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1) A chemical reaction and a table of bond dissociation energies are shown below. H3C H...
1. Bond Dissociation Energies and Free Radicals Bond Bond Dissociation Energies (kJ/mol) Bond BDE Bond BDE (kJ/mol) (kJ/mol) H-H 436 CH3-H 439 H-F 570 CH3CH2-H 432 H-CI 432 (CH3CH2 413 BDE Bond (kJ/mol) 10-N 350 0-0 180 F-F O-H 0-C O-F 460 BDE (kJ/mol) | 200 180 159 | H-Br H-I 366 298 404 350 O-C1200 O-Br (CH3)3C-H C-C (sigma) C=C(pi) 210 C1-C1243 Br-Br 193 243 0 -I 220 I-I | 151 A. The enzyme methane monooxygenase catalyzes a remarkably...
Using the table of bond dissociation enthalpies, calculate AH° for the reaction A. (Use the entries for propene and propenyl halides for the calculation of cyclohexene and cyclohexenyl halides, respectively. Pay attention to the algebraic sign of your answer!) C-H bond BDE (kJ/mol) CH3-H 439 C2H:-H 422 (CH3), CH-H 414 (CH3)3C-H 405 CH2=CHCH2-H 372 CH2=CH-H 464 Table of bond dissociation enthalpies C-X bond BDE (kJ/mol) X, and HX bonds BDE (kJ/mol) CH3-I 242 CI-CI 247 C2H5-I 238 Br-Br 192 (CH3)2...
Using the table of bond energies below, the delta H for the reaction is? H2C = CH2 + H-Br -> H3C - CH2Br This is ethylene plus hydrogen going to ethyl bromide. Bond C-C C = C C - H H - Br C - Br D (kj/mol) 348 614 413 366 276 SHOW WORK
H2C=CH2 + CI H2C=CH + HCI Use the table of bond dissociation energies above to calculate AH for this reaction, the first step in the free radical chlorination of ethene. Table of Bond Dissociation Enthalpies Bond BDE (kJ/mol) H2C=CH-H 464 H-I 297 H-Br 368 H-C1 431 H-F 568 ΔΗ: kJ/mol This reaction is:
Calculate the enthalpy for the reaction below using the following bond dissociation energies. • H-H 436 kJ/mol O-H 460 kJ/mol 0-0 180 kJ/mol • 0=0 498 kJ/mol H -774 kJ/mol -654 kJ/mol 654 kJ/mol 774 kJ/mol
Given the following bond energies and the heat of reaction for the process below, estimate the C-H bond energ!y. Bond BDE (kJ/mol) 348 614 436 A. 420 kJ B. 283 kJ C. 525 KJ D. 350 kJ E. 645 kJ
C-H bond BDE (kJ/mol) CH3-H 439 C2H:-H 422 (CH3)2 CH-H 414 (CH3)3 C-H 405 Table of Bond Dissociation Enthalpies C-X bond BDE (kJ/mol) X2 and HX bonds BDE (kJ/mol) CH3-C1 351 CI 247 CH-C1 355 НСІ 431 (CH3)2CH-C 355 (CH3)3C-CI 355 CH3 CH3 CH3CHCHCH3 CH3CHCH2CH3 + a Cl2 CI HCI Using the table of bond dissociation energies in the first part of this question: Calculate AH for this reaction. kJ/mol Overall, this reaction is CH3 CH3CHCHCH3 CH3 CH3CHCH2CH3 + b...
Using the table of average bond energies below, the AH for the reaction is k], C=0(g) + 2H2(g) → H3C-0-Hg) Bond: C-0 C=0 C=0 D(kJ/mol): 358 799 1072 C-H 413 H-H 436 O-H 463 -116 -276 +116 +276
the enthalpy change in a chemical reaction can be determined using bond energies. energy must be added or absorbed to break bonds and that energy is released when bonds are formed. therefore ,you can calculate the total enthalpy of the reaction using following formula: dH= bonds broken-bonds formed Using bond energies, calculate the change in energy that accompanies the following reaction: H2 + O2 -> 2H2O Bond Bond Energy H-H 432 kJ/mol O-O 498 kJ/mol H-O 467 kJ/mol
Using the bond energies from the table below estimate ∆H for the following reaction C2H2(g) + H2(g) → C2H4(g) C-H (413), H-H (436), C-C (348), C=C (614), C≡C (839) A) +165 kJ/mol B) -390. kJ/mol C) +390. kJ/mol D) –124 kJ/mol E) –165 kJ/mol