Question

One step in the manufacture of sulfuric acid is the oxidation of SO2 gas to SO3:...

One step in the manufacture of sulfuric acid is the oxidation of SO2 gas to SO3:
2SO2 (g) + O2 (g) 2SO3 (g) ΔH = ‒196 kJ mol–1

This reaction is usually performed at 698 K and 1-2 atmospheres of pressure.



2. Use Le Chatelier’s principle to explain why decreasing the temperature of the reaction vessel to 298 K should theoretically increase the yield of SO3 (g)
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Answer #1

According to  Le Chatelier’s principle, the reaction tends to move in that direction which will undo the change.

Now, Since This is an exothermic reaction(Given ), their is an increase in Heat in forward direction.

Now, as temperature is decrease, we need to move in that direction where their is an increase in temperature (From Le Chatelier’s principle) which occurs in FORWARD DIRECTION.

Thus the yield of SO3(g) increases on decreasing temperature.

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