Crystal Field Question.
I understand that octahedral shapes have larger splitting energies
then in tetrahedral complexes. And it would take more energy to
split more electrons. So would the order be from Highest to Lowest:
B>A>C where A, B, C are the compounds listed in their
respective orders.
octahedral is more splitting compare to tetrahedral due to more repulsion between ligand electrons and metal electrons.
so Cu is lesser splitting .
in compare to en and H2O en causes more splitting. so order is as follows.
Ni(en)3+2 > Ni(H2O)6+2 > Cu(CN)4-2
Crystal Field Question. I understand that octahedral shapes have larger splitting energies then in tetrahedral complexes....
2. a. Draw and show the crystal field splitting of the d orbitals in an octahedral complex, a tetrahedral complex, and in a square planar complex.(clearly label the orbitals) b. Explain the difference in the following crystal field splitting values (1) Co(NH3).]2+ 10200 cm"! : [CO(NH3).]* 22,900 cm (ii) [Cr(H20).]** 17,400 cm. ; [Cr(CN).]3-26,600 cm (iii) [MnF6]?- 22,200 cm-"; [ReF.]?- 27,800 cm- (iv) [Co(NH3).]2+ 10,200 cm '; [Co(NH3)4]2+ 5,900 cm c. Draw and show the filling of 6 d electrons...
please help answer question 4, a-f please using the data below from chart 1 objectives from lab, thank you DATA:CA y 3 Ay No3 Part I: Cell Potential of voltaic cells under standard conditions: cell CU CND2 #27 14.0m Give the half Half cell reaction at Combinations Oxidation Reduction E the anode and with [ion] takes place Theoretical takes place cathode. Write in M here here (V) above the arrow E c (V) if it is oxidation or reduction. |-0.340...