1. (25 points) The Hamiltonian operator H, for a particular molecule has a complete set of...
(3)Consider an atomic p-electron (-1) which is governed by the Hamiltonian H-Ho +Hl,where Ho=a L,.bhand H,-./2 where a,bandcare nonzero real numbers with a 굶b. (a) Determine the Hamiltonian in Matrix form for a basis | I,m > with 1-land ,n = 0,±1. You may use the formula (b)Treat H,as a perturbation of Ho. What are the energy eigenvalues and eigenfunctions of the unperturbed problem? (c)Assume as>lcl and bsslcl. Use perturbation theory to calculate eigenvalues of H to first non trivial...
Please solve with the
explanations of notations
1. The two dimensional Harmonic Oscillator has the Hamiltonian n, n'>denotes the state In> of the x-oscillator and In'> of the y-oscillator. This system is perturbed with the potential energy: Hi-Kix y. The perturbation removes the The perturbation removes the degeneracy of the states | 1,0> and |0,1> a) In first order perturbation theory find the two nondegenerate eigenstates of the full b) Find the corresponding energy eigenvalues. На Hamiltonian as normalized linear...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
10. A harmonic oscillator with the Hamiltonian H t 2m dr? mooʻr is now subject to a 2 weak perturbation: H-ix. You are asked to solve the ground state of the new Hamiltonian - À + in two ways. (a) Solve by using the time-independent perturbation theory. Find the lowest non- vanishing order correction to the energy of the ground state. And find the lowest non vanishing order correction to the wavefunction of the ground state. (b) Find the wavefunction...
Q10 The Hamiltonian of a two-state system is given by H E ( i)- I02)(2 | -i | ¢1)(2 | +i | ¢2) (¢1 1) where , p2) form a complete and orthonormal basis; E is a real constant having the dimensions of energy (a) Is H Hermitian? Calculate the trace of H (b) Find the matrix representing H in the | øı), | 42) basis and calculate the eigenvalues and the eigenvectors of the matrix. Calculate the trace of...
(introduction to quantum mechanics)
, the Hamiltonian matrix is H- 3. In the basis |1) - (a) Find the eigenvalues En and eigenfunctions Ion) of H. (b) The system is in state 2) initially (t 0). Find the state of the system at t in the basis n). (c) Calculate the expectation value of H. Briefly explain your result. Does it depend on time? Why?
, the Hamiltonian matrix is H- 3. In the basis |1) - (a) Find the...
3. Consider a rigid rotor whose Hamiltonian is given by H L2(21) where L is the angular momentum operator and I is the moment of inertia of the rotator. Its rotation is described by a wave function: (0, N{Yo0(0,6)(1 3i) Y1-1(0,6) 2 Y21(0.0) Y20(0.) Find the normalization constant, N. (i) Find the probability to occupy state Yo0- (ii Find the expectation value of L2 of this state (iii Find the expectation value of L2 of this state (iv) Find (L2L2/21...
Incorrect Question 9 0/1 pts The state % = to 4-1 + tzv. + tag 42 is a linear combination of three orthonormal eigenstates of the operator Ô corresponding to eigenvalues - 1, 1, and 2. What is the expectation value for Ô for this state? V o 13+2821 Which of the following is true of observable in quantum mechanics? I. They are represented by Hermitian operators. II. Multiple observables can never be simultaneously measured. III. The operators representing observables...
(10 points) A spin-1/2 particle is originally in the ground state of the Hamiltonian Ho woS At time t - 0 the system is perturbed by Here and above s, are the spin matrices. Consider H, as a small perturbation of Ho i.e., ao > wi, Find the probability for the particle to flip its spin under the perturbation at t n oo.
Consider the dimensionless harmonic oscillator Hamiltonian,
(where m = h̄ = 1).
Consider the orthogonal wave functions
and
, which are eigenfunctions of H with eigenvalues 1/2 and 5/2,
respectively.
with p=_ïda 2 2 We were unable to transcribe this imageY;(r) = (1-2x2)e-r2/2 (a) Let фо(x-AgVo(x) and φ2(x) = A2V2(x) and suppose that φ。(x) and φ2(x) are normalized. Find the constants Ao and A2. (b) Suppose that, at timet0, the state of the oscillator is given by Find the constant...