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Part 3: Working with the Titration Curve for a Polyprotic Acid and Strong Base Consider carbonic...
Part A: Calculating a Theoretical Titration Curve (Weak Acid - Strong Base) Consider the titration of 50.00 mL of 0.05 M acetic acid with 0.1 M NaOH. Calculate the pH of the resulting solution at the following points during the titration (given as volume of NaOH added). Volume NaOH pH of analyte 0.00 15.00 20.00 24.00 24.50 mL at equivalence point 40.00
Based on figure 2, the titration curve of 25.0 mL of phosphoric acid with 0.1082 M NaOH, determine the following: 1) The molarity of the acid 2) the Ka1 and pKa1 of the acid 3) the Ka2 and pKa2 of the acid Figure 2. Typical Polyprotic Acid Titration, pH vs. ml NaOH 12.00 Hd ml NaOH
1. Strong Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.150 M HCl with 0.100 M NaOH. Calculate the pH for the following volumes of NaOH (0 mL, 25 mL, 50 mL, 70 mL, 75 mL, 80 mL, 90 mL, 100 mL). pH Volume of NaOH, in milliters 0 25 50 70 75 80 90 100 L(g) (h) pH at the equivalence point Specify your choice of indicator
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.100 M formic acid, HCHO2 (Ka 1.80 x 104) with 0.100 M N2OH. Calculate the pH for the following volumes of NaOH (0 mL, 10 mL, 25 mL, 40 mL, 50 mL, 55 mL, 60 mL). Volume of N2OH, in milliters pH (a) (b) (c) (d) (e) (f) (g) 0 10 25 40 50 55 60 pH at the equivalence point Specify your...
Titration of a diprotic acid with a strong base You have a 10.0 mL solution containing 0.5 M carbonic acid. Carbonic acid is diprotic, with pKa1 = 6.35 and pKa2 = 10.33. You titrate this solution using 1.00 M NaOH . (a) Calculate the pH of the solution before adding any NaOH. (b) Calculate the amount of NaOH needed to reach the first midpoint. What is the pH? (c) Calculate the amount of NaOH needed to reach the first equivalence...
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question. a. What is the pH and what is the volume of added acid at the equivalence point? b. At what volume of added acid is the pH calculated by working an equilibrium problem based on the initial concentration and Ks of the weak base? c. At what volume of added acid does pH = 14 - pka ? d. At what volume of added...
Question: In the figure below, titration curves for strong acid with strong base and weak acid with strong base are shown. Compare the shapes of these curves early in the titration for three different cases: titration of a strong acid, titration of a weak acid with a lower pKa, and titration of a weak acid with a higher pKa. Discuss with the class why the titration curve for weak acids increase more rapidly early in the titration than do stronger...
Titration of Strong acid with strong base 2. Consider the titration of 25.0 mL of 0.100 M HCI with 0.100 M NaOH. a) Write down the chemical equation. Hellmunt Hell Hotele lua b) Calculate the volume of NaOH required to reach the equivalence point. Rome 250ML 0.25 0. In 2008 was x I c) Calculate the initial pH of the acid solution. (before adding NaOH). pol of Helin 0.1ac plte -log [ol 1] d) Calculate the pH after adding 5.00...
Consider the titration of the titration of 50.0 mL of 0.100 M acetic acid (HC2H2O2) with 0.100 M. The pka = 4.76. d. Determine the pH after 50.0 mL of titrant (NaOH) have been added. This is the equivalence point. All of the acid has been converted to its conjugate base, pH is determined by the equilibrium for the conjugate base
It's a weak acid strong base titration Experiment 4: Identification of an unknown acid by titration Page 2 of 15 Background In this experiment, you will use both qualitative and quantitative properties to determine an unknown acid's identity and concentration. To do this analysis, you will perform a titration of your unknown acid sample-specifically a potentiometric titration where you use a pH meter and record pH values during the titration, combined with a visual titration using a color indi- cator...