Reaction I, since no of product are less in no than no of reactants., hence change in entropy is negative. Since entropy is the measure of disorder.
For Reaction II and IV entropy is zero ie., no change
For reaction III, it is positive since no of products are more than reactants.
Of following reactions, which one(s) would you expect to have a negative AS? Br + Br2...
1. What type of bond cleavage does the following reaction describe? Circle one. HOOH 2 HO A.homolytic B. heterolytic C. covalent D. ionic 2. Of following four reactions, which one(s) would you expect to have a negative AS? Circle it/them. Br он Br +Br2 CI +HCI IV Br Br "Вг Br
show the mechanism for these reactions
Br Br Pd/C Br2 Br ?? Br, H20 HCI CI Br ?? H2O+
Which product(s) would you expect to obtain from each of the following reactions? In each part give the mechanism (Sw1, SN2, E1 or E2) by which each product is formed. Explain your reasoning. (20 pts) 6. a. NaSH OTs DMSO b. CI NaOCH3 C. OMs NaOCH2CH3 d. ON HCECNa e. KOC(CH3).3 CI Br NaOCH2CH3 CH3CH2OHH
Predict the major product(s) of the following reaction. Br2 H2O Br Br ...Br ...Br "ОН """он **OH "OH III IV 1) Only II and IV 2) Only I and IV 3) Only I and II 4) Only II and III
Which product(s) would you expect to obtain from the following sequence of reactions? IV II I III V
Which one of the following reactions would you expect to have a change in the standard entropy with a small magnitude? 4/2CH2(g) + O2(6) -- 1/20026)+H2013) C2H6lg)+7/20218) -- 2002(8) + 3H2O(g) c C2H2(g) + 5/20218) -- 200268) + H2O(g) 2C2H668) + 702(8) -- 400268) + 6H2O(g)
Draw the product(s) of the following reactions. HNO3/H2SO4 Br AICI3 Он So/H2SO4 Он Br2/FeBr3 d. HNO3/H2SO4 Br е. OCH3 Насо. f. AICI3 ОСНЗ CI Но. AICI3 NO3 Br2/FeBr3 h.
which of the following would you expect to have a higher melting
point? explain why
3. Which of the following would you expect to have the higher melting point? Explain why. (3 marks - 1 for the answer, 2 for the explanation) CI OH
Which of the following molecules would you expect to have the highest pka? Note that the most acidic hydrogen in each molecule has been drawn in red. ОН Br ОН F ОН CI ОН
Which of the following molecules would you expect to have the highest pka? Note that the most acidic hydrogen in each molecule has been drawn in red. он Br ОН F он CI ОН