1. Show that the wave function V = Ce-r/ao where ao = hc/(mca) is a solution...
1) (60 points) The ground state of the hydrogen atom: In three dimensions, the radial part of the Schrodinger equation appropriate for the ground state of the hydrogen atom is given by: ke2 -ħ2 d2 (rR) = E(rR) 2me dr2 where R(r) is a function of r. Here, since we have no angular momentum in the ground state the angular-momentum quantum number /=0. (a) Show that the function R(r) = Ae-Br satisfies the radial Schrodinger equation, and determine the values...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in the spherical coordinate representation is where ao-top- 0.5298 10-10rn is the Bohr radius, and μ is the electon-proton reduced mass. Here, the square of the angular momentum operator L2 in the spherical coordinate representation is given by: 2 (2.2) sin θー sin θ 00 The form of the Schrödinger equation means that all energy eigenstates separate into radial and angular motion, and we can write...
Consider a wave function for a hydrogen-like atom: 81 V πα3 a) Find the corresponding values of the quantum num bers n, 1, and m. (b) By measuring the angular momentum, what is the probability of finding 1-0? (c) Construct ψ(r, θ, φ) and another wave function with the same values of n and (azimuthal) quantum number, m+1 (d) Calculate the most probable value of r for an electron in the state corresponding to ψ(r, θ, φ) 1, but with...
Show that R(r) is a solution of the following differential
equation for l = 1, R(r) = (r/ao) *
e-r/2ao.
What is the eigenvalue? Using this result, calculate the value
of the principal quantum number (n) for this function.
h21(L+1) 2mer2 h2 e2 d dR(r) ]R(r) 4περr ER(r) 2mer2 dr dr
1. Given a state y(r) expanded on the eigenstates of the Hamiltonian for the electron, H, in a hydrogen atom: where the subscript of E is n, the principal quantum number. The other two numbers are the 1 and m values, find the expectation values of H (you may use the eigenvalue equation to evaluate for H), L-(total angular momentum operator square), Lz (the z-component of the angular momentum operator) and P (parity operator). Draw schematic pictures of 1 and...
Solution of the Schrodinger wave equation for the hydrogen atom results in a set of functions (orbitals) that describe the behavior of the electron Each function is characterized by 3 quantum numbers: n, I, and my Seronger If the value of n=1 The quantum number / can have values from to The total number of orbitals possible at the n-1 energy level is If the value of 1=3 The quantum number my can have values from to The total number...
Q-3 (25pts) The wave function of a ns electron in a hydrogen atom is r -r/(2a) y (,0,0)=1/27 927 (2-3) a) (10pts) Show that y function is already normalized. b) (10pts) Find the energy (En) of the electron. c) (5pts) Write the principle quantum number (n), orbital quantum number (?), and magnetic quantum number (mi) of the hydrogen electron state.
Solution of the Schrödinger wave equation for the hydrogen atom results in a set of functions (orbitals) that describe the behavior of the electron. Each function is characterized by 3 quantum numbers: n, 1, and my Sofringer Ervin Schrödinger n is known as the L is known as the mis known as the quantum number quantum number. quantum number. n specifies / specifies m/ specifies A. The orbital orientation B.The subshell - orbital shape. C.The energy and average distance from...
ANSWER ALL QUESTIONS 1. (a) The hydrogen atom wave functions are written as Unim. State the values of n, I, and m. State the relation between a physical quantity and each quantum number. At =0 the hydrogen atom is in the superposition state (7,0) = 4200 + A¥210 V3 where A is a real positive constant. Find A by normalization and determine the wave function at time t > 0. Find the average energy of the electron in eV given...