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Writing polyprotic acid and base reactions: 1. Write all the dissociations for the three polyprotic acids:...
1 a) Write the aqueous acid dissociation reactions for an acid and base dissociation reaction for a base according to th...
1 a) Write the aqueous acid dissociation reactions for an acid and base dissociation reaction for a base according to the Bronsted-Lowry definition b) Determine conjugate bases of acids and acids of bases c) Write the equilibrium expression for an acid or a base aqueous dissociation d) Evaluate strength of an acid or base based on its Ka or Kb or pKa or pKb. e) Apply Kw at 25oC and at different temperatures. f) Solve for the pH of strong...
Worksheet 19 Titration of Polyprotic Acids Name: 1. Calculate the sulfite ion [SO3'] concentration in a...
Worksheet 19 Titration of Polyprotic Acids Name: 1. Calculate the sulfite ion [SO3'] concentration in a 0.123 M solution of the weak acid, sulfurous acid (H2SO3). The stepwise dissociation constants of carbonic acid are: Ka1 1.41 x 102 Ka2-6.31 x 108 3. Consider the following dissociation of the triprotic acid, phosphoric acid (HsPOs): Step 1 H3POa + H2O <=> H30+ + H2PO4, Step 2 HP0i + H2O <=> H30+ + HP042- Step 3 HPO42-+ H2O <-> H3O+ + PO43- Kal=7.1...
Part 3: Working with the Titration Curve for a Polyprotic Acid and Strong Base Consider carbonic...
Part 3: Working with the Titration Curve for a Polyprotic Acid and Strong Base Consider carbonic acid, H.CO, (which is polyprotic) - a) Write the multi-step dissociation equilibrium for this acid in water (ie, there should be three chemical dissociation stages connected by two equilibrium arrows, given below): b) Below is an idealized titration curve showing the exhibited pH for 25.00 mL of a 0.100 M aqueous carbonic acid solution as a function of added 0.100 M NaOH in units...
please help >< Polyprotic acids have more than one proton to donate to water, therefore have...
please help ><
Polyprotic acids have more than one proton to donate to water, therefore have more than one equilibrium constant for proton donation. For phosphoric acid, there is a three-step equilibrium: H, PO +H,0 5 H2PO4 + H30* H,PO," +H,0 5 HPO - +H30* HPO 2- +,0 5 PO.- +,0* Kai = 7.11 x 10-3 Ka2 = 6.32 x 10-8 Ka; = 4.5 x 10-13 For all conjugate acid base pairs: K, XKK where K is for the reaction...
Phosphoric acid is triprotic with the step-wise dissociation shown below. A 1.75 M phosphoric acid solution...
Phosphoric acid is triprotic with the step-wise dissociation shown below. A 1.75 M phosphoric acid solution is prepared. Calculate the equilibrium concentrations of the species indicated. Report all answers in scientific notation using 2 sig figs. Rather than use the quadratic equation, you can make assumptions like we do in class (ie if K<<1, then 0.1-x ~ 0.1). Please fill in blanks below all species. Please answer each equilibrium concentration of each species in scientific notation. H3PO4H3PO4 + H2OH2O ↔↔...
Orthophosphate (PO4 3- ) is a soluble polyprotic acid capable of protonating/deprotonating up to 3 protons...
Orthophosphate (PO4 3- ) is a soluble polyprotic acid capable of protonating/deprotonating up to 3 protons to produce aqueous H3PO4 0 , H2PO4 - , HPO4 2- and PO4 3- . The pKa values of the associated dissociation reactions are as follows: pKa1=2.1; pKa2 = 7.2; and pKa3 = 12.4. Here you are asked to construct the speciation diagram of orthophosphate showing the concentrations of each of the four orthophosphate species in the pH range 1 -14 for a solution...
Acid & Base 1. Follow the acid & base experiment procedure and answer the following questions 2- Watch t...
Acid & Base 1. Follow the acid & base experiment procedure and answer the following questions 2- Watch the atom viewer for sodium hydroxide and hydrochloric acid then write what you observe. 3. Is sodium hydroxide acid or base and why? 4- Is hydrochloric acid or base and why? 5. Write the dissociation reaction for sodium hydroxide and for hydrochloric acid. 6- What is Unknown Solution 2 in the experiment represents acid or base and why? 7- Write the name...
(3 points) A 0.0730 M solution of a monoprotic acid is 1.07% ionized. What is the...
(3 points) A 0.0730 M solution of a monoprotic acid is 1.07% ionized. What is the pH of the solution? Calculate the Ka of the acid. (2 points) The pH of a 0.025 M solution of a monoprotic acid is 3.21. What is the Ka value for the acid? (2 points) Determine the percent ionization of a 0.0028 M HA solution. (Ka of HA = 1.4 x 10-9) (4 points) Lysine is triprotic amino acid (separately loses three H’s in...
a through e 1. The acid dissociation constant for HBrO is 2.3 x 10° at 25°C....
a through e
1. The acid dissociation constant for HBrO is 2.3 x 10° at 25°C. a. Write the reaction that corresponds to Ka. Rxn: b. Identify one conjugate acid-base pair in your reaction in part (@). C. Calculate the pH of a 0.45M solution of HBrO at 25°C. pH = d. Calculate the pH of a 0.25M solution of NaBrO at 25°C. pH = e. True/false: HBrO is amphoteric. HBrO is a stronger acid than HBrO2. (Circle one for...
Writing Proton-Transfer Equations for Acid-Base Reactions •PROBLEM: Write balanced total and net ionic equations for the...
Writing Proton-Transfer Equations for Acid-Base Reactions •PROBLEM: Write balanced total and net ionic equations for the following reactions and use curved arrows to show how the proton transfer occurs. –(a) hydriodic acid (aq) + calcium hydroxide (aq) → Give the name and formula of the salt present when the water evaporates. –(b) potassium hydroxide (aq) + propionic acid (aq) → Note that propionic acid is a weak acid. Be sure to identify the spectator ions in this reaction.
Worksheet 19 Titration of Polyprotic Acids Name: 1. Calculate the sulfite ion [SO3'] concentration in a 0.123 M solution of the weak acid, sulfurous acid (H2SO3). The stepwise dissociation constants of carbonic acid are: Ka1 1.41 x 102 Ka2-6.31 x 108 3. Consider the following dissociation of the triprotic acid, phosphoric acid (HsPOs): Step 1 H3POa + H2O <=> H30+ + H2PO4, Step 2 HP0i + H2O <=> H30+ + HP042- Step 3 HPO42-+ H2O <-> H3O+ + PO43- Kal=7.1...
Part 3: Working with the Titration Curve for a Polyprotic Acid and Strong Base Consider carbonic acid, H.CO, (which is polyprotic) - a) Write the multi-step dissociation equilibrium for this acid in water (ie, there should be three chemical dissociation stages connected by two equilibrium arrows, given below): b) Below is an idealized titration curve showing the exhibited pH for 25.00 mL of a 0.100 M aqueous carbonic acid solution as a function of added 0.100 M NaOH in units...
please help ><
Polyprotic acids have more than one proton to donate to water, therefore have more than one equilibrium constant for proton donation. For phosphoric acid, there is a three-step equilibrium: H, PO +H,0 5 H2PO4 + H30* H,PO," +H,0 5 HPO - +H30* HPO 2- +,0 5 PO.- +,0* Kai = 7.11 x 10-3 Ka2 = 6.32 x 10-8 Ka; = 4.5 x 10-13 For all conjugate acid base pairs: K, XKK where K is for the reaction...
Acid & Base 1. Follow the acid & base experiment procedure and answer the following questions 2- Watch the atom viewer for sodium hydroxide and hydrochloric acid then write what you observe. 3. Is sodium hydroxide acid or base and why? 4- Is hydrochloric acid or base and why? 5. Write the dissociation reaction for sodium hydroxide and for hydrochloric acid. 6- What is Unknown Solution 2 in the experiment represents acid or base and why? 7- Write the name...
a through e
1. The acid dissociation constant for HBrO is 2.3 x 10° at 25°C. a. Write the reaction that corresponds to Ka. Rxn: b. Identify one conjugate acid-base pair in your reaction in part (@). C. Calculate the pH of a 0.45M solution of HBrO at 25°C. pH = d. Calculate the pH of a 0.25M solution of NaBrO at 25°C. pH = e. True/false: HBrO is amphoteric. HBrO is a stronger acid than HBrO2. (Circle one for...
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