which process is associated with a negative entropy change? why?
A) NaCl(s) -> Na+(aq) + Cl-(aq)
B) N2(g) + 3H2(g) -> 2NH3(g)
C) 2BrCl(l) -> Br2(l) + Cl2(g)
D) H2O (l) -> H2O (g)
which process is associated with a negative entropy change? why? A) NaCl(s) -> Na+(aq) + Cl-(aq)...
When sodium chloride dissolves in water, the ions dissociate: NaCl (s) --> Na+ (aq) + Cl- (aq) Consider the equation, DG = DH - TDS. For each dissolving process, substitute the signs of DG and DH into the equation and predict the possible sign(s) for the entropy (DS). Explain why you chose this sign(s). Does the sign for entropy change seem to make sense? Explain.
2. Which of the following equations will have a negative ∆S? A. 3 H2(g)+ N2(g) --> 2 NH3(g) B. C6H6(l)--> C6H6(g) C. NH4OH(s)--> H2O(l)+ NH3(g) D. NaCl(s) --> Na+(aq) + Cl-(aq)
17.51 Calculate the entropy change for the following processes. (a) 1.00 mol H,O(s) melts at 0 °C. AH = 6.01 kJ/mol. (b) 2.00 mol CH.() vaporizes at 80.0 °C. AH vap = 30.7 kJ/mol. 17.52 - Calculate the entropy change for the following processes. (a) 2.00 mol NH3(e) vaporizes at -33.0 °C. AHvap = 23.35 kJ/mol. (b) 1.00 mol C,H,OH(s) melts at -114 °C. AHjus = 5.0 kJ/mol. 17.53 Use data from Appendix G to calculate the standard entropy change...
Predict the sign of the entropy change, ΔS∘, for each of the reaction displayed. Drag the appropriate items to their respective bins. Pb2+(aq)+2Cl−(aq)→PbCl2(s) CaCO3(s)→CaO(s)+CO2(g) 2NH3(g)→N2(g)+3H2(g) 2Mg(s)+O2(g)→2MgO(s) C5H12(g)+8O2(g)→5CO2(g)+6H2O(g) H2O(l)→H2O(g) Positive Negative
B. Calculate the standard entropy change for the reaction 2Na(s)+Cl2(g)?2NaCl(s) using the data from the following table: Substance ?H?f (kJ/mol) ?G?f (kJ/mol) S? [J/(K?mol)] Na(s) 0.00 0.00 51.30 Cl2(g) 0.00 0.00 223.1 NaCl(s) -411.0 -384.0 72.10 Express your answer to four significant figures and include the appropriate units. Part A Predict the sign of the entropy change, AS°,for each of the reaction displayed. Drag the appropriate items to their respective bins. Ag+(aq) + Cl-(aq) → AgCl(s) | | Ca(OH)2(s) →...
For the reactions below, which reactions have negative entropy? 1. AgNO3(aq) + NaCl(aq) --> AgCl(s) + NaNO3(aq) 2. H2O(g) + CO2(8) --> H2CO3(aq) 3. H2(g) +12(8) --> 2 HI(g) 4. C2H2O2(g) --> 2 CO(g) + H2(g) 5. H2O(g) --> H2O(1) O 2, 3, 4 1, 2,5 1,4,5 0 2,4
Which reaction is predicted to have a negative S? BaCl2 (s) → Ba2+ (aq) + 2Cl- (aq) H2 (g) + I2 (s) → 2HI (g) C3H8 (g) + 5 O2 (g) → 3CO2 (g) + 4 H2O (g) N2 (g) + 3H2 (g) → 2NH3 (g) 2 KClO3 (s) → 2KCl (s) + 3 O2 (g)
Short Answer: (4 points each) 1.) Predict whether the entropy change is positive or negative for each of the following reactions. GIVE YOUR REASON FOR YOUR PREDICTIONS a) 2KC1O4(s) → 2KCIO3() + O2(8) b) H2O → H2O) c) 2Na(3) + H2O → 2NaOH(aq) + H2() d) N2(g) → 2N) 2.) State whether the sign of the entropy change expected for each of the following processes will be positive or negative, and EXPLAIN YOUR PREDICTIONS. a) PC130) + Cl2(e) → PCls(s)...
Can you also explain why? 1. Which change occurs with the largest increase in entropy at 25°C a. Br2 (liq)Br2 (g) b. C c. H2O (s) H20 (liq) d. HCI (g) + H20 (liq) HaO* (aq)+ Cr (aq) (graphite)C (diamond)
Predict whether the entropy change is positive or negative for each of the following reactions. Give reasons for your predictions. a. 2 KClO4(s) + 2 KClO3(s) + O2(g) b. H2O(g) → H20(1) c. 2 Na(s) + 2 H20(1) ► 2 NaOH(aq) + H2(g) d. N2(g) → 2 N(g)