Assuming it is a mono substitution reaction. Predict the products for the following reactions and draw...
Predict the Major product(s) for the following reactions and draw their corresponding arrow-pushing mechanisms. If there is no reaction write NR. (21 points total) detailed Show the correct stereochemistry when needed KOH THF substitution Cl Mechanism: MeOH substitution Mechanism: CI t-BuOK, DMF heat elimination Mechanism:
1, Write detailed, arrow-pushing mechanisms for the following reactions. Predict the products when none are given. Н-о a) H2SO4 (cat.) CH3CO2H b) H2SO4 (cat.) CH,он c) H2SO4 (cat.) H2, Pd/C (no mechanism required) d) HCI e)
Question 3 (a) Predict the products A-F of the following reactions (no mechanisms are required): Na CO2 A NO2 Na SME HNMez POCI3 HNO3, H2SO4 H2, Pd/C NaNO2, HCI then H2O, warm [6 marks) (b) Suggest a mechanism for the following reaction: H2SO4
Name Topic: Reaction Mechanisms: Predict your ability: For each of the following reactions, predict the major and minor product, underlining the major product. After, draw a complete arrow-pushing mechanism to obtain each product. СНЗ Good Average Needs Improvement 1. H30+, H20 CH S. CH Br2, H2O
Predict the products and draw a reasonable mechanism for the substitution reaction of 2-bromo-methylheptane with the azide anion. Assume that it is an SN1 mechanism. Make sure you show proper formal charges and curved arrow formalism.
Predict the major organic products formed in the following reactions. Be certain to indicate stereochemistry in your products if it is important. H2 Pd/C HCI H2O H2SO4 Br2 Draw a stepwise, detailed mechanism for the acid-catalyzed hydration reaction in question 2 above. Use curved arrows to indicate the flow of electrons. (Note: use hydronium ion, H307, in your mechanism to indicate “acidic water”).
Predict the major organic products formed in the
following reactions. Be certain to indicate stereochemistry in
products if it is important.
H2O H2SO4 Br2 3. Draw a stepwise, detailed mechanism for the acid-catalyzed hydration reaction in question 2 above. Use curved arrows to indicate the flow of electrons. (Note: use hydronium ion, H:07, in your mechanism to indicate "acidic water"). (6 pts)
The following reaction follow an E1 mechanism. Propose an arrow-pushing mechanism for the following transformations using proper curved arrows: Conc. H2SO4 heat By what mechanisms are the following reactions likely to occur? Draw the major product(s) for each reaction. Show relevant stereochemistry if appropriate. If the expected products are racemic, just draw one enantiomer and write racemic. NaoMe NaoMe OTS NaSH OTS H20
5. Draw an arrow-pushing mechanism for the following reaction, and predict the stereochemistry of the product(s). If more than one stereoisomer is formed, state which stereoisomers will be formed in equal quantities and which will be formed in unequal quantities. cat. H2SO4 HO Draw an arrow-pushing mechanism for the following reaction, and predict the stereochemistry of the product(s). If more than one stereoisomer is formed, state which stereoisomers will be formed in equal quantities and which will be formed in...
Predict the major substitution products of the following
reaction.
Predict the major substitution products of the following reaction. Use the wedge/hash bond tools to indicate stereochemistry. If there is more than one major product possible, draw all of them. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.