Predict the major organic products of the following reactions.
1-bromobutane + sodium cyanide in acetone
2-hydroxy-3,3-dimethylbutane in HI
1-chloro-1-methylcyclohexane + NaOH/H2O
1- chloro-1-methylcyclohexane + KOC(CH3)3, HOC(CH3)3
Predict the major organic products of the following reactions. 1-bromobutane + sodium cyanide in acetone 2-hydroxy-3,3-dimethylbutane...
Complete the following reactions and state the dominant mechanism acetone b. (R)-2-bromobutane + Nash mechanism: c. (18,2S)-1-bromo-1,2-diphenylpropane methanol + NaOCH; mechanism: d. 3-chloro-2,2-dimethylbutane + NaSCH; mechanism: t-BuOH e. 2-chloro-2-methylpentane + (CH3),CONa H).CoNa BUCH mechanism:
Predict the major organic product of products of each of the following reactions. a) (CH),CHCH-CH- H2SO4 HO b) (CH3),CHCH=CH, 1. Hg(OAc), H2O 2. NaBH 1. BH3-THF c) (CH3),CHCH=CH2 2. H2O3, NaOH
Predict the major organic product or products of each of the following reactions: Identify the mechanism taking place in each of the reactions and please provide explanation. H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Predict the major organic product or products of each of the following reactions. H2SO4 a) (CH3),CHCH-CH2- 1. Hg(OAc), H,0 2. NaBH4 b) (CH3)2CHCH=CH, 1. BH3-THF 2. H2O2, NaOH c) (CH3)2CHCH=CH2
Predict the major products for each of the following reactions. KOC(CHsh HOC(CH3)hs HBr H20, H2SO4, 100 C H PO4. conc -0109%0 60 100 C
ROBLE Predict the major products of the following reactions 22-5 (a) acetone )LDA (2) CH2-CHCH2Br (1) LDA (2) CH3I (1) LDA (2) CH3CH2I ROBLE Predict the major products of the following reactions 22-5 (a) acetone )LDA (2) CH2-CHCH2Br (1) LDA (2) CH3I (1) LDA (2) CH3CH2I
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. 2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
For the following reactions, predict the MAJOR product(s). If a pair of enantiomers is expected, draw both enantiomers. NaSH Cis-1-bromo-3-methylcyclohexane acetone OTs 1. NaI/acetone 2. NaCN/DMF CH3 NaCN H,с. Br CH3 Бшн.
Part 2. Predict the Organic Products. Predict the major organic product(s) for each of the following reactions. Be sure to show stereochemistry when appropriate. (3 points each) 1) NaNH / NH3 2) CH31 1) BH3 / THE 2) H2O2/NaOH/H20 1) OsO4 / THE 2) Has | 1) NaNH / liq. NH3 2) H20