3. Based on CFT qualitative discussions in class, qualitatively sketch the energy level diagram for the...
3. For each of these following complexes: Hexaaquacobalt(III), Trioxalatocobaltate(III), Triglycinatocobaltate(III), Tricarbonatocobaltate(III), and Tris(1,10-phenanthroline)cobalt(III).... Write out the chemical formula Identify the coordination number of the metal ion Identify whether the ligand is monodentate or polydentate Does the complex form cis-trans isomers? Does the complex form enantiomers? 4. In each of the complexes mentioned, cobalt has an oxidation state of +3. How many d electrons does Co(III) have? 5. Draw the Crystal Field splitting diagram for the Co(III) complex assuming it is...
Which dorbital configuration has the highest crystal field stabilization energy (CFSE) in a low spin octahedral crystal field? d4 d3 d6 ОООО g8 d? Predic whether the following complex is diamagnetic or paramagentic. 72+ paramagnetic need more information to answer this question diamagnetic The magnetic property of a transition metal complex can be predicted using crystal field theory. If we assume that the magnetic moment arises entirely from unpaired electron spins then the "spin only magnetic moment (us) is given...
1. What distinguish a transition metal from a main group metal? 2. Why is zinc not considered a transition metal? 3. Write the electronic configuration of the following ions; V". Cr, Mn, Fe, Ni, Ti" 4. What are basic assumptions of Crystal Field Theory? 5. Compounds containing the Scion are colorless whereas those containing Ti* ion are colored. Explain. 6. Predict the number of unpaired electrons in [Cr(en) ions. 7. What are spectrochemical series? 8. The compound hexaminecobalt(III) chloride is...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
For each of the following examples, (a) Draw a molecular orbital diagram. Include both the atomic orbitals that combine and the molecular orbitals that are formed. Clearly show the relative energies of all orbitals. Label all orbitals and show the appropriate number of electrons in the molecular orbitals. Give both labeling conventions (e.g. sigma2s and 1sigmag) for each of the molecular orbitals. You do not have to sketch the actual orbitals. (b) Give the bond order. (c) Indicate the effect...
So that we are all on the same page - we will use the following electrochemical series, taken from page 1070 of Tro. CN-1 > NO, > en > NH3 > H20 > OH > F-1 > CL-1 > Br 1>1-1 For the octahedral field splitting diagrams, be sure to show and annotate how you determine the following in your problem-solving process: a) electron configuration of the neutral metal b) electron configuration of the ion c) number of d electrons...
please only answers for questions 1-23. No work needed
1) Give the ground state electron configuration for the ion of Ba. A) [Krj5s24d 105pfes2 B) (KrjS24d105ph26p2 9(KrjS24d105p6 D) Kr525p E) [Kr]5s24d105pés 2) Choose the valence orbital diagram that represents the ground state of Se A) 1 11 1 4s 4p в) 1 11 4s 4p C) 1L 3s Зр D) 11 1L 1 3s Зр E) 1 1 4s 4P 3) How many valence electrons do the alkaline earth metals...