ochem puzzle 2 Puzzle 2 - Fill in all missing reagents and products in the boxes....
Fill in the boxes with the missing reagents or product.
Fill in the boxes with the missing reagents or product. 1 . (20 pts.) Fill in the boxes with the missing reagents or product. c) pgs. 434-436 book
Fill in the boxes with the
missing reagents or product.
Fill in the boxes with the missing reagents or product.
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
Fill the missing reagents/products in each box: (2pts each, 12 pts total) 1) KOH H*, H2O Heat 2) Ph-CH2-Br
Fill in missing reagents
12. Fill in the missing reagents or products in the following scheme. (14 pts) Ma OH HCI NaOE! NaOEL
13. Reactions: Fill in the missing products for each of the boxes in the following reaction sequences. (30) OH Na2Cr2O7 H2SO4 H2O PCC NaBH HOCH, PBr3 Br2, H20 NaH BrMg- 2. H2O* NaOEt 1. OsO4 2. NaHSO3
Fill in the missing products or reagents (above blank arrows) for the following reaction schemes. No charged species should be drawn anywhere in this assignment. Acidic workup steps are assumed and are NOT explicitly included. Scheme 1: 10 pts EC- H2 KMnO4 Lindlar OH O ملتين NAOMe MeOH Scheme 2:12 pts 1) LDA H2O MgBr 2) O H2SO4 NaH Br LINHA mCPBA
Predict the Products/Reagents.
Draw the expected products from the following reactions or fill
in the missing reagent(s). Where a stereocenter is created,
indicate the configuration of the product.
Predict the Products/Reagents. Draw the expected products from the following reactions or fil in the missing reagent(s). Where a stereocenter is created, indicate the configuration of the product Br Mgo Et20 8. 1. PhCH2Br 2. BuLi PPh3 9. H2N Et, (c CO2Et Ph 10. NH2 NaBH3CN
2. Synthesis: Fill in the missing products in the synthesis process below. Stereochemistry should be shown if applicable. Br m-CPBA NaOEt DMSO H+ MeOH 1. Predicting Products/reagents: Draw the structure of the reagents or the major organic product(s) of each reaction in the boxes provided. Stereochemistry should be shown if applicable. 1) xs LAH, Et20 2) H20 CI HO CI OH CI pyridine
fill in missing products or reagents
1. Ph Mg Br a. Ho quench N Once Nadet (a equiv.), Eloh then quench o ? oft H