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Question A4 In the laboratory you performed the following reaction. W CH3! HNO3, H2SO4 Toluene (a)...
3.) (12 points) For the following electrophilic aromatic substitiution reaction: 02N. CN CN CN HNO3 H2SO4 O2N в a) Whic...
3.) (12 points) For the following electrophilic aromatic substitiution reaction: 02N. CN CN CN HNO3 H2SO4 O2N в a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product, labelling the rate-determining step. c) Referring back to the mechanism you drew in part b, explain your choice of part a
7) Consider the following reaction of an alkene with acidic water which we will cover in...
7) Consider the following reaction of an alkene with acidic water which we will cover in chapter 4 (4.9). (H30 represents a generic acid like HNO3, H2SO4, etc.) OH The reaction mechanism contains 3 steps ぶー Step 1 Step 2 Step 3 a) In step 1, add in the appropriate curved arrows to show how cyclopentene and hydronium become the cyclopentyl cation and water. Label the nucleophile and electrophile b) In step 2, draw intermediate A that is formed when...
1. Draw the (major) organic products of the following reactions: HNO3 H2SO4 HN (CH3)3CBr AlBr3 FeBr3...
1. Draw the (major) organic products of the following reactions: HNO3 H2SO4 HN (CH3)3CBr AlBr3 FeBr3 Br Sort the following molecules by their reactivity toward electrophilic aromatic substitution (1-most reactive, 4 2. least reactive): NH2 so,H Place either the letter A or C below the following compounds to indicate whether each of them are achiral (A) or chiral (C) 3. но Cl Determine the configuration (R or S) for each stereocenter in the following compounds: 4. Cl Cl NH2 но...
please help in all sections asap!! Provide the reagents necessary to carry out the following conversion....
please help in all sections asap!!
Provide the reagents necessary to carry out the following conversion. ОСН Br Br NO2 Choose the correct reagents for step 1 fuming H2SO4 HNO3/H2S04 excess Br2/ FeBr3 dilute H2SO4 O Cl2/FeCly O CH3ONA Choose the correct reagents for step 2. Cl2/ FeCl3 HNO3/H2SO4 CH3ONA fuming H2SO4 excess Br2/ FeBr3 dilute H2SO4 Choose the correct reagents for step 3 CH3ONA HNO3/ H2SO4 O excess Br2/ FeBr3 Odilute H2S04 fuming H2SO C2/ FeCl Choose the correct...
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products...
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products are formed when a strong electrophile is added to benzene?) Model 1: (review) Electrophilic Addition of HCI Rani o g cyclohexene carbocation intermediate Run 2 U X benzene This product carbocation intermediate DOES NOT Critical Thinking Questions 1 For Rxn I (above) draw curved arrows showing the mechanism of electrophilic addition of HCl. Include an appropriate carbocation intermediate in the box above. Figure 1:...
Can you help me identify reagent (i), Compound 8 and Compound 12 in the reaction scheme?...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Calculate the theoretical yield and percent yield for experiments 7, 8, and 9. For experiment 9,...
Calculate the theoretical yield and percent yield for
experiments 7, 8, and 9. For experiment 9, determine the
theoretical yield based on starting with 0.50g of 3-nitrobenzoic
acid. Show work
Acid I (experiment 7): Weight of methyl 3-nitrobenzoate = 1.9
g
Acid II (experiment 8): Weight of 3-nitrobenzoic acid = 1.75
g
Acid III (experiment 9): Weight of 3-nitrobenzamide = 0.30 g
Experiment 7:
-2.5 mL concentrated H2SO4
-1.75 mL concentrated HNO3 (16M)
-2.1 mL concentrated Methyl Benzoate
Experiment 8:...
3.) (12 points) For the following electrophilic aromatic substitiution reaction: 02N. CN CN CN HNO3 H2SO4 O2N в a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product, labelling the rate-determining step. c) Referring back to the mechanism you drew in part b, explain your choice of part a
7) Consider the following reaction of an alkene with acidic water which we will cover in chapter 4 (4.9). (H30 represents a generic acid like HNO3, H2SO4, etc.) OH The reaction mechanism contains 3 steps ぶー Step 1 Step 2 Step 3 a) In step 1, add in the appropriate curved arrows to show how cyclopentene and hydronium become the cyclopentyl cation and water. Label the nucleophile and electrophile b) In step 2, draw intermediate A that is formed when...
1. Draw the (major) organic products of the following reactions: HNO3 H2SO4 HN (CH3)3CBr AlBr3 FeBr3 Br Sort the following molecules by their reactivity toward electrophilic aromatic substitution (1-most reactive, 4 2. least reactive): NH2 so,H Place either the letter A or C below the following compounds to indicate whether each of them are achiral (A) or chiral (C) 3. но Cl Determine the configuration (R or S) for each stereocenter in the following compounds: 4. Cl Cl NH2 но...
please help in all sections asap!!
Provide the reagents necessary to carry out the following conversion. ОСН Br Br NO2 Choose the correct reagents for step 1 fuming H2SO4 HNO3/H2S04 excess Br2/ FeBr3 dilute H2SO4 O Cl2/FeCly O CH3ONA Choose the correct reagents for step 2. Cl2/ FeCl3 HNO3/H2SO4 CH3ONA fuming H2SO4 excess Br2/ FeBr3 dilute H2SO4 Choose the correct reagents for step 3 CH3ONA HNO3/ H2SO4 O excess Br2/ FeBr3 Odilute H2S04 fuming H2SO C2/ FeCl Choose the correct...
250 ChemActivity 29 Electrophilic Aromatic Substitution no ChemActivity 29 Part A: Electrophilic Aromatic Substitution (What products are formed when a strong electrophile is added to benzene?) Model 1: (review) Electrophilic Addition of HCI Rani o g cyclohexene carbocation intermediate Run 2 U X benzene This product carbocation intermediate DOES NOT Critical Thinking Questions 1 For Rxn I (above) draw curved arrows showing the mechanism of electrophilic addition of HCl. Include an appropriate carbocation intermediate in the box above. Figure 1:...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Calculate the theoretical yield and percent yield for
experiments 7, 8, and 9. For experiment 9, determine the
theoretical yield based on starting with 0.50g of 3-nitrobenzoic
acid. Show work
Acid I (experiment 7): Weight of methyl 3-nitrobenzoate = 1.9
g
Acid II (experiment 8): Weight of 3-nitrobenzoic acid = 1.75
g
Acid III (experiment 9): Weight of 3-nitrobenzamide = 0.30 g
Experiment 7:
-2.5 mL concentrated H2SO4
-1.75 mL concentrated HNO3 (16M)
-2.1 mL concentrated Methyl Benzoate
Experiment 8:...
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