mechanism for each of the following reactions.
2. Classify each of the...
1. Give a detailed mechanism for each of the following reactions, 2. Classify each of the...
1. Give a detailed mechanism for each of the following reactions, 2. Classify each of the following reactions as an Aldo condensation, a Claisen condensation, Dieckmann condensation, or Michael reaction. CO2Et CO,Et 1. Catalytic NaOet 2. Hz0* COEt
Need Help. Will Rate If Complete. 1) NaoEt, EtOH Br 2) O 3) H30+ / A....
Need Help. Will Rate If Complete.
1) NaoEt, EtOH Br 2) O 3) H30+ / A. 1) NaoEt, EtOH (s) ar 2) Y Br 3) Hz0+ / A 1) NaOme/MeOH ~ Br OMe 3) Hz0+/A. 1) NaOEt, EtOH 2) V Br 3) NaOEt, EtOH COOEt 5) H30+/A Robinson Annulation NaoEt, EtOH/A come lui OMe 28- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen...
8. Draw a detailed arrow pushing mechanism for the following transformation. You must show arrows for...
8. Draw a detailed arrow pushing mechanism for the following transformation. You must show arrows for every step, writing statements like “proton transfer” without showing the arrows for that step is not an acceptable answer. 1. NaOEt, EtOH لا ملہ ان ام Et 2. Hz0+, Heat
1. Provide the detailed mechanism of the aldol condensation reaction between 2 mols of benzaldehyde and...
1. Provide the detailed mechanism of the aldol condensation reaction between 2 mols of benzaldehyde and 1 mol of acetone under basic conditions. Show all intermediates and steps for full credit. There are 10 steps to the complete mechanism. (2 pts for each step) 2. Give the products for the following aldol reactions. (5 points each) مل OH H 2. н 3. OH ܘܐ OH o 5. ОН" -CHO 6. OH
1. Provide the structure of the product (an acetal) in box and a detailed mechanism for...
1. Provide the structure of the product (an acetal) in box and a detailed mechanism for the entire transformation (15 points): acetal: inoi Ho Mechanism 2. Provide the starting material AND reagents you would use to synthesize the following product by a Dieckmann condensation. Also draw a detailed mechanism for this transformation (15 points): Mechanism: 3. Provide the products of each step in the boxes provided and draw a detailed mechanism for each transformation (20 points): step 1 step 2...
(b) For TWO of the following reactions provide a mechanism that explains the product shown and...
(b) For TWO of the following reactions provide a mechanism that explains the product shown and explain any regiochemical control that has occurred in its formation. [2 x 5 marks] EtO2C LCOMEt CO2Et NaOEt mwag mo (i) NaOEt, Ph Br (ii) 0 1 Eto V 0 L oEt HO (ii) aqueous acid, heat EtO2 CO2Et NaOEt EtO2C CO2Et
give the product(s) for each of the reactions and choose any two that draw/write the mechanism...
give the product(s) for each of the reactions and choose any
two that draw/write the mechanism for the transformation
Many useful synthetic produces involve sequences of aldol. Claisen, Michael, and Mannich reactions. The following questions describe a few samples. Give the product(s) for each of the following reactions (2 points each). Also, choose any two to write/draw mechanisms for the transformation (3 points/each) (15 points) 1) NaOC2Hs 2) H30 &heat 1 CeHs C2HsO2C 1) NaOC2Hs & heat co22Hs 2)heat 2...
Provide a step-by-step mechanism to account for the product of each of the following reactions. Show...
Provide a step-by-step mechanism to account for the product of
each of the following reactions. Show the structure of each of the
intermediates and use curved arrows to indicate electron flow in
each of these steps.
3. Provide a step-by-step mechanism to account for the product of each of the following reactions. Show the structure of each of the intermediates and use curved arrows to indicate electron flow in each of these steps. a) NaOEt (1 equiv) EtOH O OH...
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but...
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but do show ALL reaction intermediates. (30 pts) LiAIH4 G CH3-C-00HE (b) F (c) OH CH3 6. Give the product of the following reactions and in each case give a detailed reaction mechanism by which it is formed. (40 pts, 10 each) pH 4-5 ca. H2S4 HBrJ (c)--/SH NaOH I (d) H CH3 H CH3
5. Give the products of the following reactions....
3. Give the major organic product(s) of each of the following reactions or sequences of reactions....
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
1. Give a detailed mechanism for each of the following reactions, 2. Classify each of the following reactions as an Aldo condensation, a Claisen condensation, Dieckmann condensation, or Michael reaction. CO2Et CO,Et 1. Catalytic NaOet 2. Hz0* COEt
Need Help. Will Rate If Complete.
1) NaoEt, EtOH Br 2) O 3) H30+ / A. 1) NaoEt, EtOH (s) ar 2) Y Br 3) Hz0+ / A 1) NaOme/MeOH ~ Br OMe 3) Hz0+/A. 1) NaOEt, EtOH 2) V Br 3) NaOEt, EtOH COOEt 5) H30+/A Robinson Annulation NaoEt, EtOH/A come lui OMe 28- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen...
8. Draw a detailed arrow pushing mechanism for the following transformation. You must show arrows for every step, writing statements like “proton transfer” without showing the arrows for that step is not an acceptable answer. 1. NaOEt, EtOH لا ملہ ان ام Et 2. Hz0+, Heat
1. Provide the detailed mechanism of the aldol condensation reaction between 2 mols of benzaldehyde and 1 mol of acetone under basic conditions. Show all intermediates and steps for full credit. There are 10 steps to the complete mechanism. (2 pts for each step) 2. Give the products for the following aldol reactions. (5 points each) مل OH H 2. н 3. OH ܘܐ OH o 5. ОН" -CHO 6. OH
1. Provide the structure of the product (an acetal) in box and a detailed mechanism for the entire transformation (15 points): acetal: inoi Ho Mechanism 2. Provide the starting material AND reagents you would use to synthesize the following product by a Dieckmann condensation. Also draw a detailed mechanism for this transformation (15 points): Mechanism: 3. Provide the products of each step in the boxes provided and draw a detailed mechanism for each transformation (20 points): step 1 step 2...
(b) For TWO of the following reactions provide a mechanism that explains the product shown and explain any regiochemical control that has occurred in its formation. [2 x 5 marks] EtO2C LCOMEt CO2Et NaOEt mwag mo (i) NaOEt, Ph Br (ii) 0 1 Eto V 0 L oEt HO (ii) aqueous acid, heat EtO2 CO2Et NaOEt EtO2C CO2Et
give the product(s) for each of the reactions and choose any
two that draw/write the mechanism for the transformation
Many useful synthetic produces involve sequences of aldol. Claisen, Michael, and Mannich reactions. The following questions describe a few samples. Give the product(s) for each of the following reactions (2 points each). Also, choose any two to write/draw mechanisms for the transformation (3 points/each) (15 points) 1) NaOC2Hs 2) H30 &heat 1 CeHs C2HsO2C 1) NaOC2Hs & heat co22Hs 2)heat 2...
Provide a step-by-step mechanism to account for the product of
each of the following reactions. Show the structure of each of the
intermediates and use curved arrows to indicate electron flow in
each of these steps.
3. Provide a step-by-step mechanism to account for the product of each of the following reactions. Show the structure of each of the intermediates and use curved arrows to indicate electron flow in each of these steps. a) NaOEt (1 equiv) EtOH O OH...
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but do show ALL reaction intermediates. (30 pts) LiAIH4 G CH3-C-00HE (b) F (c) OH CH3 6. Give the product of the following reactions and in each case give a detailed reaction mechanism by which it is formed. (40 pts, 10 each) pH 4-5 ca. H2S4 HBrJ (c)--/SH NaOH I (d) H CH3 H CH3
5. Give the products of the following reactions....
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
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