2. Complete MO diagrams for the following diatomic molecules, anions, and cations. Calculate their bond order....
Using the molecular orbital energy ordering for second-row homonuclear diatomic molecules in which the π2p orbitals lie at lower energy than the σ2p, predict the bond order in a molecule or ion with each of the following numbers of total valence electrons.(Use the drawing MO energy diagrams) Will the molecule or ion be diamagnetic or paramagnetic? Part A Determine the bond order in a molecule or ion with 4 valence electrons. Part B Will this molecule or ion be diamagnetic...
Complete the table below, which lists information about some diatomic molecules or molecular ions. In particular: • Decide whether each molecule is stable or not. • Decide whether each molecule would be diamagnetic or paramagnetic. • Calculate each molecule's bond order. molecule stable? diamagnetic or paramagnetic? bond order 미미 diamagnetic paramagnetic X diamagnetic To oo ooo paramagnetic diamagnetic paramagnetic
2. (40 points) The MO diagrams for homonuclear diatomic molecules are given below. LUMO Lowes Unceaupiad 2P HOMD (tHighast ocaupied No No mixing Mixing of og orbitals (a) (b) Bo BongNon 8-2 Va) (15 pts) Choose the appropriate diagram for the N2 molecule and place the right number of electrons. Indicate the frontier orbitals (HOMO and LUMO) and the bond order. b) (20 pts) Sketch a qualitative MO diagram for the heteronuclear diatomic anion CN; place the right number of...
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Which are correct? In molecular orbital (MO) energy level diagram for cyanide ion? The MO shows: (a) bond order = 2 (b) bonder order =3 ) cyanide ion is paramagnetic ) cyanide ion is! diamagnetic (e) HOMO is nu HOMO is og (6%) (2) Write down the diatomic molecules 2p orbitals for (a), (b), (6%) (3) What is the bond order of (a) OF(b) to which atom ( O or F ) the...
Draw the MO energy level diagrams for N2, N2+, and N2- Calculate the bond order for each. Which has the shortest bond? Which is/are paramagnetic? Draw the MO energy level diagram for O2- and calculate its bond order.
2. (40 points) The MO diagrams for homon omonuclear diatomic molecules is given below. umolt Anh HOMO Homo a) Bo 8 4 2 No mixing Mixing of, orbitals (a) (b) U2 36 zire .02=642=2e- va) (15 pts) Choose the appropriate diagram for the O molecule and place the right number of electrons. Indicate the frontier orbitals (HOMO and LUMO) and the bond order. b) (20 pts) Sketch a qualitative MO diagram for the heteronuclear diatomic anion CN; place the right...
Name MOLECULAR ORBITAL THEORY 1. Following species are given: 0:2. 03. 02.02.02 a. For each species draw an MO diagram and fill in all the electrons. Use the energy diagram for Oz. b. Determine the Bond order of the species c. Determine if the species are paramagnetic or diamagnetic 2. Carbon monoxide has one of the strongest covalent bonds. Show with MO theory why this is the case. 3. The molecule HF has a single bond between H and F....
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
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A) Draw the Lewis Dot structu re for 02. 3. b) What is the bond order? c) Is O2 diamagnetic or paramagnetic? 6. Look up M.O. diagram for 02. a) Using the bond order formula given, calculate the bond order for O2 according to MO. Compare this answer to the bond order calculated in earlier question. d) Is O2 diamagnetic or paramagnetic according to MO? Compare this answer to the question in earlier question. hen a substance...
2. Use the MO theory to complete the following table and answer the questions that follow. (6 Pts.) Molecule/ion Bond order Paramagnetic/Diamagnetic N2 N2. N2 A) Which molecule/ion has the longest bond length? B) Which moleculefion has the strongest bond?