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Shown below on Fischer projections are two enantiomeric alcohols. What alkene and what reagents would yield...
13. What is the major organic product of the following reaction? ma POCI OH 16-POCIE CIZOPO...
13. What is the major organic product of the following reaction? ma POCI OH 16-POCIE CIZOPO 14. Which of the following statements about Grignard reagents (R-Mg-X) is true? (i) because of the highly polar nature of the Mg-X and Mg-C bonds in Grignard reagents, water and CH3OH are good solvents for Grignard reactions. (ii) reaction of a Grignard reagent with an aldehyde yields a secondary alcohol; (iii) Grignard reagents are strongly nucleophilic; (a) only () is true (d) only (i)...
20. Provide the reagents necessary to complete the following the following transformation. A. 1. BH3 THF2....
20. Provide the reagents necessary to complete the following the following transformation. A. 1. BH3 THF2. H2O2. HO- B. H20, H2SO4 C. OsO4 H202 D. CH3CO3H E. 1. CH3CO3H 2. H, H20 21. Provide the major organic product of the reaction below. 10. 2. (CHS uraw the major organic product generated in the reaction below. Pay particular attention to and stereochemical detail. CH3 CH, KMnO4 (warm, conc.) CH, H 23. Give the structure of the alkene which would yield the...
Alkene reaction and mechanisms practice exercise 1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic...
Alkene reaction and mechanisms practice exercise
1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic acid A) results in oxidative cleavage of the ring to produce an acyclic compound B) yields a meso epoxide C) yields an equimolar mixture of enantiomeric epoxides D) gives the same product as treatment of cyclopentene with Os04 E) none of the above 26) Provide a detailed, step-by-step mechanism for the reaction shown below. но Br2 na + HBT Br 27) Provide a detailed,...
19 NAME For the reactions shown below, . In the dashed circles of compound 1 write a Me and an H that would yield 2...
19 NAME For the reactions shown below, . In the dashed circles of compound 1 write a Me and an H that would yield 2 h. Over under the boxed arrow, add a suitable reagent for the elimination reaction Finish the Newman Projection to show the conformation needed for the elimination react d. In the dashed circles of compound 4, write a Me and an H for the product that would form. e. Check the box to indicate that this...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for each of the following molecules 0% HJC BM How similar are the names for B and C, even though there is the single change to the structure 2 Rank the priorities of these functional groups and substituents using Cahn-Ingold-Prelog nomenclature. Highest priority will be 1 and lowest will be 5; show your rationale CH:CH:CH CH CHCH:CH CHs,-SCH,-CH: CH:CH:CHCH CHCH, -CH2NHOH,-CH:NO Draw dash/wedge representations for...
please help me with Organic Chemistry/Alkenes problems. Thank you! Directions: Place your answers to the following...
please help me with Organic Chemistry/Alkenes problems. Thank you!
Directions: Place your answers to the following questions in the spaces provided. 1. A common problem in the acid-catalyzed hydration of alkenes is the formation of an ether byproduct. Show the formation of the ether byproduct in relation to the reaction below by providing a curved-arrow mechanism for its formation. (2 pts) H30+ Н,0 OH Ans. 2. Which is the correct sequence of steps necessary to complete the following reaction? он...
____ 1. The diagram below represents serine, a polar, uncharged amino acid. Which functional group gives...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
13. What is the major organic product of the following reaction? ma POCI OH 16-POCIE CIZOPO 14. Which of the following statements about Grignard reagents (R-Mg-X) is true? (i) because of the highly polar nature of the Mg-X and Mg-C bonds in Grignard reagents, water and CH3OH are good solvents for Grignard reactions. (ii) reaction of a Grignard reagent with an aldehyde yields a secondary alcohol; (iii) Grignard reagents are strongly nucleophilic; (a) only () is true (d) only (i)...
20. Provide the reagents necessary to complete the following the following transformation. A. 1. BH3 THF2. H2O2. HO- B. H20, H2SO4 C. OsO4 H202 D. CH3CO3H E. 1. CH3CO3H 2. H, H20 21. Provide the major organic product of the reaction below. 10. 2. (CHS uraw the major organic product generated in the reaction below. Pay particular attention to and stereochemical detail. CH3 CH, KMnO4 (warm, conc.) CH, H 23. Give the structure of the alkene which would yield the...
Alkene reaction and mechanisms practice exercise
1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic acid A) results in oxidative cleavage of the ring to produce an acyclic compound B) yields a meso epoxide C) yields an equimolar mixture of enantiomeric epoxides D) gives the same product as treatment of cyclopentene with Os04 E) none of the above 26) Provide a detailed, step-by-step mechanism for the reaction shown below. но Br2 na + HBT Br 27) Provide a detailed,...
19 NAME For the reactions shown below, . In the dashed circles of compound 1 write a Me and an H that would yield 2 h. Over under the boxed arrow, add a suitable reagent for the elimination reaction Finish the Newman Projection to show the conformation needed for the elimination react d. In the dashed circles of compound 4, write a Me and an H for the product that would form. e. Check the box to indicate that this...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for each of the following molecules 0% HJC BM How similar are the names for B and C, even though there is the single change to the structure 2 Rank the priorities of these functional groups and substituents using Cahn-Ingold-Prelog nomenclature. Highest priority will be 1 and lowest will be 5; show your rationale CH:CH:CH CH CHCH:CH CHs,-SCH,-CH: CH:CH:CHCH CHCH, -CH2NHOH,-CH:NO Draw dash/wedge representations for...
please help me with Organic Chemistry/Alkenes problems. Thank you!
Directions: Place your answers to the following questions in the spaces provided. 1. A common problem in the acid-catalyzed hydration of alkenes is the formation of an ether byproduct. Show the formation of the ether byproduct in relation to the reaction below by providing a curved-arrow mechanism for its formation. (2 pts) H30+ Н,0 OH Ans. 2. Which is the correct sequence of steps necessary to complete the following reaction? он...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
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