Homework Answers
a. Hydrobromination of propylene
b. Dehydroiodination of cyclohexane
c. Dehydrobromination of 2,3-dibromobutane
d. Dehydrobromination of 2,3-dibromobutane
e. Reaction of acetanylide with methyl bromide(SN2)
f. Electrophilic substitution of benzene with bromine
g. Markonikov addition of HBr
h. Catalyic isomerization of alkene
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поyy ouppocetter Classify each of the following reactions using appropriate name tags/descriptions of the organic reaction...
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR...
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br Вг HЕr (d) NaOH осH CH, Cl Вr НС Br Br CH CH OH Cн CH, Он Н н'. Н,о Он Н "сн CH, CH,CH CH,CH Он н' (g) CH Oн осн, н CH—С-С (h) 2 н Н Н Н
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br...
4. Alcohols undergo two major types of elimination reactions. Classify the following reactions as DEHYDRATION (removal...
4. Alcohols undergo two major types of elimination reactions. Classify the following reactions as DEHYDRATION (removal of W U RCACIAD 20s Sax oa or DEHYDROGENATION (removal of hydrogen). ater) а. НС, CH2 concentrated., acid CH2 Cн Hас CH2 A-CH2 CH CH2 Н,с сн CH3 CH3 OH (Oil-D b. Н,С CH CH2 O CH2 CH2 CH H3C CHh CHh CH CH CH2 Н.С CH3 CH3 ОН CH CH2 CH2 CH2 CH2 C. CH, CH, "oн Но
4. Alcohols undergo two major...
C) Give the major organic products for the following reactions and show the mechanism for 1-3. Be sure to consider...
C) Give the major organic products for the following reactions and show the mechanism for 1-3. Be sure to consider the regioselectivity of each reaction! Cн. Brz CHs н" 2 сн,он CHs Cl2 3 н,о но- CH Hа Pd/C Cн
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3....
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"
6.48 In each of these reactions, the organic starting material is achiral. The structural formuls of...
6.48 In each of these reactions, the organic starting material is achiral. The structural formuls of the product is given. For each reaction, determine the following. (1) How many stereoisomers are possible for the product? (2) Which of the possible stereoisomers is/are formed in the reaction shown? (3) CH CH + HBr Br (а) Br Br C (b) Br Br +Br CC (c) Br +HCI (d) +Cl2 in H2O (e) ОН -00*c0 OsO4 (f) ROOH OH ОН 1.BН, 2.Н,О, NaOH...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2)...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с...
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с Сн, Н CH,CH нс H 15. (3 pts each) Give the product(s) for the following reactions, and name all reactants and products. CH, он ОН н,с + нэс- сн - сн 3 нус. NH2 ОН Hн ІІ ОН + н-с-с-о-н НО P н Н ОН
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3...
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
Give the organic products, with the CORRECT REGIOCHEMISTRY AND STEREOCHEMISTRY, when appropriate. !!! CH3 -C CH-CH...
Give the organic products, with the CORRECT REGIOCHEMISTRY AND
STEREOCHEMISTRY, when appropriate. !!!
CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br Вг HЕr (d) NaOH осH CH, Cl Вr НС Br Br CH CH OH Cн CH, Он Н н'. Н,о Он Н "сн CH, CH,CH CH,CH Он н' (g) CH Oн осн, н CH—С-С (h) 2 н Н Н Н
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br...
4. Alcohols undergo two major types of elimination reactions. Classify the following reactions as DEHYDRATION (removal of W U RCACIAD 20s Sax oa or DEHYDROGENATION (removal of hydrogen). ater) а. НС, CH2 concentrated., acid CH2 Cн Hас CH2 A-CH2 CH CH2 Н,с сн CH3 CH3 OH (Oil-D b. Н,С CH CH2 O CH2 CH2 CH H3C CHh CHh CH CH CH2 Н.С CH3 CH3 ОН CH CH2 CH2 CH2 CH2 C. CH, CH, "oн Но
4. Alcohols undergo two major...
C) Give the major organic products for the following reactions and show the mechanism for 1-3. Be sure to consider the regioselectivity of each reaction! Cн. Brz CHs н" 2 сн,он CHs Cl2 3 н,о но- CH Hа Pd/C Cн
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"
6.48 In each of these reactions, the organic starting material is achiral. The structural formuls of the product is given. For each reaction, determine the following. (1) How many stereoisomers are possible for the product? (2) Which of the possible stereoisomers is/are formed in the reaction shown? (3) CH CH + HBr Br (а) Br Br C (b) Br Br +Br CC (c) Br +HCI (d) +Cl2 in H2O (e) ОН -00*c0 OsO4 (f) ROOH OH ОН 1.BН, 2.Н,О, NaOH...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с Сн, Н CH,CH нс H 15. (3 pts each) Give the product(s) for the following reactions, and name all reactants and products. CH, он ОН н,с + нэс- сн - сн 3 нус. NH2 ОН Hн ІІ ОН + н-с-с-о-н НО P н Н ОН
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
Give the organic products, with the CORRECT REGIOCHEMISTRY AND
STEREOCHEMISTRY, when appropriate. !!!
CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
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