Number 12 Determine the coordination number for each ion: How many ions of each type are...
Name Report Sheet: The Structure of Crystals-An Experiment Using Models 9.11 Section 1. Coordination Numbers: Number of nearest neighbors on the same level SC ВСС FCC Number of nearest neighbors on the level above Number of nearest neighbors on the level below Coordination Number (-total # of nearest neighbors) 2. Total mumber of lons in the NaCI Unit Cell # of ions x fraction contributed to the unit cell- # of jons contributed Chloride ions on corners of the unit...
.Nickel oxide crystallizes in the NaCl type of crystal structure. The length of an edge of the unit cell of NiO is 4.18 Å. What is the NiO bond length? Assuming the anions touch along the face diagonal, what is the radius of an O2 anion? What is the approximate radius of the Ni2 ion? eaup foxo bi bo 40 Jobholdo eieoO 68 8 athanic Al ADOrep
Q. 3. Potassium fluoride adopts the rock salt (NaCl type) structure, with a density of 2.48 g/cm3. Using the data for the Part 4 model you constructed, calculate the expected distance between the center of the potassium ion and the center of an adjacent fluoride ion in pm. Q. 4. The diameter of a Cs+ ion is 334 pm; the diameter of a Br- ion is 392 pm. For CsBr, which crystallizes in the CsCl type structure from Part 5,...
The ReO3 structure is cubic with an Re atom at each corner of the unit cell, one O atom at the unit cell edge midway between the Re. Sketch the unit cell and determine the coordination numbers of the ions, and the identity of the structure if one cation were located at the body center. Confirm the formula of the compound.
3. The ReO2 structure is cubic with one Re atom at each corner of the unit cell and one O atom on each unit cell edge midway between the Re atoms. a. Sketch this unit cell. b. Determine the coordination number of each cation and anion. c. Confirm that the stoichiometry is consistent with the structure. d. Determine the identity of the structure type that would be generated if a cation were inserted into the center of the ReOz structure.
Calcium Fluoride Determine the number of calcium ions per unit cell. Determine the number of fluoride ions per unit cell. What is the empirical formula of calcium fluoride based on the relative number of each ion in the unit cells? Is the empirical formula determined from the lattice structure in agreement with the one predicted by the typical ion charges? Are the anions or cations arranged in one of the basic cubic unit cells (simple, body-centered, face-centered)?
Post-lab question Part A 1. Metallic sodium forms a body centered cubic crystal. Why would the water displacement method used in part A not be suitable to determine the density of sodium? (Hint: watch the following video to help you answer this question: https://www.youtube.com/watch?v=18tOtZKpi04) 2. Calculate the density of sodium. (The radius of a sodium atom is 186pm) Post-lab Question Part B: Consider cubic array iodide ions (r =220pm) in which the anions are touching along the face of the...
question 9 10 11 12 13 W (9)Explain the following terms: (9%) (a) Fermi level (b) p-type semiconductors (c) type- II superconducting (10) TiO, has a Rutile structure (a) What is the coordination number (C.N.) does each Ti atom have? (b) How many Ti atoms are at the body center of the unit cell (c) How many Oxygen atoms are at the quadrants of the bottom face in a unit cell? (9%) (11) Use the r./r.ratio to determine the C.N....
6. A single crystal, a. is made of grains with different crystallographic directions b. is formed as the result of interlocking unit cells without any interruption c. does not show polymorphism d. has isotropic properties 7. By increasing the temperature from room temperature to the melting point of iron, the sequence of polymorphic transformations of iron is a FCC-BCC-HCP b. FCC-BCC-FCC c. BCC-FCC-BCC d. BCC-FCC-HCP 8. The Miller indices for the crystallographic plane shown are a. (123) b. (336) c....
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1- [Ag(NH3)2]1+ [Cu(OH2)4]2+ [Pt(NH3)2Cl2] [Fe(CN)6]4- [Fe(OH2)6]2+ [Zn(CN)4]2- [Cd(NH3)4]2+ [Cu(CO)5] [CuCl5]3- [Fe(EDTA)]2- [Pt(en)2]2+