Predict the predominant alkene product that would form when 2-bromo-2-methylpentane is treated with sodium methoxide in methanol. If the base were changed to KOC(CH2CH3)3 would the same alkene predominate? If not, why? What would be the structure of this alternate product be, if it formed?
Predict the predominant alkene product that would form when 2-bromo-2-methylpentane is treated with sodium methoxide in...
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___that is generated through an __mechanism. A) ether, Sw1 B) ether, SN2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___ that is generated through an ____mechanism. A) ether, SN1 B) ether, Sn2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
can question 7.58 and 7.69 be answered please 7.6 7.58 When (R)-3-bromo-2,3-dimethylpentane is treated with sodium hydroxide, four different alkenes are formed. Draw all four products and rank them in terms of stability. Which do you expect to be the major product? 7.59 When 3-bromo-2,4-dimethylpentane is treated with sodium hydroxide (NaOH), only one alkene is formed. Draw the product and explain why this reaction has only one regiochemical outcome. educed when each of the
what major E2 product would form on the reaction of (2S,3R) 2-bromo-3-methylpentane with base? QuesLIUI What major E2 product would form on reaction of (2S,3R) 2-bromo-3-methylpentane with ba CH3 O (Z) 3-methylpent-2-ene (E) 3-methylpent-2-ene (3R) 3-methylpent-1-ene (Z) 3-methylpenta-1,3-diene
4. When 2-bromo-1-phenylbutane is reacted in methanolic sodium methoxide, one might expect to see two products. However, only one product is formed to an appreciable extent. a. Write a detailed reaction scheme b. Write a detailed mechanism. c. Explain why only one of the possible products is formed to appreciable extent.
Draw and name the SN2 major product formed when (2R,5S)-2-bromo-5-chlorohexane is treated with sodium iodide in acetone. (Use only one equivalent of NaI.)
QUESTION 2 What major E2 product would form on reaction of (2S,3R) 2-bromo-3-methylpentane with base? |||11111 CH3 A. (Z) 3-methylpent-2-ene B. (E) 3-methylpent-2-ene C. (3R) 3-methylpent-1-ene D. (Z) 3-methylpenta-1,3-diene
3. If sodium methoxide in methanol was used in place of potassium t butanol, your GC analysis would look much more like the 2-butanol/sulfuric acid reaction products. In addition, a new, non-alkene product would be present in the GC analysis from a competing, non-elimination mechanism. Explain why the alkene distribution would change, what the new product would be, and why this new product would form. 4. If 2-bromobutane was reacted with trimethylamine to produce sec-butyl trimethyl- ammonium bromide (see below),...
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2) and the major organic products 1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
When 5-bromo-1-pentanol is treated with sodium hydride in diethyl ether, the product is analyzed to be C5H10O. Propose a likely structure for this product, suggesting a reasonable mechanistic pathway for its formation. Draw the mechanism of the first step of the reaction. Include ions in the answer. Include all lone pairs in your answer.