Calculate the second-order corrections to energy for the following Hamiltonian matrix.
Use the degenerate perturbation theory. Consider 'b' as perturbation.
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Exercise 4: Fine structure of hydrogenic atoms a) Consider a Hamiltonian H-Ho + λΗ. with Mr a small perturbation. Show that in (non-degenerate) perturbation theory the first order correction to the unperturbed, discrete energy level E(Holis given by and the second order by b) Apply this to evaluate the first order corrections to the energy levels (the so-called fine structure) of a hydrogenic atom, that arise due to relativistic corrections. Confirm that the answer for the total first order correction...
sorry i have only this information. Part B (Advanced: grade +0,+I,+2) Use degenerate perturbation theory to compute the second order energy shifts if 2 Solve for the eigenvalues of the total Hamiltonian by exact diagonalization of the matrix. Compare the exact solution to the approximated one given by the perturbation theory, e.g. using a sketch of the energies as a function ofA, for different values of the inter-atomic detuning Δ-ah- a2. Identify the regime when the perturbation theory gives a...
Consider a quantum mechanical system with 4 states and an unperturbed Hamiltonian given by 1 0 0 0 Ho E0 0 2 0 a small perturbation is added to this Hamiltonian 0 0 1 0 where e is much smaller than E a) [10pts] What are the energy eigenvalues of the unperturbed system of the following states? 1 o 2o 0 and which energy levels are degenerate? b) [10pts Find a good basis for degenerate perturbation theory instead of c)...
2. (20 pts) Degenerate Perturbation Theory. A system with Hamiltonian H has two degenerate eigenstates l ψ )and lp : Ea h petturbationHi-h E, :}lifts the degeneracy. The matrix given is in the basis Ambatas nlist 0 Eindthe "good" states, the two eigenstates Ιψ%)-α ws> +Pr IOS)ofHL and the sorresponding eigenvalues AEF which resolve the degeneracy 2. (20 pts) Degenerate Perturbation Theory. A system with Hamiltonian H has two degenerate eigenstates l ψ )and lp : Ea h petturbationHi-h E,...
(3) Take the case of 3 states ji> i-1,2, 3 which are eigenfunctions of H with degenerate eigenenergies, represented in matrix form. 10 0 0 H(0) 10 10 01,Ιψο > 12 A perturbation Hamiltonian is applied to the original system H 0 0 10 of matrix 3 0 0] a-1 Fl("-Volo a , with the off-diagonal elements given by a and numerically 1 (a) Calculate the energies of the three states to first-order perturbation theory represented by H'- HHby adding...
Physical Chemistry 1) Recall that first-order perturbation theory can be used to compute the energies of a as long as the coupling constant is small. First-order perturbation theory tells us that wh Hamiltonian splits into two terms en the such that Hi is small, the energy of a wavefunction φ) that is an exact solution of Ho is given by H° is given by: where E? is the energy of ф, under Ho. For a two-spin system, the wavefunctions are:...
H2 Consider two harmonic oscillators described by the Hamiltonians łty = ħws (atât ta+2) and = ħwz (6+6 +) with â (h) and at (@t) being the annihilation and creation operators for the first (second) oscillator, respectively. The Hamiltonian of two non-interacting oscillators is given by Ĥg = îl + Ħ2. Its eigenstates are tensor products of the eigenstates of single-oscillator states: Ĥm, n) = En,m|n, m), where İn, m) = \n) |m) and n, m = 0,1,2, ... a)...
H2 Consider two harmonic oscillators described by the Hamiltonians łty = ħws (atât ta+2) and = ħwz (6+6 +) with â (h) and at (@t) being the annihilation and creation operators for the first (second) oscillator, respectively. The Hamiltonian of two non-interacting oscillators is given by Ĥ, = îl + Ĥ2. Its eigenstates are tensor products of the eigenstates of single-oscillator states: Ĥm, n) = En,m|n, m), where İn, m) = \n) |m) and n, m = 0,1,2, ... 1....
(3)Consider an atomic p-electron (-1) which is governed by the Hamiltonian H-Ho +Hl,where Ho=a L,.bhand H,-./2 where a,bandcare nonzero real numbers with a 굶b. (a) Determine the Hamiltonian in Matrix form for a basis | I,m > with 1-land ,n = 0,±1. You may use the formula (b)Treat H,as a perturbation of Ho. What are the energy eigenvalues and eigenfunctions of the unperturbed problem? (c)Assume as>lcl and bsslcl. Use perturbation theory to calculate eigenvalues of H to first non trivial...
4. (30 points) Harmonic oscillator with perturbation Recall the Hamiltonian of an harmonic oscillator in 1D: p21 ÃO = + mwf?, where m is the mass of the particle and w is the angular frequency. Now, let us perturb the oscillator with a quadratic potential. The perturbation is given by Î' = zgmw?h?, where g is a dimensionless constant and g <1. (a) Write down the eigen-energies of the unperturbed Hamiltonian. (b) In Lecture 3, we introduced the lowering (or...