ANSWERS ONLY NO EXPLANATION NEEDED ! [14]. The rate of Sy I reaction is propontional to...
Chem 233 Exam III (A) October 28, 2019 Page 7 14. Which of the following would an of the following would be the best base for performing the following elimination? A KOCHA B. KOCH(CH) C. KOC(CH.) D. this reaction is not an elimination reaction 15. Which of the following statements is (are) true of Sul reactions of alkyl halides in general? A) The rate of an SNI reaction depends on the concentration of the alkyl halide. B) The rate of...
one of the Kekulé structures is not consistent with valence rules? 3. How many degrees of unsaturation (double bond equivalents) ore fouand in 3 O-H 4. The regiochemistry of Markovnikov with no rearrangements of alkenes is c. subject to solvent effects 5. The kinetics of this reaction is. a. first-order b. c, cannot be determined 6. Hydroboration/oxidation of alkenes occurs with a. syn b. trans c. anti d. random 7. The reaction of an alkene with dichlorocarbene is: 8. The...
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Name Exam 2: Chapters 4-7 Please put all of your answers on the scantron sheet. This exam paper must be returned with the scar For questions that list only 1,2,3,4, use the letters a,b.c.d respectively on the Scantron 1. What is the approximate value of the H-C-H bonds angle in ethylene? a. 90° b. 109 c. 120 d. 180 2. What type of molecular orbital is formed by the...
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Which of the following compounds is most reactive towards nucleophilic addition reaction? H1 H H A B С D E Predict the product for the following reaction sequence. iii PBrz Mg/ether Н H Cr04 ОН 2. Hz0+ A. 6,7-dimethyl-3-nonanol B. 6,7-dimethyl-3-nonanone C. 6,7-dimethyl-3-nonanal D. 3,4-dimethyl-7-nonanol E. 3,4-dimethyl-7-nonanone Predict the product for the following reaction 1. LiAlH4 (excess) 2. H30* OH OH OH -Н HO B с D Provide the structure of the ylide needed to prepare...
3. What is the major product of the following reaction? CH, CH2 HO, BH, THE 4. Refer to the reaction in question 3. The regiochemistry of the hydroboration/oxidation of alkenes is: a Markovnikov. b. non-Markovnikov c. subject to solvent effects. d. unrelated to alkene structure. 5. Which of the following carbocations is the least stableone? D. CHE C d. CHE CH H₂C-¢. H-C H₂C-¢. сн. 6. Which of the following statement is NOT correct? a. Alkenes react with H, in...
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11. Deterni ne the product of the following reaction. 2. A. C. B. D. E. None of the choices is correct. E) E A) A D) D B) B c) C 12. Determine the product of the following reaction. H20, H2S04 HgSO4 OH A. へ 人H E. None of these choices is correct. D. E) E D) D C) C в) в A)A 13. Which of the following reaction conditions would result in anti-Markovnikov addition to an alkene?...
4.(18 points) Using the arrow, provide the detailed reaction conditions necessary to give the following. You do not need to provide any starting material or product, just the reaction conditions (see example below) 1.B Example: Show reagent 'B' followed by aqueous acid: 2. H30 a. Markovnikov addition of H2O to a double bond: b. Anti-Markovnikov addition of H2O to a double bond: c. Markovnikov addition to form an alkyl bromide from an alkene: d. Reaction conditions to change 1,2-dimethylcyclohexene into...
Determine the product of the following reaction. 1 L CHOCH "CH Br no reaction H DH (D) 8. Which reagent(s) is needed to facilitate the following reaction: (A) H20, (B) 1. Hg(OAc)2 in H2O 2. NaBH4 (C) 1. Hg(OAc), in CH,OH (D) 1.BH; THE 2. NaBH4 2. H2O2, NaOH (E) all of the above would work 9. Which of the following compounds is the final product of the reaction below: CI (A) (B) CHA + 2 mol Cl, in cct...
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14. Provide the major organic product of the reaction below 2 CHIS 15. Draw the major organic product venerated in the reaction below. Pay particular attention to regio- and stereochemical detail. 1.0, 2. (CH 16. Addition of HCl to 3-methyl-1-butene yields a mixture of two constitutional alkyl chloride isomers. What are they likely to be and how are they formed? Give detailed equations. 17. If stereoisomers are considered, how many alkyl chlorides from #16, could be products? 18. Give...
1. What is the nucleophile in the following S2 reaction and what is the leaving group Br + NaCN 2. What are products of the following sequences of elementary steps? ci 1. Proton transfer involving NaOH 2. Nucleophile elimination 3. Nucleophilic addition of CH,MgBr 4. Sy2 involving CH Br (c) 1. Electrophilic addition of C 2. Electrophile elimination of HC (b) 1. E2 involving NaOCH, 2. Electrophilic addition involving H 3. Coordination involving H20 4. Proton transfer involving H2O OH...