Procedure B. 1. Build two models of 1, 2-dimethyleyclopentane. The two methy can be on the...
Exercise 2: Geometric isomers. Build plastic models of cis- and trans-1,2-dibromoethene. Confirm that the two models are not superimposable. (2) For Draw a top view (atoms in plane) and side view (wedge) for each structure. Exercise 3: Cyclohexane. Build a plastic model of cyclohexane and rotate all C – C bonds into the staggered conformation. (3) Sketch the chair conformation you have constructed.
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2. Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3. Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons? 4. Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...
Remove one hydrogen atom from C_1 the hexane model, and one H atom plus its bond from C_6. Bend the carbon chain around and join C_1 to C_6 to make cyclohexane. Mentally designate one carbon as C_1. Place the model in the chair conformation by tipping C_1 up and C_4 down. Check the conformation with the instructor. Identify the axial and equatorial hydrogens and describe their orientation relative to the plane of the ring. Look down each successive C-C bond...
5. Construct a model of 1,2-difluoroethane. Draw the Newman projections for the staggered and eclipsed conformations of 1,2-difluoroethane. Are these molecules isomers or conformers? If they are isomers to what specific category do they belong? 6. The structure of cyclohexane (C6H12) is based on a six membered ring of carbon atoms. Construct a model of cyclohexane. Cyclohexane can exist in two conformations; the boat or chair conformation (shown below). What are the C-C-C, C-C-H, and H-C-H bond angles at each...
Numbers 2-4 & Thhe other 1 & 2 (Straight Chain Angle). Cylic Angle 1.Propane. 109.5. - Butane. 109.5. 90 Pentane 109.5. 108 2. Newman projections: Draw the Newman projections of all of the different energy levels and label them as staggered or eclipsed in order from lowest energy to highest. 3. Cyclohexane: Draw both the chair and boat conformation of 1,4-dimethylcyclohexane with the methyl groups as cis and trans for both conformations. Label your molecules for cis and trans. Tell...
TU c) Start with the model of propene built in 3a), substituting different hydrogen atoms of propene with a methyl group to form isomers of butene, CaHg. How many different isomers exist for butene (C4Hg)? Prepare models and draw the Lewis structures for each of the isomers. d) Two of isomers of butene comprise a pair of stereoisomers. Draw the skeletal structures and include IUPAC names for the cis and trans isomers. Recall in the cis isomer both methyl groups...
these are the phrase options Part Build models for the two isomers of 1-iodo-1-propene, then complete the sentences that describe these models. CH I CHE cis-1-iodo-1-propene trans-1-iodo-1-propene Match the phrases in the left column to the appropriate blanks in the sentences on the right. Make certain each sentence is complete before submitting your answer. View Available Hint(s) Reset chiral with superimposable mirror images 1. Try to manipulate the cis and trans isomers of 1-iodo-1-propene rotating bonds, but without breaking bonds....
2. Draw the line structure for a C5H13N FM amine containing a quaternary carbon, a FM alcohol C6H140 with two tertiary carbons and a cyclic ether of FM C5H100. (6 pts) 3. Draw the most stable chair conformation of each of the following compounds, and then determine whether represents the cis isomer or the trans isomer. Which one is the more stable chair conformation cis or trans isomer? Compound More stable chair conformation Cis or Trans Isomer?
Define and provide examples of the following terms: a) n-alkanes b) alkene c) alkyne d) saturated e) hydrophobic f) aromatic g) hydrophilic h) combustion i) methylene group j) methyl group k) common name l) IUPAC name m) conformations n) Newman projection o) eclipsed p) staggered q) gauche conformation r) anti conformation s) catalytic cracking t) cis-trans isomers of a ring u) chair conformation v) boat conformation w) distorted boat x) half chair conformation y) axial position z) equatorial position aa)...