Qno 6:- Diethyl ether and THF are the solvents that can be used
as grignard reagents. This is because Most Grignard reactions are
conducted in ethereal solvents, especially diethyl ether and THF.
With the chelating diether dioxane, some Grignard reagents undergo
a redistribution reaction to give di-organomagnesium
compounds.
Hence option (c) is correct.
Q no 2:-Diethyl ether is an especially good solvent for the
formation of Grignard reagents especially Diethyl ether are good
solvents and are non-acidic (aprotic). Water or alcohols would
protonate them and thus can destroy the Grignard reagent, because
the Grignard carbon is highly nucleophilic. This is why grignard
reaction must be carried out in dry condition. Because water can
destabilise the intermediate.
Hence option (c) is correct.
Qno 4:-The Grignard reagent functions as a nucleophile, attacking
the electrophilic carbon atom that is present within the polar bond
of a carbonyl group
Hence option (e) is correct.
6 QUESTION 6 (1 point) Which of the following solvent(s) can be used for the Grignard...
lo (6 points) a. Why must ether used as solvent for the Grignard be scrupulously free of water or alcohol? b. 1-butanol, diethyl ether and pentane have close molecular weight but different boiling point, 1-butanol having the highest boiling point. Explain these observations
Diethyl ether is a good solvent to be used with Grignard reagents. Which of the following explanations for this laat alle! It can serve as a Lewis base and stabilize the Grignard reagent. It has a very high boiling so it can be heated to drive the Grignard formation to completion. It is polar enough to stabilize the Grignard reagent. It is aprotic and thus is not acidic enough to react with the Grignard reagent.
1. will a Grignard reagent be formed if acetone is used as solvent instead of diethyl ether. (reaction of bromobenzene with magnesium) 2. what is the product if reacting benzaldehyde with the Grignard reagent from Q1 in acetone?
please give correct answers to these 5 questions with explanations, thankyou Which solvent(s) is required for a nucleophilic addition reaction involving a Grignard reagent and a carbonyl compound? What is the primary organic product of the following reaction? н* Select one: +H2N. All reactions must be carried out in water All reactions must be carried out in dry solvents (free of water, for example diethyl ether). Select one There will be no reaction An initial reaction must be carried in...
i need help with the prelab questions please Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepare a Grignard reagent, phenyl magnesium bromide, from bromobenzene and magnesium metal. The Grignard reagent will then react with methyl benzoate to form triphenylmethanol. Introduction Grignard reagents, such as organomagnesium halides, were discovered in 1910 by French chemist Victor Grignard. The Grignard reaction is one of the most general methods for carbon- carbon bond formation in all of organic chemistry....
( ) 1. Which of the following solvents can be used with Grignard reagents? A. H2O B. methanol C. diethyl ether D. phenol ( ) 2. Which of the following reagents is appropriate to reduce a carboxylic acid into a primary alcohol? A. LiAlH4 B. NaBH4 C. Zn(Hg)/HCl D. Na2Cr2O7/H2SO4 ( ) 3. What is the correct IUPAC name of the following compound A. 5-bromo-2-methyl phenol B. 4-bromo-2-methylphenol C. 5-bromo-2-hydroxyltoluene D. 1-bromo-4-methylphenol ( ) 4. Which of the following compounds...
help with 23 HAPTER 14: ORGANOMETALLIC COMPOUNDS TWO common solvents for Grignard reagents are: 1) ethanol and diethyl ether. 2) diethyl ether and tetrahydrofuran (THF). 3) tetrahydrofuran (THF) and toluene. 4) water and ethanol. What is the product of the following reaction? CH, CH. CHCH.CH - ether 2) 2-ethyl-1-pentanol 2) 2-ethyl-1-butanol 3) 3-pentanel 4) 3-aethyl-1-pentanc: The reaction of benzyl sagnesius bromide (C.HSCHMB) with acetaldehyde (CHC40) followed by hydrolysis yields: 1) 1-phenyl-1-propanol 2) 1-phenyl-2-propanol 3) 2-phenyl-2-propanel 4 .-ghen -propane: mo synthesize...
all of them please QUESTION 1 1 points Save Answer Which of the following can have cis/trans isomers? Draw their isomers. CH3CH2CH=CH2 (CH3CH2)2CCHCH3 CH3CH2CH=CHCH3 CH2=CH2 QUESTION 2 1 points Save Answer Name the following compounds, with cis/trans nomenclature. trans-4-methyl-2-hexene trans-4-thyl-2-pentane O cis-4-thyl-2-pentane O cis-4-methyl-2-hexene QUESTION 3 1 points Save Answer Name the following compounds, with cis/trans nomenclature Br Br Otrsans-2,5-dibromo-3-hexene trans-1,4-dibromo-2-butane O cis-1,4-dibromo-2-butane cis 2,5-dibromo-3-hexene Click Save and Submit to see and submit Click Save All Answers to save all...
The following solutions all lower the freezing point of the given solvent.. Arrange them in order of increasing freezing point depression. a. 0.1 m MgCl, in water, i = 2.7, K_f = 1.86 degree C/m b. 0.20 m toluene in diethyl ether, i = 1.00, K_f = 1.79 degree C/m c. 0.20 m glycol methanol, i = 1.00, K_f = 1.99 degree C/m
1. encircle the appropriate reagent/solvent (out of the three indicated in each equation) from the list below to bring about the given conversions): Reagent A-NaBH4 in methanol Reagent B-LiAlH4 in methanol Reagent C-LiAlH4 in diethyl ether or tetrahydrofuran (THF) 2. One of these reagent/solvent systems should NEVER be attempted: which one is it and why should it not be used? Reagent.... Reagent..... H or Reagent ....... or Reagent ....... or Reagent ....... or Reagent... COOCH -OH CONHA NH2 Reagent. Reagent............