Why does the ^1H NMR spectrum of the hydrido ligand in cis-[RhH(C0)(PM_e3)_2] consist of 8 resonance...
4) Why does the 1H NMR spectrum of the hydrido ligand in cis-[RhH(CO)(PMe3)2] consist of 8 resonances of equal intensity? (1-bond and 2-bond couplings are both involved in this question; assume that 13C is at natural abundance of 1%, and thus not involved in the coupling, and that Pt is 100% 195Pt, spin 1/2). Your answer: 4) Why does the 1H NMR spectrum of the hydrido ligand in cis-[RhH(CO)(PMe3)2] consist of 8 resonances of equal intensity? (1-bond and 2-bond couplings...
Using the tree approach for predicting first-order NMR spectra for molecules and draw the requested spectra for the following molecules #1-#3 in the space provided (do not use backside of pages). All spectra are collected with no {1H} (proton decoupling). The NMR active nuclei are all I = 1⁄2, i.e., dipolar, so Pascal’s triangle applies. Consider only 1-bond coupling constants 1JAB, and ignore ≥2- bond coupling constants (EXCEPT where noted in #2); label the chosen coupling constant on each branch...
Evaluate and investigate the following IR Spectrum, 13C NMR Spectrum and 1H NMR Spectrum. Identify the most important peaks and correlate the results as much as you can from the obtained product in the multi-step synthesis of ethyl acetoacetate. This is Product E from this multi-step synthesis where Product C was identified as in the figure below and as such, identify what product can be obtained after the synthesis from the spectra provided. Use the template below in analysing the...