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The standard free energy of formation of nitric oxide, NO, at 1000. K (roughly the temperature...
Nitric oxide, NO, also known as nitrogen monoxide, is one of the primary contributors to air pollution, acid rain, and the depletion of the ozone layer. The reaction of oxygen and nitrogen to form nitric oxide is N2(g) + O2(g) +2NO(9) The heat produced by an automobile engine is sufficient to convert some of the nitrogen and oxygen in the air to nitric oxide. The spontaneity of a reaction can be determined from the sign of, A-G • A reaction...
The equilibrium constant, K, for the formation of nitrosyl chloride from nitric oxide and chlorine. 2NO(g) + Cl2(8) = 2NOCI(g) is 6.5 x 104 at 35°C. In which direction will the reaction proceed to reach equilibrium if the starting concentrations of NO, Cl., and NOCI are 2.6 x 10-3 M, 7.4 x 10-M, and 5.8 M respectively? o o O shift right shift lent neither
For the reaction of oxygen and nitrogen to form nitric oxide, consider the following thermodynamic data (Due to variations in thermodynamic values for different sources, be sure to use the given values in calculating your answer.): ΔH∘rxn 179.97 kJ/mol ΔS∘rxn 22.99 J/(mol⋅K) Calculate the equilibrium constant for the following reaction at room temperature, 295.9 K: Whatever answer you get multiply by 1x1031 and enter that number to 4 decimal places.
Problem 7: Nitric oxide, NO, is a common air pollutant produced by automobile engines and power plants according to the reaction N2 (g)+02 (g) 2NO (g) A constant-volume reactor of 100 L is initially charged with 4 mol of N2 and 1 mol of O2 and then temperature is increased to 800 K. Estimate the equilibrium extent of the reaction if the pressure is kept constant at 1 bar (Answer: 5.567 x 10-6)
For the aqueous reaction the standard change in Gibbs free energy is Delta G degree = 7.53 kJ/mol. Calculate Delta G for this reaction at 298 K when [dihydroxyacetone phosphate] = 0.100 M and [glyceraldehyde-3-phosphate] = 0.00400 M. The constant R = 8.3145 J/(K middot mol) Delta G =
4. (a) Calculate the Gibbs Free Energy of formation for urea at 25°C. Given: The standard enthalpy of formation is -333.17 kJ mol and the standard entropy of formation is 136.093 J K mol". (b) is the formation of urea a spontaneous process under these conditions? Explain. (7 pts) J mol
4. [201 At 500 K, we have the data of standard enthalpy of formation and standard entropy of formation as follows: AH° (kJ/mol) AfSe (J/K mol) Substance HI (g 32.41 221.63 Н2 (g) 5.88 145.64 I2 (g) 69.75 279.94 One mole of H2 and one mole of I2 are placed in a vessel at 500 K. At this temperature only gases are present and the equilibrium of the following reaction is established. Н2 (9) + I, (9) 2HI (g) (1)...
Use the reaction and the data given in the table below for Questions 16-17. Nitric oxide reacts with chlorine to form NOCI. The data refer to 298 K 2NO(g) + Cl2(g) Substance: AHo s (kJ/mol): 2NOC?(g) NO(g) C2gNOCIg) 90.29 ? 51.71 261.6 S (J/K-mol): 210.65 223.0 16. What is the equilibrium constant for the reaction above at 298 K?
I cannot seem to figure it out. The standard Gibbs-free energy of a system is related to its equilibrium constant through the following equation. AG = R.T.In(K) In this equation R is the gas constant, T is the temperature, and the next to AG defines the conditions as standard ambient temperature and pressure, i.e. "SATP". (Answer the following questions to three significant figures.) (a) Given an equilibrium constant of 6.28 x 10-3, what is its standard Gibbs-free energy? 4.9 12.6...
Consider the reaction: N2(g) + 3H2(g) <---> 2NH3(g) The Gibbs free energy of formation ((delta)Gfo) for ammonia is -16.5 kJ/mol and the reaction is exothermic. Calculate the (delta)Gorxn and the equilibrium constant for the reaction and clearly state whether K increases or decreases with temperature.