Show a synthesis of each of the following target moleviles from methylenecyclohecane. Letters G-L
This as well
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Show a synthesis of each of the following target moleviles from methylenecyclohecane. Letters G-L This as...
ChemActivity 10: Oxidation and Reduction 149 7. Show a synthesis of each of the following target molecules from methylenecyclohexane. (Some syntheses may be only one step.) methylenecyclohexane (starting material) OH -CC-CH₂ OH OH OH _LOH OCH OH- 8 Draw the product that results when each set of reagents is mixed with methyeyclohexene 1) BHS THE HBr peroxides 2) HOOH NAOH HCI 1) Hg(OAc), THF, H2O 2) NaBH, NaOH Bry Pd 0°, dark, no peroxides Pd 1) MCPBA 2) H SO./...
For 1 - 3, design reasonable syntheses of each of the target molecules using the provided starting material and organic and inorganic reagents of your choice. Show the reagents needed for each step and the product of each step. Do not show any mechanisms. Please put all your answers on this sheet. Write your answers like this (actual number of starting steps may vary)material reagent(s) reagent(s) ABCD target Two equally reasonable routes are possible Can you find them both? (For...
a synthesis of each of the following target molecules from the starting reagent synt (8) 4. Sh ow methylenecyclohexane Br CH2 CH3 ?? Br ?? ??
Design a multi-step synthesis for each of the following target molecules from the indicated starting material. Show the reagents needed for each step and the product of each step. Do not show any mechanisms. Draw the structures of the diene and the dienophile that reacted to form the Diels-Alder product shown. Provide the missing reagents in this multistep synthesis.
Problem 1. Using the required reactant, show a
multi-step synthesis for each of the target molecules. For the
second target molecules, you must choose a reactant. Note, that the
equivalencies can be different for the required reactants and that
you can you use any reagent/reaction conditions of your choosing to
convert the required reactants to product.
Target Molecule OH OH Required Reactant Target Molecule ОН но- н -он Required Reactant
3) Provide a synthesis of the following molecules. Be sure to show all reagents and isolable products. No mechanisms required. Full credit to those syntheses that maximize yield and minimize side products. HO a) OEt b) and any alcohols Br HO Ho 요 c) OMe OH Br d) 0 OH e)
Devise a multi-step synthesis
of the target molecule from the given starting material. Show all
necessary reagents and conditions for each step and the product of
each step.
ОН
3. Devise a multi-step synthesis of the target molecule from the given starting material. Show all necessary reagents and conditions for each step and the product of each step. (7) OH BONUS: Please provide the arrow pushing mechanism of this reaction. Be sure to show a charges and stereochemistry where needed. To receive full credit, what is the name of this reaction? (4) NaOE HOE Br
(3) Propose an efficient synthesis of target molecules (a) and (b). All of the carbons in the targets must come from one of the compounds below. Draw the structure of the product formed after each synthetic step. Do not write mechanisms. Note Points off for long, inefficient syntheses Нас CH3I OEt OEt H-C CH methyl iodide ethyl 2-butenoate ethyl acetoacetate he ptane-2,6-dione H2C он CH
3. Devise a multi-step synthesis of the target molecule from the given starting material. Show all necessary reagents and conditions for each step and the product of each step. (7) OH