5. For each of the following questions, provide the missing reagents and conditions or predict the...
5. For each of the following questions, provide the missing reagents and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic mixture if applicable. If no reaction occurs, write out "no reaction." (48pts) - juli heptanal CH,(CH2)2NH2 NaBH,CN EtOK /EtOH HOX.B01 — jon
For each of the following questions, provide the missing reagents (that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic mixture if applicable. If no reaction occurs, write out "no reaction." . a. d. Ag,O/NH,OH "ОН e. 1) CH (CH,),Br/ 2 Li 2) HCI f но но но. (:) g. н NH NH
(Matching) Complete the following reaction by selecting the most appropriate reagent or reagents for each missing step. 1.777 2. CH,Br 3.??? OET 4.772 5.777 EIO OH NaH SOCI H,0* heat mi IV NaBH EtOH Br EtOH CH,CH,Br NaOH, THE VI VII VIH IX Х O CH,BE Br Br Br Br XI XII XV XIII XIV < 1st Step [Choose > 3rd Step [Choose 4th Step [Choose) 5th Step
Predict the products Predict the Product. Provide the stable organic product(s) for each reaction below NaBH CHOH 1 2 HCI, H,0 NaBH, (1 вg.)., сн,он 1. 2. HC, н,о 1. NaBH(осH (1 eq.), сн,он CI 2. HCI, H,O 1. LIAIH (1 eq.), THF Br 2. HCI, H2O
Please show detailed mechanism or explain in words. DQ25.11 Homework Draw the starting material: . SOCI, DMF 2. (CH,CH),CuLi, THF Ph 3. H,O Hint: Note that organocuprates only add once to acyl chlorides. DQ25.12 Homework Draw the product of the following reactions: 0 O HN CH CI NaBH (1 equiv.) EtOH Hint: Think about the reactivity of the carboxylic acid derivatives. DQ25.13 Homework Draw the product of the following reaction. CH,NO cc, tBuOK, DMSO CCI Hint: The first step in...
3. (20 points) Complete the following by adding the missing reagents) or major organic prodacet) он 1. CH CH,MgBr 1. Na 2. PhCH Br CH,CHO NaB 14. When a ketone is treated with LiAIH, followed by addition of H,O, what general class of product results? e) aldehyde b) secondary alcohol c)tertiary alcohol d) ether a) primary alcohol 15. What are the expected products of the reaction of PhOCH, with 1 equivalent of concentrated HI? b) phenol and methanol a) phenol...
5. What is the major Organic substitution product of the following reaction? PBr3 LiCN pyridine acetone A) A B)B C C D D E) E 6. Which reagents could be used to achieve the following transformation? OH OH A) Reaction with HBr, followed by reaction with NaOH in DMSO B) Reaction with Hg(OAc), in H,O/THF, followed by reaction with NaBH C) Reaction with CF,COOOH first, then H in H,O. D) Br, then hot CH,OH E) None of the above.
In each reaction box, place the best reagent and conditions from the list below. H-CEC-H 5 сна H2, Lindlar's catalyst H202. NaOH, H20 BHY/THF CrO2, H2SO4, H20 CH3Br Hz. Pt CH3CHBr NaBH NaNH2 NaOH CH,CH CH Br
1. For each of the following questions, provide the missing reagents that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racer mixture if applicable. If no reaction occurs, write out "no reaction." a 1) LiAlH 2) H.O NaBH / MeOH si -
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2) and the major organic products 1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...