4. Now consider the catalase catalyzed decomposition of hydrogen peroxide to water. The much needed catalyst....
The decomposition of hydrogen peroxide at 200 °C involves a first order rate law. The starting concentration of H202 is 0.20 M and changes to 0.0050 M after 10 minutes. Calculate the rate constant (in s1). 2H202(aq) 2H20(I) + 02(g) Select one: a. 4.0x 10-3 b. 4.0x 10-4 c. 6.1 x 103 d. 6.1 x 10-2 e. 4.0 x 10-2
4. [Chang, 10.27) The activation energy for the decomposition of hydrogen peroxide: 2H2O2 (aq) → 2H200 + O2(g) is 42 kl.mol-1, whereas when the reaction is catalyzed by the enzyme catalase, it is 7.0 kJ. mol-1. Calculate the temperature that would cause the nonenzymatic catalysis to proceed as rapidly as the enzyme-catalyzed decomposition at 20°C. Assume the pre-exponential factor to be the same in both cases.
The enzyme catalase catalyzes the decomposition of hydrogen peroxide. The following data are obtained regarding the rate of reaction as a function of substrate concentration using concentration of catalase equals to 3.5 x 10^–9 M : Analyzing the data using the Lineweaver-Burk plot: we calculated the S = 0.698 s , and I = 26.6 M^-1 s , Km for this enzyme is: [H202lo (M) Initial Rate (Ms1) 1.38 x 10-3 0.001 0.002 2.67 x 10-3 0.005 6.00 x 103...
please 6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: O(g) + O(g) 20(8): rate-k[O][NO] Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: H:Os(aq) + (aq) → H2O(1) Ol(aq) --- -slow H2O2(aq) + Ol'(aq) → H2O(1) + O2(g) + l'(aq) ------fast What is:...
6 The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: rate k[O][NO] Os(g)+O(g)+20;(g); Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: -slow H2O:(aq) +I(aq)H;O(1) + 0I°(aq) -fast H20:(aq) +Or(aq)H:O()) +02(g)+l'(aq) What is: iv) the catalyst? iv) the intermediate ii) the rate law i) the...
4. The decomposition of hydrogen peroxide, H2O2, produces water and oxygen gas. a. Write a balanced equation for this decomposition reaction. b. The reaction is faster with the addition of potassium iodide, KI. Should this chemical appear in the balanced reaction? What is its purpose? 5. If you were running a reaction at 25°C and increased the temperature 30°C to 55°C. How much faster should the reaction at the higher temperature be? 4. For the reaction Fe3+ (aq) + SCN...
The value of Km for the shown data for a hexokinase-catalyzed reaction is with the unit of . The value of Vmax for. the same reaction is with the unit of . Be sure to give the values with the correct number of significant figures. You might have to construct a kinetic plot. For units, choose one answer from (uM, 1/ UM, HM/second, uM x second, mM, 1/mM, second, 1/second, mM/second, mM x second) vo (mM/sec) Glucose concentration (mm) 0.10...